Non-Noble Metal Catalysis

1. Auflage 2019
ISBN: 978-3-527-34061-3
Verlag: Wiley-VCH GmbH

Buch, Englisch, 616 Seiten, Format (B × H): 177 mm x 247 mm, Gewicht: 1312 g

An expert overview of current research, applications, and economic and environmental advantages

The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals-enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes.

Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns.

Providing essential conceptual and practical exploration, this valuable resource:

-Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications
-Highlights the multiple advantages of using non-noble metals in homogenous catalysis
-Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry
-Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum

Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.

Autoren/Hrsg.

Klein Gebbink, Robert J. M.

Moret, Marc-Etienne

Fachgebiete

• Naturwissenschaften Chemie Physikalische Chemie Chemische Reaktionen, Katalyse
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Chemische Reaktionstechnik (incl. Katalyse, Elektrolyse)

Inhaltsverzeichnis

PrefaceAPPLICATION OF STIMULI-RESPONSIVE AND "NON-INNOCENT" LIGANDS IN BASE METAL CATALYSISIntroductionStimuli-Responsive LigandsRedox-Active Ligands as Electron ReservoirsCooperative LigandsSubstrate Radicals in CatalysisSummary and ConclusionsCOMPUTATIONAL INSIGHTS INTO CHEMICAL REACTIVITY AND ROAD TO CATALYST DESIGN: THE PARADIGM OF CO2 HYDROGENATIONIntroductionReaction Energetics and Governing FactorNewly Designed Catalysts and Their ReactivityCorrelation Between Hydricity and ReactivityConcluding RemarksCATALYSIS WITH MULTINUCLEAR COMPLEXESIntroductionStoichiometric Reaction PathwaysApplication in CatalysisPolynuclear ComplexesOutlookCOPPER-CATALYZED HYDROGENATIONS AND AEROBIC N-N BOND FORMATIONS: ACADEMIC DEVELOPMENTS AND INDUSTRIAL RELEVANCEIntroductionCu-Promoted N-N Bond FormationCu-Catalyzed Homogeneous HydrogenationConclusionsC=C HYDROGENATIONS WITH IRON GROUP METAL CATALYSTSIntroductionIronCobaltNickelConclusionBASE METAL-CATALYZED ADDITION REACTIONS ACROSS C-C MULTIPLE BONDSIntroductionCatalytic Addition to Alkenes Initiated Through Radical MechanismOther Catalytic Additions to Unsaturated Bonds Proceeding Through Initial R· (R¿H) AttackCatalytic Addition to Alkenes Initiated Through Polar MechanismsHydrosilylation ReactionsConclusionIRON-CATALYZED CYCLOPROPANATION OF ALKENES BY CARBENE TRANSFER REACTIONSIntroductionAchiral Iron Porphyrin CatalystsIron Phthalocyanines and CorrolesIron Catalystswith N or N,OLigandsThe [Cp(CO)2FeII(THF)]BF4 CatalystConclusionsNOVEL SUBSTRATES AND NUCLEOPHILES IN ASYMMETRIC COPPER-CATALYZED CONJUGATE ADDITION REACTIONSIntroductionCatalytic Asymmetric Conjugate Additions to Alpha-Substituted Alpha,Beta-Unsaturated Carbonyl CompoundsCatalytic Asymmetric Conjugate Additions to Alkenyl-HeteroarenesConclusionASYMMETRIC REDUCTION OF POLAR DOUBLE BONDSIntroductionManganeseIronCobaltNickelCopperConclusionIRON-, COBALT-, AND MANGANESE-CATALYZED HYDROSILYLATION OF CARBONYL COMPOUNDS AND CARBON DIOXIDEIntroductionHydrosilylation of Aldehydes and KetonesReduction of Imines and Reductive Amination of Carbonyl CompoundsReduction of Carboxylic Acid DerivativesHydroelementation of Carbon DioxideConclusionREACTIVE INTERMEDIATES AND MECHANISM IN IRON-CATALYZED CROSS-COUPLINGIntroductionCross-Coupling Catalyzed by Simple Iron SaltsTMEDA in Iron-Catalyzed Cross-CouplingNHCs in Iron-Catalyzed Cross-CouplingPhosphines in Iron-Catalyzed Cross-CouplingFuture OutlookRECENT ADVANCES IN COBALT-CATALYZED CROSS-COUPLING REACTIONSIntroductionCobalt-Catalyzed C-C Coupling Through a C-H Activation ApproachCobalt-Catalyzed C-C Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides)Cobalt-Catalyzed C-X Couplings Using C-H Activation ApproachesCobalt-Catalyzed C-X Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides)MiscellaneousConclusions and Future ProspectsTRIFLUOROMETHYLATION AND RELATED REACTIONSTrifluoromethylation ReactionsTrifluoromethylthiolation ReactionsPerfluoroalkylation ReactionsConclusionCATALYTIC OXYGENATION OF C=C AND C-H BONDSIntroductionOxygenation of C=C BondsOxygenation of C-H BondsConclusions and Outlook ORGANOMETALLIC CHELATION-ASSISTED C-H FUNCTIONALIZATIONIntroductionC-C Bond Formation via C-H ActivationC-Heteroatom Formation via C-H ActivationConclusionsCATALYTIC WATER OXIDATION: WATER OXIDATION TO O2 MEDIATED BY 3D TRANSITION METAL COMPLEXESWater Oxidation - From Insights into Fundamental Chemical Concepts to Future Solar FuelsModelWell-DefinedWater Oxidation CatalystsConclusion and OutlookBASE-METAL-CATALYZED HYDROGEN GENERATION FROM CARBON- AND BORON NITROGEN-BASED SUBSTRATESIntroductionHydrogen Generation from Formic AcidHydrogen Generation from AlcoholsHydrogen Storage in Liquid Organic Hydrogen CarriersDehydrogenation of Ammonia Borane and Amine BoranesConclusionMOLECULAR CATALYSTS FOR PROTON REDUCTION BASED ON NON-NOBLE METALSIntroductionIron and Nickel CatalystsOther Non-Noble Metal-Based Catalysts: Co, Mn, Cu, Mo, and WConclusionNONREDUCTIVE REACTIONS OF CO2 MEDIATED BY COBALT CATALYSTS: CYCLIC AND POLYCARBONATESIntroductionCocatalysts for CO2/Epoxide Couplings: Salen-Based SystemsCo-Porphyrins as Catalysts for Epoxide/CO2 CouplingCocatalysts Based on Other N4-Ligated and Related SystemsAminophenoxide-Based Co ComplexesConclusion and OutlookDINITROGEN REDUCTIONIntroductionActivation of N2Reduction of N2 to AmmoniaReduction of N2 to SilylaminesConclusions and OutlookIndex

Über Autor(innen)

Bert Klein Gebbink, PhD, is full professor at Utrecht University, The Netherlands. His current research interests include homogeneous catalysis, organometallic chemistry, and bioinorganic chemistry, with a specific focus on iron-based catalysis, the immobilization of homogeneous catalysts and the catalytic conversion of biomass into chemical building blocks.Marc-Etienne Moret, MSc, is assistant professor at Utrecht University, The Netherlands. His research interests lie in the organometallic chemistry of base metals with the aim of using these cheap, nontoxic metals to promote (in)organic transformations of environmental / industrial significance.