Buch, Englisch, 487 Seiten, Format (B × H): 178 mm x 254 mm, Gewicht: 986 g
Reihe: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition
Compounds with Sulfur of Oxidation Number IV
Buch, Englisch, 487 Seiten, Format (B × H): 178 mm x 254 mm, Gewicht: 986 g
Reihe: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition
ISBN: 978-3-662-06365-1
Verlag: Springer
PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.
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