Molten Salt Chemistry and Technology

Erscheinungsjahr 1991
ISBN: 978-3-03859-763-6
Verlag: Trans Tech Publications

Sonstiges, Englisch, 814 Seiten, Format (B × H): 125 mm x 142 mm, Gewicht: 200 g

This "state-of-the-art" volume presents the new developments in fundamental research and in industrial applications of Molten Salts. Special attention is placed on recent developments of special topics such as Electrodeposition of Refractory Metals (Niobium, Molybdenum), and Organic Chemistry and Electrochemistry in Molten Salts.

Autoren/Hrsg.

Chemla, M.

Devilliers, D.

Vogler, Matthias

Inhaltsverzeichnis

Thermodynamic Properties of the Surface Phase from Fused Salts to WaterComplexes in Polyvalent Metal - Alkali Halide MeltsSolubility Studies of the Ca-CaO-CaCl2 System Spectroscopic and Electrochemical Investigations of Selected Aromatic and Heteroaromatic Compounds in Ambient Temperature Chloroaluminate MeltsSurface Tension of Alkali-Metal Acetate Hydrated Melts The Effect of Possible Phase Changes on the Heat Conduction of Slags Gold Anions in Alkali Bromide Melts: Solubility and Optical SpectrumInvestigations of Complex Formation and Phase Diagrams of Molten Salts Related to the Oxidized Form of Sulphuric Acid CatalystsNeodymium Chloride and Alkali Chlorides Mixtures: Calorimetric Investigation and Modeling BaF2-NaF-ZrF4 Melts: Experimental Thermodynamics and ModelingStructural Study of Molten CaCl2-KCl System Molecular Dynamics Simulation of Molten Mixture of Lithium Bromide and Lithium IodideStructural Analyses of B2O3-Cs2O GlassesEstimation of Excess Thermodymanic Functions of Aluminium Monochloride Dissolved in Alkali Chloride Melts Microstructure of the Metal-Molten Salt InterfaceCatalytic Activity and Spectroscopic Investigations of the M2S2O7/V2O5-SO2/O2/SO3/N2 System (M = Na, K and Cs)High Temperature NMR Studies of Oxide Glasses and MeltsThermodynamic Modeling of the 3(Zr,Hf)Cl4-2POCl3 Distillable Molten Salt CompositionStructure of Molten Alkanoates: Order and Disorder AspectsShort Range Structures of Several Rare Earth Chloride MeltsDirect Observations of Marangoni Convection in Molten SaltsCorrelations between Structure, Spectra and Thermodynamics of Transition Metals Dissoloved in Molten Chloroaluminate SolutionsX-Ray Diffraction Analysis of Molten AgCl under Ultra High PressureThe Chemla Effect in Molten (Li,Cs) Cl - Electromigration and MD Simulation Vapour Pressure and Thermodynamics of the System 1-Methyl-3-Ethyl-Imidazolium Chloride - Aluminium ChlorideThermodynamcis of MgCl2 in Plutonium Electrorefining The Thermodynamic Properties of Molten PbO-PbCl2PbS SolutionsConstruction and Thermodynamic Analysis of Molten Salt Phase Diagrams of Systems Containing Rare Earth ChloridesStudies on the Behaviour of Hydrous Melts: The Non-Aqueous (Ag, TI)NO3+DMSO Liquid System from Thermodynamic and Volumetric MeasurementsEffects of Alkali Halides on Sodium Borate Melts by Means of Molecular Dynamics SimulationsViscosity and Glass-Transition Temperature of Some Silicate Melts under Low and High PressuresSolubility of FeCl2 in Molten NaCl-AlCl3Careful (Partial) Oxidation of Methane Gas on Molten Metal ComplexesVibrational Spectra of Fluoro and Oxofluoro Complexes of Nb(V) and Ta(V)Raman Spectra of Subvalent Mercury Species Formed during Electrolysis of HgCl2 in MeltsPourbaix Diagram of Molten Oxide MixtureEmF Studies of AgNO3-KNO3-NaNO3 MeltsElectrochemical Properties of NbCl5 or K2NbF7 Dissolved in NaCl-KCL Equimolar MixtureElectroreduction of Fluoniobate, K2NbF7, in Fused NaCl-KCIPreparation of Electrode Materials by Elecrolytic Reduction of Molten SaltsStability and Electrochemical Properties of Mono and Trivalent Indium Species in Fused LICL-KCL EutecticBehaviour of Oxygen Reduced Species in Molten Na2CO3-K2CO3 Eutectic at 750-800?C: Correlation with the Oxidative Coupling of MethaneChemical and Electrochemical Behaviour of Tin Ions in ZnCl2-xNaCl Molten SaltsFundamental Study of Electrodeposition of Chromium in Fused Salts by Pulse TechniquesChemical and Electrochemical Behaviour of Chromium Containing Ions in the Molten Na2CO3-K2CO3 (58/42 MOL%) Eutectic Mixture at 800?CQualitative and Quantitative Electrochemial Studies of Multivalent Elements in Molten Oxide GlassesImpedance Measurements in KF-2HF Melts Production of Fluorine with Large Amplitude AC Signals in KF-2HF Melts Electrochemical Determination of Arsenic (III) in Molten Sodium HydroxideElectrochemical Behaviour of Niobium in CsCl-KCI-NaCI-NbCI5 MeltEffects of Oxide on Anodic Behaviours of Graphite Electrodes in Fluoride Molten SaltsRotating Ring Disk Electrode in Molten Chloride SystemsAn Electrochemical Study of Tungsten Species in an Acidic Zinc Chloride-Sodium Chloride MeltElectrochemical Reduction of Niobium Ions in Molten NaCl-KCIElectrochemical Investigation of Diffusion of Lithium in Beta-LiAl Alloy at Room TemperatureThe Conventional Standard Potential of AlloysElectrochemical Reduction of Molybdenum from KF-B2O3-K2MoO4 Molten Salt SystemContinuous Refining of Niobium in Molten SaltsThe Auxiliary Electrode for TiCl2 Electrolysis Design of Anodes The Auxiliary Electrode for TiCl2 Electrolysis the Active Porous MassElectrodeposition of Aluminum from AlCl3-MEIC-NaCl and AlCl3-MEIC-LiCl MeltsSummerized Process in the Electrolysis of Cryolite-Alumina MeltsIntercalation of Fluorine into Graphite in the KF2HF Melt Electrochemical Behaviour of Lithium Oxide in Equimolar NaCl-KCl at a Glass Carbon ElectrodeThin-Layer Melt Electrolysis The Niobium Chemistry in Molten LiCl+KCl EutecticElectrochemical Experiments in Molten Sulphates for Simulating Hot Corrosion of Metallic High Temperature MaterialsElectrochemical Studies and Anode Reaction Mechanisms of Al-Li Alloys and Li2O-LiF-CaF2 MeltsAspects of the Liquid Cerium Electrodeposition in Molten Halide MediaFormation of Corrosion Resistant Niobium Coatings by Electrode-Position in Fluoride MeltsStandard Potentials of Lanthanide and Actinide Trichlorides in Molten Eutectic LiCl-KCl ElectrolyteMetallurgical Electrochemistry: The Interface between Materials Science and Molten Salt ChemistryElectrochemical Reduction of Quinones from Molten AmidesElectroanalytical Study of the Reduction of KWCl6 in Molten LiCl-KCl EutecticDevelopment of AL-Mn Alloy Electroplated Steel Sheet from Molten SaltThe Electrochemical Process at the Interface of Carbon Electrode and Metal in the Baths for Refining of AluminiumElectrolysis of Zr4+ in the Molten Fluoride System under Gamma-Ray Radiation FieldStudies of the Electroreduction of Tantalum and Niobium in Fluorochloroaluminate MeltsAnodic Behavior of Nickel and Nickel Based Alloy in a CsF-HF-NH4F SystemLow Polarization Electrode Impregnated with Molten Metal Fluorides in Fluorine CellKinetics ot the Oxygen Electrode Reactions at Golden Electrode in Molten (Li/Na) Carbonate EutecticElectrochemical Characteristics of Calcia Stabilized Zirconia Electrolyte in the Molten Alkali Chloride-Carbonate SystemsResearch on Chemical Metallurgy of Al-Li Master Alloy in Molten SaltElectrorefining of Titanium Metal in Molten Alkali Halide MixturesAmide Electrolyte Molten Systems: Mixtures Showing Megavalue of the Dielectric ConstantMolten Salts Reactions a Process for Fine Grained Solids PreparationTemperature Dependence of the Vapor Pressures and Electrochemical Windows of the NH4HF2-HF MixturesInvestigation of the 1-Methyl-3-Ethyl-Imidazolium Chloride-AlCl3 Melt for Lithium Battery ApplicationGlobal Measure for Energy & Environmental Problems by Thorium Molten-Salt Nuclear Energy SynergeticsHydrotreating Properties of MoS2 Catalysts Prepared from Thiocyanate MeltsFeasibility Study of Materials for a Medium-Temperature Reserve Cell ConceptHigh-Temperature Calibration Quality Data: Molten Salts and MetalsMolten Salts Database for PC Users: Design and DevelopmentMolybdenum Alumosilicides Corrosion by Molten SaltsPreparations of Ion-Exchanged Beta-Alumina by Employing Molten Salts and those Applications to Thermodynamic InvestigationsThe Solubilization and Desulfurization of Coal in Low Temperature Chloroaluminate MeltsHigh Temperature Corrosion of Nickel with Molten Alkali Carbonate CoatingInfluence of the Environment in the Corrosion Kinetics of Different Superalloys at High Temperature in Eutectic Melt 60%V2O5-40%Na2SO4Effect of Hydrogen Sulfide on Kinetics of Hydrogen Oxidation in Molten Alkali CarbonateStudies on Pressurized Oxygen Electrode Reaction in Molten Alkali CarbonateGas Driven Electrolyte Flow and Its Implications for the Dynamics of Aluminium Smelter Cells