NMR Spectroscopy of Polymers

Innovative Strategies for Complex Macromolecules
Erscheinungsjahr 2012
ISBN: 978-0-8412-2667-8
Verlag: American Chemical Society

Buch, Englisch, Band 1077, 560 Seiten, Format (B × H): 160 mm x 228 mm, Gewicht: 842 g

Reihe: ACS Symposium Series

Nuclear magnetic resonance (NMR) spectroscopy is a premiere technique for the studies of polymers. It is widely used for polymer identification, quality control, and reaction monitoring to structure determination, polymer morphology, compatibility, chain conformation, dynamics, diffusion, and imaging. NMR users can be found in academia, industry, government agencies, and independent laboratories worldwide. Because articles on polymer NMR tend to be published in a
large number of different journals, it is useful to have a single book that includes review and papers on the latest advances by acknowledged leaders and active researchers in this field. This book satisfies this need.

This book originates from a three-day symposium at the Pacifichem Conference in December 2010, where active practitioners of NMR gathered to provide a lively and highly successful symposium that included 43 talks and 24 posters, representing the state-of-the-art research of polymer NMR in solids, liquids, and imaging. Most of the papers in this book are taken from the lectures given at the Pacifichem meeting. A total of 31 articles are included in this book, covering fundamental and applied
research, new methodology development, polymer structure determination, polymer dynamics and diffusion, nanostructures and nanocomposites, supramolecular assemblies, blends, miscibility, and heterogeneity, polymers under confinements and on surfaces, and multidimensional NMR. Thus, this book provides
a good representation of what is happening at the forefront of research in polymer NMR and also furnishes timely and authoritative reviews and original papers on the theory and the practice of NMR spectroscopy of polymers.

Zielgruppe

Chemists, physicists, biochemists, and chemical engineers as well as graduate students who are engaged in research and applications of polymer NMR

Autoren/Hrsg.

Cheng, H.N.

Asakura, Tetsuo

English, Alan

Fachgebiete

• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere
• Naturwissenschaften Physik Elektromagnetismus Mikroskopie, Spektroskopie
• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Polymerwerkstoffe
• Naturwissenschaften Chemie Analytische Chemie Magnetresonanz

Inhaltsverzeichnis

Preface
H. W. Spiess - An Appreciation
Overviews
1. Innovative NMR Strategies for Complex Macromolecules
H. N. Cheng, Tetsuo Asakura, and Alan D. English
2. Overview of NMR of Bulk Polymers
Hans Wolfgang Spiess
3. Tutorial on Solution NMR of Polymers
Peter L. Rinaldi
Solid State Polymer Structure
4. New Insights into Amorphous Macromolecules and Their Mixtures from Advanced Magnetic Resonance Experiments
Jeffery L. White, Marcin Wachowicz, Lance Gill, Joshua Damron, and Justyna Wolak-Dinsmore
5. Solid-State NMR Investigations of Semi-Crystalline PVIBE/?-PL and PK/PA Blends: Crystallite Size, Type, and Morphology Related to Physical Properties
Atsushi Asano
6. Investigation of Filler-Matrix Interactions and Confinement Effect in Polymer Nanocomposites
K. P. Pramoda, K. Y. Mya, T. T. Lin, J. Wang, and C. B. He
7. 1H MAS NMR Spectroscopy of Polyethylene Acrylic Acid Copolymers and Ionomers
Todd M. Alam, Janelle E. Jenkins, Michelle E. Seitz, C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper, Travis W. Baughman, and Kenneth B. Wagener
8. A Solid-State NMR Study of Boric Acid Doped in Poly(vinyl alcohol)
Kazuhiko Yamada
Polymer Motion and Diffusion
9. NMR Characterization of Canopy Dynamics in Nanoscale Ionic Materials
Michael L. Jespersen, Peter A. Mirau, Ernst von Meerwall, Richard A. Vaia, Robert Rodriguez, Nikhil J. Fernandes, and Emmanuel P. Giannelis
10. Dynamics of Disordered Structure of ?-Conjugated Polymers Investigated by Solid-State NMR
N. Asakawa, Y. Inoue, T. Yamamoto, R. Shimizu, M. Tansho, and K. Yazawa
11. Molecular Mobility and Phase Composition in Polyolefins: From Fundamental to Applied Research
V. M. Litvinov
12. Molecular Dynamics and Structure of the Crystalline Region of Isotactic-Polyolefins Characterized by Solid-State NMR
Toshikazu Miyoshi
13. Chain Mobility in Crosslinked EPDM Rubbers. Comparison of 1H NMR T2 Relaxometry and Double-Quantum 1H NMR
Pieter C. M. M. Magusin, Ramona A. Orza, Victor M. Litvinov, Martin van Duin, and Kay Saalwächter
14. Diffusion NMR of Polymers in Bicelles
Peter M. Macdonald
15. Understanding Anisotropy, Transport, and Ion Associations Inside Ionic Polymers
Jianbo Hou, Jing Li, Kyle G. Wilmsmeyer, Zhiyang Zhang, and Louis A. Madsen
16. 13C-NMR Observed Conformations and Motions of Neat Liquid and Crystalline n-Hexatriacontane and as a Guest in the Narrow Channels of Its Inclusion Compound Formed with ?-Cyclodextrin
M. A. Hunt, S. Villar-Rodil, M. A. Gomez-Fatou, I. D. Shin, F. C. Schilling, and A. E. Tonelli
Biopolymers and Biochemistry
17. NMR Characterization and Product Design of Novel Silk-Based Biomaterials
Aya Nagano, Yu Suzuki, Yasumoto Nakazawa, J. T. Gerig, and Tetsuo Asakura
18. The Interaction of A?(1-40) Peptide with Lipid Bilayers and Ganglioside As Studied by Multinuclear Solid-State NMR
Yasumoto Nakazawa, Yu Suzuki, Hazime Saitô, and Tetsuo Asakura
19. Characterization of Microbial Poly(?-L-lysine) and Its Derivatives by Solid-State NMR
Shiro Maeda, Chizuru Sasaki, and Ko-Ki Kunimoto
20. NMR, NIR, and Infrared Spectroscopy of Carbohydrate?Protein Interactions and Glycoproteins
I. C. Baianu and V. Prisecaru
NMR in Solution and in the Melt
21. Advanced Solution 2D-NMR of Fluoropolymers
Peter L. Rinaldi, Silapong Baiagern, Peter Fox, Jon L. Howell, Linlin Li, Xiaohong Li, Donald F. Lyons, Elizabeth F. McCord, Sangrama K. Sahoo, Eric B. Twum, and Faith J. Wyzgoski
22. Statistical Models and NMR Analysis of Polymer Microstructure
H. N. Cheng and Massoud J. Miri
23. Composition and Phase Morphology of Hard/Soft Acrylic Latex Polymers: NMR and AFM Study
Kebede Beshah and Robert F. Antrim
24. Application of Melt-State NMR Spectroscopy for Polyolefin Characterization in Industry
Gerhard Hubner, Isa Fonseca, and Matthew Parkinson
25. NMR Rescaling Revisited
M. E. Ries, A. Bansal, and M. G. Brereton
26. An NMR Investigation of a Polymer Melt under Shear
Ute Böhme and Ulrich Scheler
NMR Imaging
27. NMR Imaging and Its Application in the Study of Pharmaceutical Tablets
H. Thérien-Aubin, Y. J. Wang, and X. X. Zhu
28. Effect of Molecular Architecture on the Performance of 19F NMR Imaging Agents
Hui Peng, Kristofer Thurecht, Steven Hsu, Idriss Blakey, Oliver Squires, Nyoman Kurniawan, Stephen Rose, and Andrew K Whittaker
Special NMR Techniques
29. Latex State and Solid-State NMR Spectroscopy of Elastomers
Seiichi Kawahara
30. Proton MAS NMR Analysis of Phenyl Silane Functionalized Silica Nanoparticles
Khalid A. M. Thakur, Mark McCormick, Wendy L. Thompson, Chuntao Cao, and William J. Schultz
31. Dependence of the Amount of Xe Sorption on the 129Xe NMR Chemical Shift in Glassy Polymers
H. Yoshimizu
Epilogue: An Addiction to NMR
Editor's Biographies
Indexes
Author Index
Subject Index

Über Autor(innen)

English, Alan
Alan D. English is a DuPont Fellow in DuPont Central Research and Development at the Experimental Station in Wilmington, DE. His interests include solid state NMR spectroscopy of polymers and development of polymer structure/property/processing relationships. He is both an APS Fellow and an ACS Fellow and has been the recipient of a number of awards including the ACS Award in Applied Polymer Science and the International Award of the Society of Polymer Science Japan. He is the author of nearly 100 papers/patents/books and has organized or co-organized 15 symposia at national meetings/workshops since 1981. He is also an Associate Editor of Macromolecules.

Cheng, H.N.
H. N. Cheng is currently a research chemist at Southern Regional Research Center of the U.S. Department of Agriculture in New Orleans, where he works on projects involving improved utilization of commodity agricultural materials, green chemistry, and polymer reactions. Over the years, his research interests have included NMR spectroscopy, polymer characterization, biocatalysis and enzymatic reactions, functional foods, and pulp & paper technology. He is an ACS and a POLY Fellow and has authored or co-authored 148 papers, 24 patent publications, co-edited 7 books, and organized or co-organized 20 symposia at national meetings since 1997.

Asakura, Tetsuo
Tetsuo Asakura has been Associate Professor and Professor in the Department of Biotechnology of Tokyo University of Agriculture and Technology since 1981. He was Assistant Professor of Nihon University School of Dentistry at Matsudo in 1980-81 and Visiting Professor in the Department of Chemistry at Florida State University in 1990-91. He has produced approximately 300 publications. His research specialties include structural analysis of polymers using NMR, NMR chemical shift calculation, characterization of silk and transgenic silk, and applications of silk to biomaterials. He received Awards of Polymer Society in Japan and Fiber Society in Japan.

H. N. Cheng is currently a research chemist at Southern Regional Research Center of the U.S. Department of Agriculture in New Orleans, where he works on projects involving improved utilization of commodity agricultural materials, green chemistry, and polymer reactions. Over the years, his research interests have included NMR spectroscopy, polymer characterization, biocatalysis and enzymatic reactions, functional foods, and pulp & paper technology. He is an ACS
and a POLY Fellow and has authored or co-authored 148 papers, 24 patent publications, co-edited 7 books, and organized or co-organized 20 symposia at national meetings since 1997.

Tetsuo Asakura has been Associate Professor and Professor in the Department of Biotechnology of Tokyo University of Agriculture and Technology since 1981. He was Assistant Professor of Nihon University School of Dentistry at Matsudo in 1980-81 and Visiting Professor in the Department of Chemistry at Florida State University in 1990-91. He has produced approximately 300 publications. His research specialties include structural analysis of polymers using NMR, NMR chemical shift calculation,
characterization of silk and transgenic silk, and applications of silk to biomaterials. He received Awards of Polymer Society in Japan and Fiber Society in Japan.

Alan D. English is a DuPont Fellow in DuPont Central Research and Development at the Experimental Station in Wilmington, DE. His interests include solid state NMR spectroscopy of polymers and development of polymer structure/property/processing relationships. He is both an APS Fellow and an ACS Fellow and has been the recipient of a number of awards including the ACS Award in Applied Polymer Science and the International Award of the Society of Polymer Science Japan. He is the author of
nearly 100 papers/patents/books and has organized or co-organized 15 symposia at national meetings/workshops since 1981. He is also an Associate Editor of Macromolecules.