Advances in Silicones and Silicone-Modified Materials

Erscheinungsjahr 2012
ISBN: 978-0-8412-2559-6
Verlag: American Chemical Society

Buch, Englisch, Band 1051, 312 Seiten, Format (B × H): 157 mm x 229 mm, Gewicht: 544 g

Reihe: ACS Symposium Series

Silicon, silica and silicones each have important but separate technological roles to play for mankind in this millennium. All three have the element silicon (Si) in common but they have unique and distinctive chemistries, properties and applications. This book describes recent advances in silicones and the advanced materials which are based on the siloxane bond (Si-O).

We have seen tremendous developments in silicon-based materials over the past century and yet clearly there is still much potential for new advanced materials based on the siloaxne bond. With the high abundance of silicon and oxygen on Earth, we are probably working with the most sustainable and "green" materials if we adopt the correct materials chemistry, materials processing, materials recovery and materials reuse strategies.

Zielgruppe

Academics and professionals in related fields

Autoren/Hrsg.

Clarson, Stephen

Owen, Michael

Smith, Stephen

Van Dyke, Mark

Fachgebiete

• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Polymerwerkstoffe
• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere

Inhaltsverzeichnis

Preface

Dedication

Introduction
1. Advanced Materials Containing the Siloxane Bond

Stephen J. Clarson

Silicones
2. Properties and Applications of Silicones
Michael J. Owen
3. Polymorphs of Octaphenylcyclotetrasiloxane
Abhilasha M. Baruah, Anirban Karmakar, and Jubaraj B. Baruah
4. Synthesis and Characterization of Cycloaliphatic Siloxanes Copolymers
Ruby Chakraborty and Mark D. Soucek
5. Trypsin-Catalyzed Cross-Linking of ?,?-Triethoxysilyl-Terminated Polydimethylsiloxane: An Experimental and Computational Approach

Paul M. Zelisko, Travis Dudding, Karen R. Arnelien, and Heidi Stanisic
6. Viscoelastic Behavior of Polydimethylsiloxane Stabilized Magnetite Magnetic Nanoparticle Complexes

Wen Yin, Qiongdan Xie, Jianjun Deng, Jonathan D. Goff, Timothy P. Vadala, Judy S. Riffle, and Alan R. Esker
7. Characterization of Complex Engineering Silicones by 1H Multiple Quantum NMR and Large Scale Molecular Dynamics Simulations

Robert S. Maxwell, Richard H. Gee, Theodore Baumann, Naida Lacevic, Julie L. Herberg, and Sarah C. Chinn
8. Characterization of a Biomedical Grade Silica-Filled Silicone Elastomer Using Ultrasound

Alexander R. Anim-Mensah, Jeffrey E. Franklin, Aniruddha S. Palsule, Luis A. Salazar, Christopher W. Widenhouse, David B. Mast, James E. Mark, William B. Krantz, and Stephen J. Clarson
9. Fluorosilicones

Michael J. Owen

Copolymers, Networks and Dendrimers
10. Fluorine-Containing Organosilicon Polymers of Different Architectures Synthesis and Properties Study

N. A. Sheremetyeva, N. V. Voronina, A. V. Bystrova, V. D. Miakushev, M. I. Buzin, and A. M. Muzafarov
11. Radially Layered Poly(amidoamine-organosilicon) Dendrimers

Petar R. Dvornic and Michael J. Owen
12. Etching of Silicone Elastomers: Controlled Manipulation of Surface Roughness

Michael A. Brook, Lihua Liu, Shigui Zhao, and Zaid N. Mammo
13. Novel Organo-Siloxane Copolymers for Flame Retardant Applications

Ravi Mosurkal, Vincent Tucci, Lynne A. Samuelson, Kenneth D. Smith, Phillip R. Westmoreland, Virinder S. Parmar, Jayant Kumar, and Arthur C. Watterson
14. An Investigation into the Influence of Crosslinker Type and Solvent Composition on Physical Properties and Phase Transition Behavior of Poly(N-isopropylacrylamide) Hydrogels

Candan Erbil, Ezgi Toz, Özgür Akdemir, and Nurseli Uyan?k

Polyhedral Oligomeric Silsesquioxanes
15. Ion Effects on Trisilanolphenyl-POSS as an Adhesion Promoter

Sarah M. Huffer, Ufuk Karabiyik, Joshua R. Uzarski, and Alan R. Esker
16. Polyhedral Oligomeric Silsesquioxane-Functionalized Perfluorocyclobutyl Aryl Ether Polymers

Scott T. Iacono, Stephen M. Budy, Joseph M. Mabry, and Dennis W. Smith, Jr.
17. What Does It Take To Make a Stable POSS®/Polymer Composite?

David A. Schiraldi and Subramanian Iyer

Silica
18. The Role of Non-Bonded Interactions in Silica Formation in Vitro

Siddharth V. Patwardhan, David Belton, Graham Tilburey, and Carole C. Perry
Applications of Silicones and Silicone-Modified Materials
19. Function of Silicon-Oxygen Bonds in Fabrication of Holographic Gratings

Yusuke Kawakami and Yeong Hee Cho
20. Foam Control
Michael J. Owen

Indexes
Author Index

Subject Index

Über Autor(innen)

Stephen Clarson is Professor at the University of Cincinnati.

Michael Owen is Professor at the Michigan Molecular Institute.

Stephen Smith, Proctor and Gamble.

Mark Van Dyke is Associate Professor at Wake Forest University School of Medicine.