Biocatalysis

2000
ISBN: 978-3-211-83527-2
Verlag: Springer Vienna

Buch, Englisch, 184 Seiten, HC runder Rücken kaschiert, Format (B × H): 215 mm x 303 mm, Gewicht: 793 g

The book contains in its first part reviews on modelling of enzyme properties in organic solvents, lipase-catalysed synthesis of carboxylic amides, chemoenzymatic synthesis of lipidated peptides and chemoenzymatic transformations in nucleoside chemistry. In the second part contributions on recent developments in biocatalysis are given: lipase and esterase catalysed resolutions, investigations on regio- and stereoselective biocatalytic acylations in steroid side-chains and of substrate- and stereospecificity of Penicillin G amidases, deracemisation for amino acid synthesis, biocatalytic hydrolysis of nitriles, enzymatic and microbial hydroxylation of dienes and alpha-methyl esters, enantioselective sulphoxidations by peroxidases.

Zielgruppe

Research

Autoren/Hrsg.

Griengl, Herfried

Fachgebiete

• Naturwissenschaften Biowissenschaften Biochemie (nichtmedizinisch)
• Naturwissenschaften Biowissenschaften Tierkunde / Zoologie Tierphysiologie
• Wirtschaftswissenschaften Wirtschaftssektoren & Branchen Fertigungsindustrie Chemische Industrie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Biotechnologie Industrielle Biotechnologie
• Naturwissenschaften Chemie Organische Chemie Supramolekularchemie

Inhaltsverzeichnis

Invited Reviews.- Modelling of Enzyme Properties in Organic Solvents.- Lipase-Catalyzed Synthesis of Carboxylic Amides: Nitrogen Nucleophiles as Acyl Acceptor.- Chemoenzymatic Synthesis of Lipidated Peptides.- Chemoenzymatic Transformations in Nucleoside Chemistry.- Contributions.- Lipase-Catalyzed Regio- and Stereoselective Acylation of Hydroxy Groups in Steroid Side Chains.- Comparative Study of Substrate- and Stereospecificity of Penicillin G Amidases from Different Sources and Hybrid Isoenzymes.- Lipase-Catalyzed Resolution of Ibuprofen.- Novel Carboxyl Esterase Preparations for the Resolution of Linalyl Acetate.- Microbial and Enzymatic Synthesis of Optically Pure D- and L-3-Trimethylsilyl-alanine by Deracemization of D,L-5-Trimethylsilyl-methyl-hydantoin.- Immobilization of Rhodococcus AJ270 and Use of Entrapped Biocatalyst for the Production of Acrylic Acid.- Beauveria bassiana ATCC 7159 Contains an L-Specific ¦Á-Amino Acid Benzamidase.- Bacterial Biotransformation of Isoprene and Related Dienes.- Enantioselective Sulfoxidations Catalyzed by Horseradish Peroxidase, Manganese Peroxidase, and Myeloperoxidase.- Synthesis of Optically Active ?-Methyl ß-Hydroperoxy Esters by Diastereoselective Singlet Oxygen Ene Reaction and Horseradish Peroxidase Catalyzed Kinetic Resolution.