Carbyne and Carbynoid Structures

Softcover Nachdruck of the original 1. Auflage 1999
ISBN: 978-94-010-5993-0
Verlag: Springer

Buch, Englisch, 446 Seiten, Format (B × H): 160 mm x 240 mm, Gewicht: 742 g

Reihe: Physics and Chemistry of Materials with Low-Dimensional Structures

This is a book on one of the most fascinating and controversial areas in contemporary science of carbon, chemistry, and materials science. It concisely summarizes the state of the art in topical and critical reviews written by professionals in this and related fields.

Zielgruppe

Research

Autoren/Hrsg.

Heimann, R. B.

Evsyukov, S. E.

Kavan, Ladislav

Fachgebiete

• Naturwissenschaften Chemie Physikalische Chemie
• Naturwissenschaften Chemie Analytische Chemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffprüfung
• Naturwissenschaften Chemie Anorganische Chemie

Inhaltsverzeichnis

1: Introduction.- 1.1. The discovery of carbyne.- 1.2. The nature of carbyne: pros and cons.- 2: Carbyne and carbynoid structures in nature.- 2.1. Carbon-how many allotropes associated with meteorites and impact phenomena?.- 2.2. Other natural carbynoid structures.- 3: Syntheses of carbyne and carbynoid structures.- 3.1. Catalytic and electrochemical polycondensation reactions.- 3.1.1. Dehydropolycondensation of acetylene.- 3.1.2. Polycondensation reaction of halides.- 3.2. Chemical, photo-, and electrochemical transformations of polymers.- 3.2.1. Chemical dehydrohalogenation of polymers.- 3.2.2. Photo-and laser-induced dehydrohalogenation of polymers.- 3.2.3. Dehydrogenation of polyacetylene at high static pressure.- 3.3.1. Decomposition of hydrocarbons.- 3.3.2. Pyrolysis of organic polymers.- 3.4. Phase transformation of carbon materials.- 3.4.1. Condensation of carbon vapour.- 3.4.2. Ion-assisted condensation of carbon.- 3.4.3. Dynamic pressure synthesis.- 3.5. Electrochemical methods.- 4: Structural models of carbyne.- 4.1. Structural and electronic properties of polyyne.- 4.2. Kinked chains and layered structure.- 4.3. Carbyne intercalation compounds.- 4.4. Electron diffraction and microscopy.- 5: Properties of carbyne and carbynoid structures.- 5.1. Chemical properties.- 5.2. Thermophysical properties.- 5.3. Electrical and optical properties.- 6: Molecular and electron spectroscopy of carbyne structures.- 6.1. Raman and infrared spectroscopy.- 6.2. Electron spin resonance spectroscopy.- 6.3. Electron spectroscopy.- 6.4. Electron energy loss spectroscopy studies of carbynoid structures.- 7: Suggested technical applications of carbyne materials.- 7.1. Diamond synthesis from carbyne.- 7.2. Medical applications of carbynoid materials.