Interfaces and Interphases in Analytical Chemistry

Erscheinungsjahr 2011
ISBN: 978-0-8412-2604-3
Verlag: American Chemical Society

Buch, Englisch, Band 1062, 298 Seiten, Format (B × H): 153 mm x 224 mm, Gewicht: 590 g

Reihe: ACS Symposium Series

The book focuses on analyses that occur at particular interfaces or in specific interfacial regions. A broad range of electroanalytical, spectroscopic, and chromatographic techniques are discussed. As analytical devices continue to shrink, and as nanoparticles and colloids continue to grow as interesting areas of research, it is important to develop methods that probe the unique chemistry at interfaces and to understand how that chemistry differs from bulk
behavior.

Each chapter in this book focuses, in some way, on the chemistry occurring in unique, non-bulk environments. At the same time, this is not a book about surface analysis techniques, per se. Rather, it is a book about taking advantage of the unique properties of interfaces and interphases to develop or better understand new methods of analysis. As such, the book is organized according to the type of material being used, rather than by analysis technique.

Zielgruppe

Researchers using any of the material described in this book - micelles, bonded alkyl phases, nanoparticles, silica microparticles, "smart" materials.

Autoren/Hrsg.

Helburn, Robin

Vitha, Mark

Fachgebiete

• Naturwissenschaften Chemie Physikalische Chemie
• Naturwissenschaften Physik Thermodynamik Oberflächen- und Grenzflächenphysik, Dünne Schichten
• Naturwissenschaften Chemie Analytische Chemie
• Naturwissenschaften Physik Angewandte Physik Chemische Physik

Inhaltsverzeichnis

Preface

1. The "Interface" in Analytical Chemistry: Overview and Historical Perspective

R. S. Helburn
2. Defining the Micelle/Water Interface Using Computational and Experimental Results

Mark F. Vitha
Drake University, Department of Chemistry, Des Moines, Iowa 50311
3. Characterizing the Micelle/Water and Vesicle/Water Interface Using Solvatochromism and Linear Solvation Energy Relationships

Mark F. Vitha
4. Supported Lipid Bilayer Electrophoresis for Separation and Analytical Studies of Cell Membrane Biomolecules

Susan Daniel and Ling Chao
5. New Approaches to Monolithic Columns

Stefan Vujcic, Ivonne M. Ferrer, José G. Rivera, Li Li, and Luis A. Colón
6. Formation, Structure, and Reactivity of Amino-Terminated Organic Films on Silicon Substrates

Joonyeong Kim
7. Electrochemical Studies of Self-Organized Porphyrin-Polyoxometalate
Films on ITO

Giorgio Bazzan, Amit Aggarwal, and Charles Michael Drain
8. Temperature Dependent Resistance and Magnetoresistance of Single Wall Carbon Nanotubes Mounted on Silica Fiber Surfaces

Q. Lu, V. Samuilov, V. Ksenevich, T. Dauzhenka, and R. S. Helburn
9. Protein Microarray Substrates with High Interfacial Area Using Silica Colloidal Crystals

Mary J. Wirth, Corey M. Smith, Joshua J. Scott, and Michael E. Rice
10. Guanosine Gels for DNA Separations

Linda B. McGown and William S. Case
11. The Interface in Biosensing: Improving Selectivity and Sensitivity

John I. Njagi and Stanley M. Kagwanja
12. Smart Interfacial Layers: Sorption-Reinforced Catalytic Substrates for Detection and "Self-Decontamination"

Yongwoo Lee

Author Index

Subject Index

Über Autor(innen)

Vitha, Mark
Mark F. Vitha is Assistant Professor of chemistry at Drake University in Des Moines, IA, and the editor of the Chemical Analysis Series.

Helburn, Robin
Robin S. Helburn is Assistant Professor in the department of chemistry and physics at St. Francis College.

Robin S. Helburn is Assistant Professor in the department of chemistry and physics at St. Francis College.

Mark F. Vitha is Assistant Professor of chemistry at Drake University in Des Moines, IA, and the editor of the Chemical Analysis Series.