Design of Electronic Devices Using Redox-Active Organic Molecules and Their Porous Coordination Networks

1. Auflage 2021
ISBN: 978-981-16-3906-7
Verlag: Springer

Buch, Englisch, 76 Seiten, Format (B × H): 160 mm x 241 mm, Gewicht: 313 g

Reihe: Springer Theses

This book addresses the development of electronic devices using redox-active organic molecules and their porous coordination networks (PCNs), and highlights the importance of the molecular arrangement.   
Redox-active organic molecules hold considerable promise as flexible electronic elements, because their electronic state can easily be controlled using external energy. Although various kinds of redox-active organic molecules have been synthesized, attempts to apply them to electronic devices have been limited, owing to the lack of proper structural design. Moreover, ligand-based redox-active PCNs remain largely unexplored because of the limited availability of redox-active ligands. In addition to developing new redox-active organic molecules, in order to design electronic devices based on these molecules/PCNs, it is essential to understand the connections between their molecular arrangement, electrical properties, and redox activity. 
In this thesis, the redox-active organic molecule 2,5,8-tri(4-pyridyl)1,3-diazaphenalene (TPDAP), which features a large pi plane and multi-intermolecular interactivity, is used to develop a resistive switching memory device. In addition, its PCNs are synthesized to fabricate chemiresistive sensors, and the electrical properties are modulated using post-synthetic modification. Each mechanism is systematically investigated by means of structural determination and well-defined control experiments. Subsequently, the book proposes general guidelines for designing electronic devices using redox-active organic molecules. 
The book will appeal to a broad range of readers, from basic scientists to materials engineers, as well as general, non-expert readers.

Zielgruppe

Research

Autoren/Hrsg.

Kim, Jaejun

Fachgebiete

• Naturwissenschaften Chemie Analytische Chemie Magnetresonanz
• Technische Wissenschaften Elektronik | Nachrichtentechnik Elektronik
• Naturwissenschaften Chemie Organische Chemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Elektronik, Optik

Inhaltsverzeichnis

1. General Introduction.- 2. Resistive Switching Memory Devices Based on a Redox-active Organic Molecule.- 3. Humidity Detection Based on Redox-active Porous Coordination Networks.- 4. Tunable Electrical Properties of Redox-active Porous Coordination Networks via Post-synthetic Modification.- 5. Summary and Outlook.