Controlled/Living Radical Polymerization

Erscheinungsjahr 2020
ISBN: 978-0-8412-6995-8
Verlag: Oxford University Press

Buch, Englisch, 436 Seiten, Format (B × H): 156 mm x 234 mm, Gewicht: 785 g

Reihe: ACS Symposium Series

This book is focused on recent progress in the dynamically developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, and 944. Volume 1023 contains 26 chapters on mechanistic, synthetic and materials aspects of ATRP. Volume 1024 contains 24 chapters on other controlled/living radical polymerization techniques.

Zielgruppe

This book targets chemists and polymer scientists in academia and in industry

Autoren/Hrsg.

Matyjaszewski, Krzysztof

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Polymerwerkstoffe
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere

Inhaltsverzeichnis

Contents
Preface
xiOverview and Fundamentals of Radical Polymerization
1.: CRP - state of the art in 2008
Krzysztof Matyjaszewski
2.: Real and Apparent Sources of Polydispersity in Molecular Weight
Distributions from Radical Polymerization
Gregory Russell
3.: Molecular Design and Polymerization Behavior of Monomers
Polymerizable via Radical Ring-opening
Takeshi Endo and Kazuhide Morino
4.: Electron Spin Resonance (ESR) Observation of Radical Migration
Reactions in the Polymerization of Alkyl Acrylates
Atsushi Kajiwara
Kinetics & Mechanism of ATRP
5.: "Greening" of Copper Catalyzed Atom Transfer Radical Addition
(ATRA) and Cyclization (ATRC) Reactions
Tomislav Pintauer
6.: The Atom Transfer Radical Polymerization Equilibrium: Structural
and Medium Effects
Nick Tsarevsky, Wade A. Braunecker, Wei Tang, and Krzysztof
Matyjaszewski
7.: ATRP of Methacrylates Catalysed by Homo- and Heterobimetallic
Ruthenium Complexes
Albert Demonceau, Yannick Borguet, Xavier Sauvage, Dario Bicchielli,Sébastien Delfosse, Lionel Delaude, Laurianne Bareille, Pierre Le Gendre, and Claude Moïse
8.: Ruthenium Carborane Complexes in Atom Transfer Radical
Polymerization Dmitry F. Grishin, Ivan D. Grishin and Igor T.Chizhevsky
9.: Controlling the Fast ATRP of N-Isopropylacrylaminde in Water
Axel H. E. Müller, Pierre-Eric Millard, Nathalie C. Mougin, Alexander
Böker
10.: Controlled/"Living" Radical Polymerization of Vinyl Acetate
Youqing Shen, Huadong Tang, Maciej Radosz
11.: Reversible Chain Transfer Catalyzed Polymerization (RTCP) with
Alcohol Catalysts
Atsushi Goto, Norihiro Hirai, Tsutomu Wakada, Koji Nagasawa, Yoshinobu Tsujii,* and Takeshi Fukuda
Macromolecular Architecture by ATRP
12.: The Use of Atom Transfer Radical Coupling Reactions for the
Synthesis of Various Macromolecular Structures
Yusuf Yagci, Yasemin Yuksel Durmaz, Binnur Aydogan, Ioan Cianga
13.: Design of Thermoresponsive Materials by ATRP of Oligo(ethylene
glycol)-based (Macro)monomers
Jean-François Lutz, Özgür Akdemir, Nezha Badi, Sebastian Pfeifer, Zoya
Zarafshani, André Laschewsky, Erik Wischerhoff
14.: Gelation in Atom Transfer Radical Copolymerization with a Divinyl
Cross-linker
Haifeng Gao, Wenwen Li, Ke Min and Krzysztof Matyjaszewski
15.: Segregated Polymer Brushes via "Grafting to" and ATRP "Grafting
from" Chain Anchoring
Igor Luzinov, Yong Liu, and Viktor Klep
16.: Hybrid Block Copolymers Incorporating Oligosasaccharides and D
Synthetic Blocks Grown by Controlled Radical Polymerization
Yves Gnanou, Jérôme Lohmann, Clément Houga, Hugues Driguez, James
Wilson, Mathias Destarac, Sébastien Fort, Jean-François Le Meins,
Redouane Borsali, Daniel Taton
Materials Prepared by ATRP
17.: Controlled radical polymerizations as versatile synthetic routes for conjugated rod-coil block copolymers and their use as active polymer semiconducting materials in flexible organic electronic devices and systems
Georges Hadziiannou and Cyril Brochon
18.: Linear Viscoelasticity of Polymer Tethered Highly Grafted Nanoparticles.
Ramanan Krishnamoorti Vivek Goel , Joanna Pietrasik, Krzysztof Matyjaszewski
19.: Physical and mechanical properties of amphiphilic and adaptative polymer conetworks produced by Atom Transfer Radical Polymerization
Philippe Dubois, Laetitia Mespouille, Jean-Marie Raquez, Curtis W. Frank
20.: Acrylate Based Copolymers by ATRP: The Effect of Molecular Structure on Thermo-Mechanical Properties
Kaloian Koynov, Azhar Juhari, Tadeusz Pakula, and Krzysztof Matyjaszewski
21.: Novel Baroplastic Materials.
Metin H. Acar and Sebnem Inceoglu
Industrial Aspects of ATRP
22.: Functionalisation of polyHIPE Materials by ATRP Surface Grafting
Andreas Heise, David M. Cummins, Pieter C. M. M. Magusin
23.: Systematic Polymeric Libraries via Atom Transfer Radical Polymerization
Wojciech Jakubowski, Nicolay V. Tsarevsky, and Patrick McCarthy
24.: Polypropylene-graft-poly(methyl methacrylate) Graft Copolymers: Synthesis and Compatibilization of Polypropylene/Polylactide.
Hideyuki Kaneko, Junji Saito, Nobuo Kawahara, Shingo Matsuo, Tomoaki
Matsugi and Norio Kashiwa
25.: Novel Polyolefin Hybrids via Controlled/Living Radical
Polymerization
J. Saito, N. Kawahara, S. Matsuo, H. Kaneko, T. Matsugi, N. Kashiwa
26.: Opportunities in Controlled Radical Polymerization James Spanswick and Bernard Pike
Indexes
Author Index
Subject
Index.

Über Autor(innen)

Krzysztof Matyjaszewski is J.C. Warner Professor of Natural Sciences at Carnegie Mellon University in Pittsburgh, USA. His research focus is on macromolecular engineering, especially on the synthesis of well-defined copolymers using atom transfer radical polymerization and other controlled/living polymerization techniques. He is a member of the US National Academy of Engineering and the Polish Academy of Sciences and is the editor of the journals Progress in Polymer
Science and Central European Journal of Chemistry. Professor Matyjaszewski authored 13 books, over 60 book chapters, more than 600 peer-reviewed publications and holds 38 US patents. He received several awards from the American Chemical Society, including the 2009 Presidential Award in Green
Chemistry.