Reviews of Reactive Intermediate Chemistry

1. Auflage 2007
ISBN: 978-0-471-73166-5
Verlag: John Wiley & Sons Inc

Buch, Englisch, 496 Seiten, Format (B × H): 164 mm x 245 mm, Gewicht: 819 g

The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community.

The book includes:

- Relevant, practical applications
- Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces
- Discussions of emerging areas, particularly those involving dynamics and theories
- Concluding sections identifying key directions for future research are provided at the end of each chapter

Autoren/Hrsg.

Platz, Matthew S.

Moss, Robert A.

Jones, Maitland

Fachgebiete

• Naturwissenschaften Chemie Chemie Allgemein Toxikologie, Gefahrstoffe, Sicherheit in der Chemie
• Naturwissenschaften Chemie Chemie Allgemein Pharmazeutische Chemie, Medizinische Chemie
• Naturwissenschaften Chemie Chemie Allgemein Chemometrik, Chemoinformatik
• Naturwissenschaften Chemie Chemie Allgemein Chemische Labormethoden, Stöchiometrie

Inhaltsverzeichnis

Preface vii

Contributors ix

Part 1 Reactive Intermediates 1

1. Tetrahedral Intermediates Derived from Carbonyl Compounds, Pentacoordinate Intermediates Derived from Phosphoryl and Sulfonyl Compounds, and Concerted Paths Which Avoid Them 3
J.P. Guthrie

2. Silicon-, Germanium-, and Tin-Centered Cations, Radicals, and Anions 47
V.Y. Lee and A. Sekiguchi

Part 2 Methods and Applications 121

3. An Introduction to Time-Resolved Resonance Raman Spectroscopy and Its Application to Reactive Intermediates 123
D.L. Phillips, W.M. Kwok, and C. Ma

4. Time-Resolved Infrared (TRIR) Studies of Organic Reactive Intermediates 183
J.P. Toscano

5. Studies of the Thermochemical Properties of Reactive Intermediates by Mass Spectrometric Methods 207
P.G. Wenthold

6. Reactive Intermediates in Combustion 247
J.K. Merle and C.M. Hadad

7. Reactive Intermediates in Crystals: Form and Function 271
L.M. Campos and M.A. Garcia-Garibay

8. The Chemical Reactions of DNA Damage and Degradation 333
K.S. Gates

9. Conical Intersection Species as Reactive Intermediates 379
M.J. Bearpark and M.A. Robb

10. Quantum Mechanical Tunneling in Organic Reactive Intermediates 415
R.S. Sheridan

Index 465

Über Autor(innen)

Matthew S. Platz, PhD, is Distinguished University Professor at The Ohio State University, with more than 200 research articles and more than a dozen patents to his credit. Dr. Platz has been an Alfred P. Sloan Fellow, Camille and Henry Dreyfus Teacher-Scholar, and a Cope Scholar of the American Chemical Society.

Robert A. Moss, PhD, is the Louis P. Hammett Professor of Chemistry at Rutgers, The State University of New Jersey. Dr. Moss has been an Alfred P. Sloan Fellow and has published 400 articles in the areas of reactive intermediates and chemistry in molecular aggregates.

Maitland Jones Jr., PhD, is David B. Jones Professor of Chemistry at Princeton University. He has published a textbook on organic chemistry and more than 200 papers focusing on the chemistry of reactive intermediates. He has also been an Alfred P. Sloan Fellow.