Electrochemistry of N4 Macrocyclic Metal Complexes

Volume 1: Energy
2. Auflage 2016
ISBN: 978-3-319-31170-8
Verlag: Springer

Buch, Englisch, 316 Seiten, Format (B × H): 160 mm x 241 mm, Gewicht: 6812 g

This new edition describes the state of the art regarding molecular catalysts such as MN4 metal complexes, like porphyrins and phthalocyanines. This volume focuses on the particular case of the electrocatalysis of the reduction of O for practical applications in fuel cells and air batteries. Indeed, active and stable materials have been developed in the last 5 years where MN4 catalytic systems can be obtained by the pyrolysis of starting materials that do not necessarily involve MN4 complexes. These latter systems constitute a new class of stable and highly active non-precious metal catalysts for ORR that can replace expensive Platinum containing electrodes. The book also offers future projections and points out new fields of research and development of these non-precious metal catalysts.

Zielgruppe

Research

Autoren/Hrsg.

Zagal, Jose H.

Bedioui, Fethi

Fachgebiete

• Naturwissenschaften Chemie Physikalische Chemie Chemische Reaktionen, Katalyse
• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Naturwissenschaften Chemie Physikalische Chemie Elektrochemie, Magnetochemie

Inhaltsverzeichnis

From the Contents: Electrocatalysis.- Billion-Year Old Oxygen Cathode that Actually Works.- Reactivity predictors of non-precious metal pyrolyzed MNx catalysts in the reduction of O2.- Heat treated MNx non-precious metal catalysts for oxygen reduction.- Advances in metalloporphyrin catalysts for oxygen reduction.

Über Autor(innen)

Fethi Bedioui is currently at Chimie Paris Tech. Jose Zagal is currently at Universidad de Santiago de Chile.