Elementary Physicochemical Processes on Solid Surfaces

1991
ISBN: 978-0-306-43779-3
Verlag: Springer US

Buch, Englisch, 314 Seiten, HC runder Rücken kaschiert, Format (B × H): 160 mm x 241 mm, Gewicht: 1420 g

Reihe: Fundamental and Applied Catalysis

vi industrial process or a class of catalysts forms the basis of other books, with information on: fundamental science of the topic, the use of the pro­ cess or catalysts, and engineering aspects. Single topics in catalysis are also treated in the series, with books giving the theory of the underlying science, and relating it to catalytic practice. We believe that this approach is giving a collection of volumes that is of value to both academic and industrial workers. The series editors welcome comments on the series and suggestions of topics for future volumes. Martyn Twigg Michael Spencer Billingham and Cardiff Contents Introduction. 1. Chapter 1. Vibrational Relaxation of Adsorbed Particles. 5 1.1. General Approach to Describing Vibrational Relaxation. 5 1.2. Phonon Mechanism of Relaxation. 8 1.2.1. Relationship between the Simple Perturbation Theory and the Adiabatic Approximation. 9. 1.2.2. One-Mode Approximation. 11 1.2.3. Relaxation Caused by Correlation Potential Proportional to Displacement of Adsorbed Particle from Equilibrium. 12 1.2.4. Relaxation Caused by Correlation Potential Proportional to Displacement of Surface Atom from Equilibrium. 14 1.2.5. Results and Discussion. 15 1.3. Vibrational Relaxation via Interaction with Conduction Electrons. 18. 1.3.1. Dipole Approximation. '.'. 18.

Zielgruppe

Research

Autoren/Hrsg.

Zhdanov, V. P.

Fachgebiete

• Naturwissenschaften Chemie Anorganische Chemie Komplexchemie
• Naturwissenschaften Chemie Physikalische Chemie Elektrochemie, Magnetochemie
• Naturwissenschaften Chemie Anorganische Chemie Festkörperchemie
• Naturwissenschaften Chemie Organische Chemie
• Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie

Inhaltsverzeichnis

1. Vibrational Relaxation of Adsorbed Particles.- 2. Dynamics of Molecular Processes on Surfaces.- 3. Statistics of Adsorbed Particles.- 4. Theory of Rate Processes on Uniform Surfaces.- 5. Kinetics of Rate Processes on Uniform Surfaces.- 6. Kinetics of Some Heterogeneous Catalytic Reactions.- 7. Diffusion of Particles Adsorbed on Single Crystalline Surfaces.- Conclusion.