Baker / Betteridge / Belcher Photoelectron Spectroscopy

Chemical and Analytical Aspects
1. Auflage 2013
ISBN: 978-1-4831-5236-3
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 190 Seiten, Web PDF

Photoelectron Spectroscopy provides an introduction to the principles of photoelectron spectroscopy, including its applications in structural and analytical chemistry. It deals with both X-ray and UV-photoelectron spectroscopy. This book begins with the basic principles of electron spectroscopy and describes the UV photoelectron spectrometers and X-ray photoelectron spectrometers. It then lists several factors influencing the appearance of the photoelectron spectra. This book concludes by describing other forms of electron spectroscopy and photoelectron techniques. Students and chemists who are looking for a readable introduction to photoelectron spectroscopy will find this book useful.

Autoren/Hrsg.

Baker, A. D.

Betteridge, D.

Belcher, R.

Freiser, H.

Inhaltsverzeichnis

1;Front Cover;1
2;Photoelectron Spectroscopy: Chemical and Analytical Aspects;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;10
6;CHAPTER 1. BASIC PRINCIPLES;12
6.1;INTRODUCTION;12
6.2;GENERAL APPARATUS;14
7;CHAPTER 2. FACTORS UNDERLYING INSTRUMENTATION AND THEIR BEARING ON THE INTERPRETATION OF RESULTS;20
7.1;SOURCES;20
7.2;SAMPLE INTRODUCTION;30
7.3;ENERGY ANALYSIS OF THE EJECTED ELECTRONS, AND RELATED FACTORS AFFECTING THE RESOLUTION;33
7.4;ELECTRON MULTIPLIERS AND COUNTING EQUIPMENT;38
7.5;REFERENCES;39
8;CHAPTER 3. FUNDAMENTAL FACTORS AFFECTING THE APPEARANCE OF A SPECTRUM;42
8.1;FACTORS INFLUENCING THE SHAPES OF BANDS IN THE SPECTRA;42
8.2;FACTORS INFLUENCING THE POSITION OF BANDS IN THE SPECTRA;52
8.3;EXAMPLES OF THE PHOTOELECTRON SPECTRA OF SIMPLE ATOMS AND MOLECULES;54
8.4;COMPLICATING FACTORS;64
8.5;AUGER EFFECT AND AUTOIONIZATION;64
8.6;REFERENCES;66
9;CHAPTER 4. INTERPRETATION OF UV-PHOTOELECTRON SPECTRA;68
9.1;GENERAL COMMENTS;68
9.2;ELECTRONEGATIVITY AND INDUCTIVE EFFECTS;69
9.3;MESOMERIC EFFECTS;73
9.4;"LONE-PAIR" NON-BONDING ORBITALS AND INTERACTIONS BETWEEN THEM;74
9.5;7T-ORBITALS;81
9.6;INTERACTIONS BETWEEN p-SYSTEMS AND LONE-PAIR ORBITALS;81
9.7;HALOACETYLENES;83
9.8;cis- AND trans-l,3-DICHLOROPROPENE;85
9.9;VINYL HALIDES;87
9.10;SUBSTITUTED BENZENES;88
9.11;HETEROCYCLIC COMPOUNDS;93
9.12;STERIC EFFECTS;94
9.13;THE PERFLUORO EFFECT;96
9.14;CORRELATIONS;96
9.15;FUTURE DEVELOPMENTS AND OTHER STUDIES;97
9.16;REVIEW OF OTHER STUDIES;98
9.17;REVIEW OF OTHER STUDIES—ADDITIONAL MATERIAL;107
9.18;REFERENCES;109
10;CHAPTER 5. STRUCTURAL EFFECTS ON CORE ELECTRON BINDING ENERGIES AND X-RAY PHOTO ELECTRON SPECTRA;115
10.1;CHEMICAL SHIFTS;115
10.2;REFERENCES;130
11;CHAPTER 6. ANALYTICAL APPLICATIONS;131
11.1;INTRODUCTION;131
11.2;ANALYSIS BY X-RAY PES (ESCA);132
11.3;QUALITATIVE ANALYSIS;133
11.4;QUANTITATIVE ANALYSIS;136
11.5;UV-PES;143
11.6;QUANTITATIVE ASPECTS;154
11.7;REFERENCES;157
12;CHAPTER 7. OTHER FORMS OF ELECTRON SPECTROSCOPY;158
12.1;AUGER ELECTRON SPECTROSCOPY (AS);158
12.2;ELECTRON-IMPACT ENERGY-LOSS SPECTROSCOPY (EIS);162
12.3;ION-NEUTRALIZATION SPECTROSCOPY (INS);164
12.4;ANGULAR DISTRIBUTIONS OF PHOTOELECTRONS;164
12.5;OTHER PHOTOELECTRON TECHNIQUES;166
12.6;REFERENCES;167
13;APPENDIX 1: INNER-SHELL ORBITAL lONIZATION POTENTIALS FOR ATOMS;170
14;APPENDIX 2: FIRST lONIZATION POTENTIALS OF ATOMS, eV;174
15;APPENDIX 3: SELECTED APPROXIMATE ORBITAL IONIZATION POTENTIALS OF SOME SMALL MOLECULES, eV;176
16;APPENDIX 4: SELECTED VALUES OF INNER-SHELL BINDING ENERGIES MEASURED BY PHOTOELECTRON SPECTROSCOPY;177
16.1;NITROGEN 1st ;178
16.2;XENON 3d5/2;179
16.3;SULPHUR 2p;179
16.4;IODINE—VARIOUS LEVELS;180
16.5;OXYGEN 1st;180
17;APPENDIX 5: THE CALCULATION OF PARTIAL CHARGES ON ATOMS IN MOLECULES;182
17.1;REFERENCE;186
18;APPENDIX 6: PROBABILITY OF AUGER TRANSITION AS A FUNCTION OF ATOMIC NUMBER;187
19;INDEX;188