Benoit / Rempp Macromolecules

Main Lectures Presented at the 27th International Symposium on Macromolecules, Strasbourg, France, 6-9 July 1981
1. Auflage 2013
ISBN: 978-1-4831-4723-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 346 Seiten, Web PDF

Macromolecules covers the papers presented in the 27th International Symposium on Macromolecules that tackles themes that represent the trend of development in the field of macromolecular science. The book presents papers from qualified lecturers who discuss not only their work, but also the state of knowledge, developments, and applications in the field in which they are involved. The text covers topics ranging from polymer chemistry, polymer physics, to polymer technology that illustrate the diversity of the interest of researchers involved in polymer science and show the pluridisciplinarity nature of the field. The text will be of great interest to researchers and professionals who are concerned with the advances in macromolecular science.

Autoren/Hrsg.

Benoit, H.

Rempp, P.

Inhaltsverzeichnis

1;Front Cover;1
2;Macromolecules;4
3;Copyright Page;5
4;Table of Contents;6
5;SCIENTIFIC COMMITTEE;8
6;PREFACE;10
7;CHAPTER 1. ON COMMON TENDENCIES OF NON-EQUILIBRIUM POLYCONDENSATION;12
7.1;Abstract;12
7.2;Some Specific Features of Polycondensation;12
7.3;Types of Polycondensation;13
7.4;Functionality of Monomers;13
7.5;The Rule of Non-Equivalence of functional Groups;14
7.6;Raznozvennost of Polymers Formed by Non-Equilibrium Polycondensation;16
7.7;Kinetics and Mechanism of Polycondensation Reactions;17
7.8;Catalysis in Polycondensation Reactions;20
7.9;Stereoregular Polycondensation;20
7.10;Influence of the Solvent Nature on Polycondensation;21
7.11;Copolycondensation;22
7.12;Perspective of Polycondensation Development;23
7.13;REFERENCES;24
8;CHAPTER 2. TWENTY-FIVE YEARS OF LIVING POLYMERS;26
8.1;(1) Early developments in anionic polymerization;26
8.2;(2) Living polymers;27
8.3;(3) Review of some living polymer systems;28
8.4;(4) Living and dormant polymers;30
8.5;(5) Some mechanistic studies in living polymer systems;31
8.6;REFERENCES;35
9;CHAPTER 3. New Developments in Ring-Opening Polymerization;38
9.1;Abstract;38
9.2;INTRODUCTION;38
9.3;1. Catalysts for Photo-initiated Cationic Polymerization;38
9.4;2. Free Radical Ring-Opening Polymerization;40
9.5;3. Preparation of Polyphosphine;42
9.6;4. No Catalyst Alternating Copolymerizatio via Zwitterion Intermediates;43
9.7;REFERENCES;48
10;CHAPTER 4. EMULSION POLYMERIZATION: I. MECHANISMS OF PARTICLE FORMATION. II. CHEMISTRY AT THE INTERFACE;50
10.1;Abstract;50
10.2;I. MECHANISMS OF PARTICLE FORMATION;50
10.3;INTRODUCTION;50
10.4;QUANTITATIVE PREDICTION OF THE PARTICLE NUMBER; HOMOGENEOUS NUCLEATION;51
10.5;ABSOLUTE CAPTURE RATES;52
10.6;EXPERIMENTS ON NUCLEATION KINETICS;55
10.7;EFFECTS OF MONOMER SOLUBILITY; HETEROGENEOUS NUCLEATION;60
10.8;UNIFIED THEORY;61
10.9;THE THEORY APPLIED;61
10.10;REFERENCES;62
10.11;II. CHEMISTRY AT THE INTERFACE;63
10.12;INTRODUCTION;63
10.13;ORIGINS OF SURFACE GROUPS;64
10.14;SYNTHESIS OF ALL-SULFONATE MONODISPERSE POLYSTYRENE LATEXES;68
10.15;SYNTHESIS OF BIFUNCTIONAL POLYSTYRENE COLLOIDS;70
10.16;HETEROGENEOUS CATALYSIS;71
10.17;AUTOCATALYTIC POLYMER HYDROLYSIS;73
10.18;CONCLUSION;73
10.19;Acknowledgements;73
10.20;REFERENCES;73
11;CHAPTER 5. SOME PROBLEMS OF THE THEORY OF POLYMERANALOGOUS AND INTRAMOLECULAR REACTIONS OF MACROMOLECULES;76
11.1;Abstract;76
11.2;I. POLYMERANALOGOUS REACTIONS;76
11.3;II. INTRAMOLECULAR REACTIONS;80
11.4;III. REVERSE PROBLEMS OF THE THEORY OF MACROMOLECULAR REACTIONS ;83
11.5;IV. CONFORMATIONAL EFFECTS;91
11.6;V. OTHER EFFECTS;93
11.7;REFERENCES;94
12;CHAPTER 6. CHEMICAL MODIFICATIONS OF CHLORINATED POLYMERS;96
12.1;Abstract;96
12.2;INTRODUCTION;96
12.3;Part A Critical Review of the initiating systems associating an organic halide with a metal or a metal derivative;96
12.4;Part B Grafting of chlorinated rubber (C.R.) by methyl methacrylate (MMA) (6).;100
12.5;REFERENCES;107
13;CHAPTER 7. CATALYTIC ASYMMETRIC SYNTHESIS USING POLYMER SUPPORTED OPTICALLY ACTIVE CATALYSTS;110
13.1;Abstract;110
13.2;INTRODUCTION;110
13.3;RESULTS AND DISCUSSION;111
13.4;Acknowledgement;121
13.5;REFERENCES;121
14;CHAPTER 8. RECENT DEVELOPMENTS IN THE USE OF POLYMERIC REAGENTS;124
14.1;Abstract;124
14.2;INTRODUCTION;124
14.3;TRANSFER AGENTS;126
14.4;MUTUAL INACCESSIBILITY OF POLYMERIC REAGENTS;128
14.5;CONCLUDING REMARKS;134
14.6;REFERENCES;134
15;CHAPTER 9. THE EFFECT OF MACROMOLECULAR STRUCTURE ON THE BEHAVIOUR OF POLYMER CATALYSTS;136
15.1;Abstract;136
15.2;1. INTRODUCTION;136
15.3;2. METAL FREE POLYMER CATALYSTS;137
15.4;3. POLYMER-METAL CATALYSTS;142
15.5;4. FINAL REMARKS;147
15.6;ACKNOWLEDGEMENT;147
15.7;REFERENCES;148
16;CHAPTER 10. INTERMOLECULAR EXCIMER INTERACTIONS IN POLYMERS;150
16.1;Abstract;150
16.2;INTRODUCTION;150
16.3;EXPERIMENTAL DEMONSTRATION OF THE EXSISTENCE OF INTERMOLECULAR EXCIMERS;153
16.4;CONCENTRATED SOLUTIONS OF POLYSTYRENE IN 1,2-DICHLOROETHANE;156
16.5;EXCIMERS IN SOLID POLYMER FILMS;160
16.6;REFERENCES;164
17;CHAPTER 11. RELAXATION METHODS FOR STUDYING MACROMOLECULAR MOTION IN THE BULK;166
17.1;Abstract;166
17.2;INTRODUCTION;166
17.3;NMR METHODS;168
17.4;MACROMOLECULAR MOTION;171
17.5;REFERENCES;179
18;CHAPTER 12. SOME NEW ASPECTS OF CRYSTALLIZATION MODES IN POLYMERS;182
18.1;Abstract;182
18.2;INTRODUCTION;182
18.3;A) CRYSTALLIZATION FROM THE RANDOM STATE;182
18.4;B) ORIENTATION INDUCED CRYSTALLIZATION;195
18.5;Acknowledgement;200
18.6;REFERENCES;200
19;CHAPTER 13. NEUTRON SCATTERING STUDIES ON THE CRYSTALLIZATION OF POLYMERS;202
19.1;Abstract;202
19.2;INTRODUCTION;202
19.3;PRINCIPLES OF EVALUATION OF NEUTRON SCATTERING DATA;203
19.4;THE SMALL ANGLE RANGE;205
19.5;THE INTERMEDIATE AND WIDE ANGLE RANGES;206
19.6;THE DIRECT CORRELATION FUNCTION;212
19.7;SEGREGATION AND INTERMOLECULAR CLUSTERING;217
19.8;CONCLUSIONS;219
19.9;ACKNOWLEDGEMENT;219
19.10;REFERENCES;220
20;CHAPTER 14. MOLECULAR MECHANISMS IN POLYMER FRACTURE;222
20.1;Abstract;222
20.2;INTRODUCTION;222
20.3;DUCTILE DEFORMATION;222
20.4;CRAZING;223
20.5;HOMOGENEOUS DAMAGE FORMATION;227
20.6;CRACK PROPAGATION;228
20.7;CRACK HEALING;229
20.8;ACKNOWLEDGEMENTS;232
20.9;REFERENCES;232
21;CHAPTER 15. POLYELECTROLYTES-COUNTERION INTERACTIONS;236
21.1;ABSTRACT;236
21.2;INTRODUCTION;236
21.3;Polyelectrolyte theories from the point of view of counterion localization;237
21.4;Site binding;238
21.5;CONCLUSION;242
21.6;REFERENCES;243
22;CHAPTER 16. STRUCTURES AND PROPERTIES OF CONDUCTING POLYMERS;244
22.1;Abstract;244
22.2;INTRODUCTION;244
22.3;PRISTINE POLY(ACETYLENE);246
22.4;DOPED (CH)X;253
22.5;TRANSPORT PROPERTIES;258
22.6;Acknowledgement;260
22.7;REFERENCES;260
23;CHAPTER 17. A COMPREHENSIVE THEORY OF THE HIGH IONIC CONDUCTIVITY OF MACROMOLECULAR NETWORKS;262
23.1;Abstract;262
23.2;INTRODUCTION;262
23.3;QUALITATIVE APPROACH FOR THE IONIC CONDUCTIVITY OF MACROMOLECULAR MATERIALS;262
23.4;QUANTITATIVE APPROACH FORTHE IONIC CONDUCTIVITY OF MACROMOLECULAR MATERIALS;263
23.5;VISCOELASTIC PROPERTIES OF SALT-CONTAINING NETWORKS;264
23.6;EXPERIMENTAL STUDY OF THE IONIC CONDUCTIVITY OF MACROMOLECULAR NETWORKS;267
23.7;Acknowledgements;274
23.8;REFERENCES;274
24;CHAPTER 18. THE STRUCTURE AND PROPERTIES OF ULTRA HIGH MODULUS FILMS AND FIBRES;276
24.1;Abstract;276
24.2;INTRODUCTION;276
24.3;RIGID CHAIN POLYMERS;276
24.4;FLEXIBLE CHAIN POLYMERS;277
24.5;CONCLUSION;284
24.6;REFERENCES;284
25;CHAPTER 19. STRUCTURE-PROPERTY RELATIONSHIPS IN COMPOSITE MATRIX RESINS;286
25.1;Abstract;286
25.2;INTRODUCTION;286
25.3;STRUCTURE-PROPERTY RELATIONSHIPS;287
25.4;EXPERIMENTAL STUDIES OF MOLECULAR NETWORK AND MORPHOLOGICAL STRUCTURE;288
25.5;RESULTS AND DISCUSSION;294
25.6;CONCLUSIONS;298
25.7;Acknowledgement;299
25.8;REFERENCES;299
26;CHAPTER 20. THE ADHESION OF POLYMERS TO HIGH ENERGY SOLIDS;300
26.1;Abstract;300
26.2;INTRODUCTION;300
26.3;THE INTERPHASE;301
26.4;THE INTERFACIAL SURFACE;311
26.5;CONCLUSION;314
26.6;REFERENCES;314
27;CHAPTER 21. BIODEGRADATION OF POLYMERS FOR BIOMEDICAL USE;316
27.1;Abstract;316
27.2;INTRODUCTION;316
27.3;INTRACELLULAR ENZYMES;318
27.4;VARIABLE MODEL POLYMER SYSTEM FOR AN INVESTIGATION OF THE RELATIONSHIP BETWEEN STRUCTURE AND BIODEGRADABILITY;320
27.5;DEGRADATION OF COPOLYMERS OF N-(2-HYDROXYPROPYL)METHACRYLAMIDE BY MODEL ENZYMES;323
27.6;DEGRADATION OF STUDIED COPOLYMERS BY INTRACELLULAR ENZYMES;327
27.7;DEGRADATION OF HYDROPHILIC GELS WITH CHYMOTRYPSIN;329
27.8;CONCLUSIONS;329
27.9;Acknowledgement;329
27.10;REFERENCES;330
28;CHAPTER 22. SYNTHETIC POLYMER BIOMATERIALS IN MEDICINE -- A REVIEW;332
28.1;Abstract;332
28.2;INTRODUCTION;332
28.3;SYNTHETIC POLYMERIC BIOMATERIALS;333
28.4;THE POLYMER-BIOLOGIC INTERFACE;340
28.5;BIOLOGIC RESPONSES;342
28.6;TESTING AND CLEARANCE OF POLYMERIC BIOMATERIALS;343
28.7;REFERENCES;345