Brenner Interfacial Transport Processes and Rheology

1. Auflage 2013
ISBN: 978-1-4832-9227-4
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 576 Seiten, Web PDF

This textbook is designed to provide the theory, methods of measurement, and principal applications of the expanding field of interfacial hydrodynamics. It is intended to serve the research needs of both academic and industrial scientists, including chemical or mechanical engineers, material and surface scientists, physical chemists, chemical and biophysicists, rheologists, physiochemical hydrodynamicists, and applied mathematicians (especially those with interests in viscous fluid mechanics and continuum mechanics).As a textbook it provides materials for a one- or two-semester graduate-level course in interfacial transport processes. It may also be noted that, while separate practical and theoretical subdivisions of material have been introduced, a kind of cross-emphasis is often stressed: (i) to the academic scientist, or the importance of understanding major applications of interfacial transport; and (ii) to the industrial scientist, of the importance of understanding the underlying theory.

Autoren/Hrsg.

Brenner, Howard

Inhaltsverzeichnis

1;Front Cover;1
2;Interfacial Transport Processes and Rheology;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;14
6;PART: I INTERFACIAL RHEOLOGY: BASIC THEORY, MEASUREMENTS & APPLICATIONS;20
6.1;CHAPTER 1. Interfacial Rheology and Its Applications;22
6.1.1;1.1 Historical Review;23
6.1.2;1.2 Surfactants;27
6.1.3;1.3 Colloidal Dispersions;30
6.1.4;1.4 Interfacial Hydrodynamics in Engineering Processes;30
6.1.5;1.5 Summary;36
6.2;CHAPTER 2. Basic Properties of Interfacial Rheology;40
6.2.1;2.1 Interfacial Tension;41
6.2.2;2.2 Dynamic Interfacial Properties;44
6.2.3;2.3 Interfacial Shear Viscosity;46
6.2.4;2.4 Interfacial- Tension Gradient;49
6.2.5;2.5 Interfacial Dilatational Viscosity;52
6.2.6;2.6 Summary;54
6.3;CHAPTER 3. Interfacial Transport Processes;60
6.3.1;3.1 The Macroscale View of a Fluid Interface;61
6.3.2;3.2 Interfacial Geometry;63
6.3.3;3.3 Interfacial Statics;67
6.3.4;3.4 Interfacial Kinematics;72
6.3.5;3.5 The Generic Balance Equation in Continuous Three-Dimensional Media;80
6.3.6;3.6 The Generic Volumetric Transport Equation in Discontinuous Three-Dimensional Media and the Generic Surface- Excess Transport Law;85
6.3.7;3.7 Examples;94
6.3.8;3.8 Summary;101
6.4;CHAPTER 4. Interfacial Transport of Momentum;116
6.4.1;4.1 The Equations of Mass and Momentum Transport in Continuous Three-Dimensional Media;117
6.4.2;4.2 The Equations of Interfacial Mass and Momentum Transport;124
6.4.3;4.3 Non-Newtonian Interfacial Rheological Behavior;134
6.4.4;4.4 Examples;140
6.4.5;4.5 Summary;168
6.5;CHAPTER 5. Interfacial Transport of Species;180
6.5.1;5.1 The Equations of Species Transport in Continuous Three-Dimensional Media;181
6.5.2;5.2 The Equations of Interfacial Species Transport;184
6.5.3;5.3 Adsorption Kinetics;187
6.5.4;5.4 Adsorption- or Diffusion-Controlled Surfactant Transport to and from the Interface;189
6.5.5;5.5 The Surface Equation of State;190
6.5.6;5.6 Examples;192
6.5.7;5.7 Summary;204
6.6;CHAPTER 6. Measurement of Dynamic Interfacial Tension and Dilatational Elasticity;212
6.6.1;6.1 Oscillating Jet Method;213
6.6.2;6.2 Surface Wave Methods;215
6.6.3;6.3 Maximum Bubble Pressure Method;221
6.6.4;6.4 Oscillating Bubble Method;223
6.6.5;6.5 Langmuir Trough Method;224
6.6.6;6.6 Falling Meniscus Method;225
6.6.7;6.7 Pulsed Drop Method;227
6.6.8;6.8 Summary;228
6.7;CHAPTER 7. Measurement of Interfacial Shear Viscosity;232
6.7.1;7.1 Canal Surface Viscometers: The Deep-Channel Surface Viscometer;233
6.7.2;7.2 Disk Surface Viscometers;237
6.7.3;7.3 Knife Edge Surface Viscometers;239
6.7.4;7.4 Summary;244
6.8;CHAPTER 8. Measurement of Interfacial Dilatational Viscosity;248
6.8.1;8.1 Surface Wave Methods;249
6.8.2;8.2 Droplet Deformational Methods;252
6.8.3;8.3 The Maximum Bubble Pressure Method;258
6.8.4;8.4 Summary;260
6.9;CHAPTER 9. Measurement of Non-Newtonian Interfacial Rheological Properties;264
6.9.1;9.1 Nonlinear Interfacial Rheological Behavior;264
6.9.2;9.2 Viscoelastic Interfacial Rheological Behavior;270
6.9.3;9.3 Viscoplastic Interfacial Rheological Behavior;276
6.9.4;9.4 Summary;279
6.10;CHAPTER 10. Interfacial Stability;284
6.10.1;10.1 Nanna! Mode Interfacial Stability Analysis;285
6.10.2;10.2 The Stability of Superposed Fluids;286
6.10.3;10.3 Rayleigh Instability;287
6.10.4;10.4 Interfacial Turbulence;292
6.10.5;10.5 Benard Instability;295
6.10.6;10.6 Summary;297
6.11;CHAPTER 11. Thin Liquid Film Hydrodynamics;300
6.11.1;11.1 Geometrical Aspects of Thin Liquid Films;303
6.11.2;11.2 Hydrostatics of Thin Liquid Films: The Disjoining Pressure Model;306
6.11.3;11.3 Hydrodynamics of Thin Liquid Films;309
6.11.4;11.4 Summary;319
6.12;CHAPTER 12. Thin Liquid Film Stability;324
6.12.1;12.1 The Body Force Model;324
6.12.2;12.2 The Stability of a Thin Film upon a Solid Surface;329
6.12.3;12.3 Summary;338
6.13;CHAPTER 13. Emulsion and Foam Stability;342
6.13.1;13.1 Experimental Studies of Emulsion Stability;343
6.13.2;13.2 Experimental Studies of Foam Stability;347
6.13.3;13.3 Interfacial Rheology in Enhanced Oil Recovery Processes;351
6.13.4;13.4 Summary;354
6.14;CHAPTER 14. Foam Rheology;358
6.14.1;14.1 Geometrical Models;359
6.14.2;14.2 Kinematics of Spatially-Periodic Foam Media;366
6.14.3;14.3 Foam Dynamics and Rheological Properties;371
6.14.4;14.4 Summary;383
7;PART II: MICROMECHANICAL THEORY OF INTERFACIAL TRANSPORT PROCESSES;388
7.1;CHAPTER 15. A Surface-Excess Theory of Interfacial Transport Processes;390
7.1.1;15.1 The Microscale View of a Fluid Intetface;391
7.1.2;15.2 Philosophy of the Microscale Interfacial Theory;394
7.1.3;15.3 Fictitious, Induced, Nonlocal Coordinate System;400
7.1.4;15.4 Kinematics;407
7.1.5;15.5 Singular Perturbation Analysis;411
7.1.6;15.6 Surface-Excess Properties;420
7.1.7;15.7 Generic Conservation Equations;433
7.1.8;15.8 Constitutive Equations;440
7.1.9;15.9 Summary;441
7.2;CHAPTER 16. Surface-Excess Transport of Momentum;454
7.2.1;16.1 Conservation of Mass and Linear Momentum;455
7.2.2;16.2 Conservation of Angular Momentum;458
7.2.3;16.3 A Constitutive Law for the Surface-Excess Pressure Tensor;460
7.2.4;16.4 A Microscale Example of an Expanding Surfactant-Adsorbed Bubble;469
7.2.5;16.5 Summary;471
7.3;CHAPTER 17. Surface-Excess Transport of Species;480
7.3.1;17.1 Conservation of Species;481
7.3.2;17.2 Derivation of the Surfactant Adsorption Isotherm, the Bulk-Phase Partitioning Relation, - Excess Species Flux Vector;482
7.3.3;17.3 Summary: Interfacial Boundary Conditions for Mass, Momentum and Species Surfactant and Nonmaterial Interfaces;492
7.3.4;17.4 Summary;494
7.4;CHAPTER 18. A Micromechanical Line-Excess Equilibrium Line Tension;498
7.4.1;18.1 Microscale Description;500
7.4.2;18.2 Asymptotic Analysis;504
7.4.3;18.3 Line-Excess Properties;507
7.4.4;18.4 Hydrostatics of a Curved Contact Line;512
7.4.5;18.5 Summary;513
7.5;APPENDIX : A;518
7.5.1;A.1 Basic Tensor Analysis Base Vectors;519
7.5.2;A.2 Polyadic Notation;525
7.5.3;A.3 Differential Operators in Orthogonal Curvilinear Coordinates;527
7.6;APPENDIX: B;530
7.6.1;B.l Surface Geometry in Semi-Orthogonal Curvilinear Coordinates;530
8;BIBLIOGRAPHY;542
9;AUTHOR INDEX;566
10;SUBJECT INDEX;572