Cho Two-Dimensional Optical Spectroscopy

1. Auflage 2010
ISBN: 978-1-4200-8430-6
Verlag: Taylor & Francis
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 385 Seiten

Two-Dimensional Optical Spectroscopy discusses the principles and applications of newly emerging two-dimensional vibrational and optical spectroscopy techniques. It provides a detailed account of basic theory required for an understanding of two-dimensional vibrational and electronic spectroscopy. It also bridges the gap between the formal development of nonlinear optical spectroscopy and the application of the theory to explain experimental results.

Focusing on time-domain spectroscopy, the book presents detailed discussions on the underlying physics and interpretation methods of a variety of two-dimensional optical spectroscopic methods. It illustrates how novel diagrammatic techniques are useful in graphically describing the associated nonlinear optical transition pathways and involved population or coherence evolutions. The author also explains the basics of quantum dynamics and time-dependent perturbation theories that are required in describing nonlinear optical processes.

From the development of the theory to novel applications, this book covers a gamut of topics in this field, including perturbation theory, coherent Raman scattering, pump-probe spectroscopy, photon echo spectroscopy, IR-visible four-wave mixing, and linear and nonlinear optical activity spectroscopy. It shows how to apply the recently developed tools of vibrational and electronic spectroscopy in two dimensions.

Zielgruppe

Graduates, advanced undergraduates, and researchers in chemistry, physics, and biology who are interested in ultrafast spectroscopy and its applications.

Autoren/Hrsg.

Cho, Minhaeng

Fachgebiete

• Naturwissenschaften Physik Elektromagnetismus Optik

Inhaltsverzeichnis

Introduction
Quantum Dynamics
Time Evolution in Hilbert Space
Time-Dependent Perturbation Theory in Hilbert Space
Diagram Representation of the Time-Dependent Perturbation Theory in Hilbert Space
Transition Amplitude and Probability in Hilbert Space
Time Evolution in Liouville Space
Time-Dependent Perturbation Theory in Liouville Space
Transition Probability in Liouville Space and Pathways
Linear Response Spectroscopy
Linear Response Function
System-Bath Interaction and Line Broadening
Rotational Averaging of Tensors
Linear Absorption Spectroscopy
Raman Scattering
Hyper-Raman Scattering
IR-Raman Surface Vibrational Spectroscopy
Raman-IR Surface Vibrational Spectroscopy
Appendix: Nonlinear Polarization and Generated Signal Electric Field
Second-Order Response Spectroscopy
Second-Order Response Function
Three-Level System and Line-Broadening Function
Sum-Frequency Generation
Difference-Frequency Generation
IR–IR-vis Four-Wave Mixing
Third-Order Response Spectroscopy
Third-Order Response Function
Four-Level System and Line-Broadening Function
Short-Time Approximation to the Third-Order Response Function
Third-Order Response Function of a Two-Level System
Pump-Probe Spectroscopy of a Two-Level System
Rephasing Photon Echo Spectroscopy of a Two-Level System
Non-Rephasing Photon Echo Spectroscopy of a Two-Level System
Three-Pulse Photon Echo Peak Shift (PEPS)
Two-Dimensional Pump-Probe Spectroscopy
Introduction to Two-Dimensional Pump-Probe Spectroscopy
Two-Dimensional Pump-Probe Spectrum of 2LS
Two-Dimensional Pump-Probe Spectrum of Anharmonic Oscillator
Two-Dimensional Photon Echo Spectroscopy
Phase and Amplitude Detection of Two-Dimensional Photon Echo Signal Field
Two-Dimensional Photon Echo Spectrum: A Two-Level System
Two-Dimensional Non-Rephasing Spectrum: A Two-Level System
Two-Dimensional Photon Echo Spectrum: An Anharmonic Oscillator
Simple Two-Dimensional Lorentzian Peak Shape
Simple Two-Dimensional Gaussian Peak Shape
Coupled Multi-Chromophore System
Frenkel Hamiltonian in Site Representation
Delocalized Exciton Representation
Delocalized State Energy and Transition Dipole Matrix Element
Transition FFCFs
Exchange-Narrowing Effect on Absorption Spectrum
Measurements of Auto and Cross FFCFs
Exciton Population Transfer
Two-Dimensional Spectroscopy of Coupled Dimers
Model Hamiltonian of a Coupled 2LS Dimer
Delocalized Excited-State Energy Fluctuations and Time-Correlation Functions
Coupled 2LS Dimer: Quantum Beats at Short Time
Coupled 2LS Dimer: Intermediate Time Region
Coupled 2LS Dimer: Population Transfer Effects
Coupled Anharmonic Oscillators: Model Hamiltonian
Coupled Anharmonic Oscillators: Two-Dimensional Photon Echo Spectrum at Short Time
Coupled Anharmonic Oscillators: Degenerate Case
Coupled Anharmonic Oscillators: Population Transfer Effects
Chemical Exchange and Two-Dimensional Spectroscopy
Model System
Chemical Exchange Diagrams: Two-Level System
Chemical Exchange Diagrams: Anharmonic Oscillator
Polarization-Controlled Two-Dimensional Spectroscopy
Parallel Polarization ZZZZ-Echo: Two-Level System
Perpendicular Polarization ZYYZ-Echo: Two-Level System
Difference Two-Dimensional Photon Echo Spectrum: Coupled 2LS Dimer
Parallel Polarization ZZZZ-Echo: Anharmonic Oscillators
Perpendicular Polarization ZYYZ-Echo: Anharmonic Oscillators
Difference Two-Dimensional Echo Spectrum: Coupled Anharmonic Oscillators
Generalized Polarization-Controlled Two-Dimensional Spectroscopy
Determination of the Angle between Any Two Transition Dipole Vectors
Applications of Two-Dimensional Vibrational Spectroscopy
Single Anharmonic Oscillator Systems
Coupled Two-Oscillator Systems
Polypeptide Secondary Structures
Globular Proteins and Membrane-Bound Proteins
Nucleic Acids
Hydrogen-Bonding Dynamics and Chemical Exchange
Solute-Solvent Complexation and Micro-Solvation
Internal Rotation
Transient Two-Dimensional IR Spectroscopy: Protein Folding and Unfolding
Applications of Two-Dimensional Electronic Spectroscopy
Application to Fenna-Matthews-Olson Light-Harvesting Complex
Application to Semiconductors
Two-Dimensional Second-Order Response Spectroscopy
Two-Dimensional Sum-Frequency Generation
Two-Dimensional SFG of Solution Sample
Two-Dimensional SFG of Coupled 2LS Dimer
Two-Dimensional SFG of Coupled Anharmonic Oscillators
Two-Dimensional Difference-Frequency Generation
IR–IR-vis SFG and DFG
Other IIV Four-Wave Mixings
Fifth-Order Raman Scattering
Linear Optical Activity Spectroscopy
Radiation-Matter Interaction Hamiltonian and Polarization
Circular Dichroism and Optical Rotatory Dispersion
Raman Optical Activity
IR-Raman Optical Activity Spectroscopy
Raman-IR Optical Activity Spectroscopy
Nonlinear Optical Activity Spectroscopy
Nonlinear Optical Activity Measurement Methods
Rotational Averaging of Higher-Rank Tensors
Two-Dimensional Optical Activity Pump-Probe: Two-Level System
Two-Dimensional Optical Activity Photon Echo: Two-Level System
Two-Dimensional Optical Activity Photon Echo of Coupled 2LS Dimer
References appear at the end of each chapter.

Über Autor(innen)

Minhaeng Cho is the director of the Center for Multidimensional Spectroscopy at Korea University. A recipient of the Nobel Laureate Signatures Award and Young Scientist Award, Dr. Cho counts theoretical and computational chemistry and experimental ultrafast nonlinear optical spectroscopy among his research interests.