Douglas / Ho Structure and Chemistry of Crystalline Solids

1. Auflage 2007
ISBN: 978-0-387-36687-6
Verlag: Springer US
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 346 Seiten

Understandable by anyone concerned with crystals or solid state properties dependent on structurePresents a general system using simple notation to reveal similarities and differences among crystal structuresMore than 300 selected and prepared figures illustrate structures found in thousands of compounds

Bodie Douglas is Professor Emeritus of Chemistry of the University of Pittsburgh. He has had three editions of an inorganic chemistry textbook and a textbook on symmetry and group theory. He spent a year with the crystallographic group of Sir Gordon Cox at the University of Leeds (England). Shi-Ming Ho retired from Westinghouse Research Laboratory where he worked in materials science. Ideas for the system used for describing structures in this book were part of his doctoral dissertation with Bodie Douglas.

Autoren/Hrsg.

Douglas, Bodie

Ho, Shi-Ming

Inhaltsverzeichnis

1;Preface;5
2;Contents;9
3;Introduction;11
4;Classification of Crystals, Point Groups, and Space Groups;16
4.1;2.1. Seven Crystal Systems and the 14 Bravais Lattices;16
4.2;2.2. Point Groups;17
4.3;2.3. Miller Indices;21
4.4;2.4. Stereographic Projections;22
4.5;2.5. The 32 Crystal Classes;23
4.6;2.6. The 230 Space Groups;24
4.7;2.7. Hermann-Mauguin Notation and Classification;26
4.8;2.8. Representative Designation of Crystals;29
4.9;2.9. Pearson’s Simplified Notation;29
5;Close Packing and the PTOT System;31
5.1;3.1. Close Packing;31
5.2;3.2. T and O Layers (Layers of Interstitial Sites);32
5.3;3.3. Formation of the PTOT Framework;34
5.4;3.4. Notation in the PTOT System;35
5.5;3.5. Major Types of Structures in the PTOT System;36
6;Crystal Structures of the Elements and Some Molecular Crystals;44
6.1;4.1. Noble Gases;44
6.2;4.2. Metals;45
6.3;4.3. The Body-Centered Cubic Structure;53
6.4;4.4. Nonmetals;57
6.5;4.5. Some Molecular Crystal Structures;66
7;Structures Involving P and O Layers;73
7.1;5.1. Cubic Close-Packed Structures;73
7.2;5.2. Hexagonal Close-Packed Structures;82
7.3;5.3. ccp PO Crystal Structures with Partial Filling of Layers;88
7.4;5.4. hcp PO Crystal Structures with Partial Filling of Layers;99
7.5;5.5. Layer Structures (POP);118
8;Crystal Structures Involving P and T Layers;127
8.1;6.1. Cubic Close-Packed PT Structures;127
8.2;6.2. Hexagonal Close-Packed PT Structures;130
8.3;6.3. Structures Involving P and Both T Layers;134
8.4;6.4. Structures of SiC;154
9;Crystal Structures Involving P, T, and O Layers;157
9.1;7.1. Molecular 3 2PTOT (bcc) Crystal Structures;159
9.2;7.2. The 3 2PTOT Crystal Structures of the MX Type;163
9.3;7.3. Complex PTOT Crystal Structures;173
9.4;7.4. POT Crystal Structures;179
10;Structures with Multiple Layers;182
10.1;8.1. Crystal Structures Involving Unusual Combinations of P Layers;182
10.2;8.2. Crystal Structures with Double Layers;186
10.3;8.3. Crystal Structures with Triple Layers (IIP);202
11;Crystal Structures of Some Intermetallic Compounds;205
11.1;9.1. Compounds Involving Only P Layers;209
11.2;9.2. Compounds Involving PTOT Layers;223
11.3;9.3. Compounds Involving Only P and O Layers;233
11.4;9.4. The Laves Phases;236
12;Crystal Structures of Silica and Metal Silicates;243
12.1;10.1. Structures of Silica [ SiO2];243
12.2;10.2. General Patterns of Structures of Silicates;248
12.3;10.3. Crystal Structures of Some Metal Silicates;254
13;Structures of Organic Compouds;289
13.1;11.1. Aliphatic Compounds;289
13.2;11.2. Aromatic Compounds;297
14;Predicting Structures and Assigning Notations;302
14.1;12.1. General Considerations for Solids;302
14.2;12.2. General Features of Close-Packed Structures;304
14.3;12.3. Predicting Structures;305
14.4;12.4. Assignment of Notation for Structures Involving Close Packing;309
14.5;12.5. Summary;313
15;Further Reading;316
16;Polyhedra in Close-Packed Structures;319
16.1;Lattice Types;319
16.2;Polyhedra;319
16.3;Polyhedra in Cubic Close-Packed (ccp) and Hexagonal Close- Packed ( hcp) Structures;323
16.4;Models from Stacking Polyhedra;323
16.5;The CsCl Structure Described in a Close- Packed System;324
16.6;Spacial Relationships in Close-Packed Structures;325
17;Subject Index;327
18;Minerals and Gems;335
19;Formula Index;337