Eyring Advances in High Temperature Chemistry

Volume 2
1. Auflage 2013
ISBN: 978-1-4832-1514-3
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 296 Seiten, Web PDF

Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as well as the studies of the sublimation mechanism of sodium chloride, cadmium sulfide, and gallium arsenide. The temperature and emissivity measurements in the thermal imaging technique, freezing and melting point measurements of metal oxides, and phase studies on binary oxide systems at higher temperatures with a solar furnace are also encompassed. High temperature chemists and solar researchers will find the book invaluable.

Autoren/Hrsg.

Eyring, Leroy

Inhaltsverzeichnis

1;Front Cover;1
2;Advances in High Temperature Chemistry;4
3;Copyright Page;5
4;Table of Contents ;10
5;CONTRIBUTORS;6
6;FOREWORD;8
7;CONTENTS OF VOLUME 1;12
8;Chapter 1. Dissociation Energies and Free Energy Functions of Gaseous Monoxides;14
8.1;I. Introduction;14
8.2;II. The Free Energy Functions;14
8.3;III. Sources and Evaluation of Data;50
8.4;References;87
9;Chapter 2. The Matrix-Isolation Technique Applied to High Temperature Molecules;98
9.1;I. Introduction;98
9.2;II. Experimental Procedures;99
9.3;III. Optical Spectroscopy;100
9.4;IV. Electron-Paramagnetic-Resonance Spectroscopy;111
9.5;V. Orientation of Molecules in Matrices;114
9.6;References;116
10;Chapter 3. Molecular Beams in High Temperature Chemistry;120
10.1;I. Introduction;120
10.2;II. Beam Formation from High Pressures;121
10.3;III. Molecular Beam Techniques;126
10.4;IV. Molecular Beam Applications;133
10.5;References;153
11;Chapter 4. Chemical Research in Streaming Thermal Plasmas;164
11.1;I. Introduction;164
11.2;II. Recent Research;188
11.3;References;211
12;Chapter 5. Studies of the Sublimation Mechanism of Solids;216
12.1;I. Introduction;217
12.2;II. Principles of Vaporization Studies;218
12.3;III. Experimental Considerations;220
12.4;IV. Studies of the Sublimation Mechanism of Sodium Chloride Single Crystals;222
12.5;V. Studies of the Sublimation Mechanism of Cadmium Sulfide Single Crystals;229
12.6;VI. Studies of the Sublimation Mechanism of Gallium Arsenide Single Crystals;234
12.7;VII. Low Energy Electron Diffraction (LEED) Study of the Vaporizing Silver (100) Surface;241
12.8;VIII. Conclusions;244
12.9;References;246
13;Chapter 6. High Temperature Phase Studies with a Solar Furnace;248
13.1;I. Introduction;248
13.2;II. The Nature of a Solar Furnace;249
13.3;III. Temperature and Emissivity Measurement;256
13.4;IV. Freezing Point Determination of High Melting Refractory Oxides;257
13.5;V. Liquidus Curve Measurement;261
13.6;VI. Phase Studies at High Temperatures;263
13.7;VII. Summary and Conclusions;272
13.8;References;273
14;AUTHOR INDEX;276
15;SUBJECT INDEX;291