E-Book, Englisch, 172 Seiten, Web PDF
Graddon / Taube / Maddock An Introduction to Co-Ordination Chemistry
2. Auflage 2017
ISBN: 978-1-4831-8411-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
International Series of Monographs in Inorganic Chemistry
E-Book, Englisch, 172 Seiten, Web PDF
ISBN: 978-1-4831-8411-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
An Introduction to Co-Ordination Chemistry, Second Edition covers the fundamental aspects of co-ordination chemistry. The title is designed to introduce the readers to the basic principles and theories that govern co-ordination chemistry. The text first reviews the history of co-ordination chemistry, and then proceeds to discussing the modern theories of co-ordination chemistry. Next, the selection covers transition metal stereochemistry. Chapter IV talks about the stability of complex salts, while Chapter V deals with the stabilization of oxidation states. The text also covers carbonyls and II-complexes. In the last chapter, the title presents the practical applications of co-ordination chemistry. The book will be of great use to students, researchers, and practitioners of chemistry related disciplines.
Autoren/Hrsg.
Weitere Infos & Material
1;Front Cover;1
2;An Introduction to Co-Ordination Chemistry;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE TO SECOND EDITION;8
6;CHAPTER I. HISTORICAL INTRODUCTION;10
6.1;WERNER'S THEORY;13
6.2;SYSTEMATIC NOMENCLATURE;17
6.3;ISOMERISM;18
6.4;STEREOCHEMISTRY OF 6:CO-ORDINATE COMPOUNDS;23
6.5;STEREOCHEMISTRY OF 4:CO-ORDINATE COMPOUNDS;26
6.6;STEREOCHEMISTRY IN SOLUTION AND IN THE SOLID STATE;31
6.7;FURTHER READING;32
7;CHAPTER II: MODERN THEORIES OF CO-ORDINATION CHEMISTRY;33
7.1;THE OCTET THEORY-EFFECTIVE ATOMIC NUMBER;33
7.2;THE VALENCY-BOND THEORY;35
7.3;PARAMAGNETISM;39
7.4;THE CRYSTAL-FIELD THEORY;47
7.5;THE SIDGWICK-POWELL THEORY;59
7.6;FURTHER READING;63
8;CHAPTER III. TRANSITION METAL STEREOCHEMISTRY;64
8.1;BERYLLIUM, MAGNESIUM AND ALUMINIUM;65
8.2;NICKEL;81
8.3;COBALT;85
8.4;HIGH CO-ORDINATION NUMBERS;89
8.5;METAL-METAL BONDS;91
8.6;FURTHER READING;93
9;CHAPTER IV. THE STABILITY OF COMPLEX SALTS;94
9.1;THE DETERMINATION OF STABILITY CONSTANTS;95
9.2;FACTORS AFFECTING STABILITY CONSTANTS;99
9.3;CHELATION;107
9.4;CHANGE OF CO - ORDINATION NUMBER;115
9.5;FURTHER READING;116
10;CHAPTER V. THE STABILIZATION OF OXIDATION STATES;117
10.1;STANDARD REDUCTION POTENTIALS;117
10.2;UNUSUALLY HIGH OXIDATION STATES;126
10.3;UNUSUALLY LOW OXIDATION STATES;128
10.4;FURTHER READING;129
11;CHAPTER VI. CARBONYLS AND II-COMPLEXES;130
11.1;NITROSYLS;136
11.2;NITROPRUSSIDES AND COMPLEX ACETYLIDES;136
11.3;OLEFIN COMPLEXES;138
11.4;CYCLOPENTADIENYLS AND RELATED COMPOUNDS;139
11.5;FURTHER READING;148
12;CHAPTER VII. SOME PRACTICAL APPLICATIONS;149
12.1;INNER COMPLEXES;150
12.2;SOLVENT EXTRACTION;155
12.3;SEQUESTRATION;158
12.4;PORPHYRINS AND RELATED COMPOUNDS;160
12.5;FURTHER READING;164
13;AUTHOR INDEX;166
14;SUBJECT INDEX;168
