Guyot Polyvinylchloride - 2

Main Lectures Presented at the Second International Symposium on Polyvinylchloride, Lyon-Villeurbanne, France, 5 - 9 July 1976
1. Auflage 2013
ISBN: 978-1-4831-5993-5
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 128 Seiten, Web PDF

Polyvinylchloride - 2 (Lyon - Villeurbanne, 1976) is a collection of lectures presented at the Second International Symposium on Polyvinylchloride, held in Lyon-Villeurbanne, France on July 5-9, 1976. This book is divided into seven chapters and begins with a survey of chemical modifications for improved mechanical properties and thermal stability of polyvinylchloride (PVC), including crosslinking chlorination, graft polymerization, and stabilization. The subsequent chapters examine the solution properties, rheology, processing, and structure of PVC. These topics are followed by discussions of the effect of some defects on static strength and the stress-cracking resistance of rigid PVC, as well as the heat and light stabilization of PVC, particularly the mode of action of stabilizers. The final chapter considers the thermal decomposition and combustion mechanisms of PVC. This book will prove useful to polymer chemists, researchers, and students.

Autoren/Hrsg.

Guyot, A.

Inhaltsverzeichnis

1;Front Cover;1
2;Polyvinylchloride — 2;4
3;Copyright Page;5
4;Table of Contents;6
5;CHAPTER 1. CHEMICAL MODIFICATION OF PVC;8
5.1;ABSTRACT;8
5.2;INTRODUCTION;8
5.3;IMPROVEMENT OF MECHANICAL PROPERTIES;8
5.4;IMPROVEMENT OF THE THERMAL STABILITY;17
5.5;REFERENCE;33
6;CHAPTER 2. CHARACTERISATION OF POLY(VINYLCHLORIDE);38
6.1;INTRODUCTION;38
6.2;STRUCTURE OP THE PVC CHAIN;38
6.3;SOLUTION PROPERTIES AND AGGREGATES;41
6.4;ORDER IN SOLID PVC;42
6.5;POWDER RESIN MORPHOLOGY;45
6.6;CONCLUSION;46
6.7;REFERENCES;46
7;CHAPTER
3. THE RHEOLOGY OF PVC - AN OVERVIEW;50
7.1;INTRODUCTION;50
7.2;MELT VISCOSITY;50
7.3;PARTICULATE FLOW;51
7.4;TRUE MELT FLOW;53
7.5;FLOW BEHAVIOR OF COMPOUNDS;55
7.6;EFFECT OF LUBRICANTS ON FLOW;55
7.7;EFFECT OF PLASTICIZER ON FLOW;60
7.8;REFERENCES;62
8;CHAPTER
4. POLYVINYL CHLORIDE - PROCESSING AND STRUCTURE;66
8.1;1. INTRODUCTION;66
8.2;2. THE MOST IMPORTANT METHODS OF PROCESSING (Tables 4 and 5);69
8.3;3. ATTEMPT TO INTERPRET THE ABNORMAL BEHAVIOUR OF PVC DURING PROCESSING;76
8.4;REFERENCES;82
9;CHAPTER 5. RUPTURE FRAGILE DES PRODUITS EN PVC RIGIDE;84
9.1;ESSAIS STATIQUES DE LONGUE DUREE;90
9.2;ESSAIS DE FATIGUE;91
9.3;FISSURATI0N SOUS C0NTRAINTE (STRESS-CRACKING);93
9.4;CONCLUSIONS;95
9.5;REFERENCES;95
10;CHAPTER 6. THE STABILIZATION OF PVC AGAINST HEAT AND LIGHT;96
10.1;1. INTRODUCTION;96
10.2;2. HEAT STABILIZERS FOR PVC AND THEIR MODE OF ACTION;96
10.3;3. LIGHT STABILIZATION OF PVC;112
10.4;4. REFERENCES;116
11;CHAPTER 7. COMBUSTION OF PVC;118
11.1;Abstract;118
11.2;INTRODUCTION;118
11.3;REFERENCES;129