Imamoglu / Dragutan / Karabulut Metathesis Chemistry

From Nanostructure Design to Synthesis of Advanced Materials
2007
ISBN: 978-1-4020-6091-5
Verlag: Springer Netherlands
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band 243, 508 Seiten

Reihe: NATO Science Series II: Mathematics, Physics and Chemistry

This book presents selected contributions from the NATO-Advanced Study Institute New Frontiers in Metathesis Chemistry: From Nanostructure Design to Sustainable Technologies for Synthesis of Advanced Materials, which was organized in Antalya, Turkey in September 2006. Prominent scientists, young researchers and students, convened for two weeks to debate on the newest trends in olefin metathesis and identify future perspectives in this fascinating field of synthetic organic, organometallic and polymer chemistry with diverse potential applications in materials science and technology. The contributions include plenary lectures, short communications and posters dedicated to this outstanding international scientific meeting on an important scientific event in metathesis chemistry.

Coverage in this volume includes metathesis reactions such as ring-closing metathesis (RCM), enyne metathesis, cross-metathesis (CM), acyclic diene metathesis polymerizafion (ADMET) and ring-opening metathesis polymerization (ROMP), which have a broad diversification towards sustainable technologies with perspectives for industrial applications of a wide range of products.

Table of Contents
Preface. List of Participants.

I. Design of new Generations of Metathesis Catalysts.

New Ruthenium Catalysts for Alkene Metathesis; C. Fischmeister, P.H. Dixneuf.- Synthesis and Activity in Ring-Closing Metathesis of Phosphine and NHC-Containing Ruthenium-Indenylidene (bis)Pyridine Complexes; H. Clavier, S.P. Nolan.- Towards New Generations of Metathesis Metal-Carbene Precatalysts; B. Allaert et al.- Ruthenium-Aryloxide Catalysts for Olefin Metathesis; S. Monfette et al.- Homobimetallic Ruthenium-N-Heterocyclic Carbene Complexes for Olefin Metathesis; X. Sauvage et al.- Phosphine-Free Ewg-Activated Ruthenium Olefin Metathesis Catalysts: Design, Preparation and Applications; K. Grela et al.- Metathesis Catalysts Stability and Decomposition Pathway;.A.V.Nitzovsev et al.- Ruthenium Vinylidene Complexes - an Efficient Class of Homogeneous Metathesis Catalysts; I. Dragutan et al.- Mesoporous Molecular Sieves As Supports for Metathesis Catalysts; H. Balcar and J. Cejka.- "Greener Shade of Ruthenium" New Concepts of Activation, Immobilization and Recovery Of Ruthenium Catalysts for Green Olefin Metathesis; A. Michrowska et al.- Ring Opening Metathesis (ROMP) Activity of Ruthenium-Based Olefin Metathesis Catalyst Coordinated with 1 ,3-Bis(2,6-Diisopropylphenyl)-4,5-Dihydroimidazoline; S. Karabulut and F. Verpoort.-

II. Intricate Organic Synthesis via Metathesis Chemistry.

Recent Applications of Alkene Metathesis for Fine Chemical and Supramolecular System Synthesis; F. Požgan and P. Dixneuf.- The Olefm Metathesis Reactions Combined with Organo-Iron Arene Activation Towards Dendrimers and Polymers; D. Astruc, V. Martinez.- Olefin Metathesis with Ruthenium-Arene Catalysts Bearing N- Heterocyclic Carbene Ligands; L. Delaude and A. Demonceau.- Olefin Metathesis Mediated By:. -Schiff Base Ru-Alkylidenes, -Ru-Alkylidenes Bearing Unsymmetrical NHC Ligands; S. Monsaert et al.- Cross-Metathesis of Vinyl-Substituted Organosilicon Derivatives with Olefins and Dienes in The Presence of Grubbs Catalysts; C. Pietraszuk et al.-

III. Tailored Polymers by Metathesis Polymerization.

From Drug Cocktails to Tissue Engineering: Synthesis of ROMP Polymers for Biological Applications; K.D. Camm and D.E. Fogg.-Precision Polyolefin Structure: Modeling Polyethylene Containing Methyl and Ethyl Branches; G. Rojas, K.B. Wagener.- Modeling Low Density Polyethylene with Precisely Placed Butyl Branches; G. Rojas, K.B. Wagener.- Correlating Precisely Defined Primary Structure with Crystalline Properties In Halogen Containing Polyolefins; E. Boz et al.- Synthesis of New Elastomers with Controlled Structures Based on Alkylene Oxides, Grafted by ROMP; B. Spurcaciu et al.- Investigation of the Microstructure of Metal Catalyzed Cyclopentene Co-Norbornene Polymers by Spectral Methods; S.

Zielgruppe

Scientists, research fellows and practitioners working in nanotechnology, organic catalysis, polymer synthesis, organometallic chemistry, materials science, graduate and undergraduate students involved in metathesis chemistry

Autoren/Hrsg.

Imamoglu, Yavuz

Dragutan, Valerian

Karabulut, Solmaz

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Chemische Verfahrenstechnik
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Polymerwerkstoffe
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere
• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Naturwissenschaften Chemie Physikalische Chemie Elektrochemie, Magnetochemie
• Technische Wissenschaften Technik Allgemein Nanotechnologie
• Naturwissenschaften Physik Quantenphysik

Über Autor(innen)

Yavuz Imamoglu, Hacettepe University, Beytepe, Ankara, Turkey / Valerian Dragutan, Romanian Academy, Bucharest, Romania