Jones / Westenberg / Jennings Ion Association in Proton Transfer Reactions

Use of ESR for the Quantitative Determination of Gas Phase Atom and Radical Concentrations
1. Auflage 2013
ISBN: 978-1-4831-3923-4
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 86 Seiten, Web PDF

Ion Association in Proton Transfer Reactions: Use of ESR for the Quantitative Determination of Gas Phase Atom and Radical Concentrations summarizes the basic information essential for the measurement of both gas phase atoms and free radicals concentration by electron spin resonance (ESR) spectroscopy. Organized into two chapters, this book first explains the ion association in proton transfer reactions, and then characterizes the ion pairs. The second chapter focuses on the specific use of the ESR spectroscopy. This book also details the gas phase species detected by ESR spectroscopy, including each of the spectra, and the intensities of the spectral lines of the various atoms and radicals. The actual measurements made by this instrument are also shown.

Autoren/Hrsg.

Jones, J R

Westenberg, A. A.

Jennings, K. R.

Cundall, R. B.

Inhaltsverzeichnis

1;Front Cover;1
2;Ion Association Inproton Transfer Reactions: Use of Esr for the Quantitative Determination of Gas Phase Atom and Radical Concentrations;4
3;Copyright Page;5
4;Table of Contents;6
5;CHAPTER 1. ION ASSOCIATION IN PROTON TRANSFER REACTIONS;6
5.1;I. INTRODUCTION;7
5.2;II. ION PAIRS;8
5.3;III. PROTON TRANSFER REACTIONS;11
5.4;IV. CONCLUSION;25
5.5;REFERENCES;26
6;CHAPTER 2. USE OF ESR FOR THE QUANTITATIVE DETERMINATION OF GAS PHASE ATOM AND RADICAL CONCENTRATIONS;28
6.1;I. INTTRODUCTION;29
6.2;II. ESR SPECTRA;33
6.3;III. THEORETICAL INTENSITIES;56
6.4;IV. PRACTICAL MEASUREMENTS;70
6.5;REFERENCES;82
7;BIBLIOGRAPHY OF PUBLICATIONS IN WHICH GAS PHASE ESR WAS USED FOR CHEMICAL KINETIC STUDIES;85