Kerker Hydrosols and Rheology

1. Auflage 2014
ISBN: 978-1-4832-7668-7
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 606 Seiten, Web PDF

Colloid and Interface Science, Volume IV: Hydrosols and Rheology is the fourth volume of papers presented at the International Conference on Colloids and Surfaces, held in San Juan, Puerto Rico on June 21-25, 1976. This volume contains 57 chapters and begins with reviews on colloidal dispersions, interacting latex particles, reversible adsorption of hydrosols, and stability of colloidal kaolinite suspensions. The next chapters deal with determination of colloidal stability, the microstructure of latex particles, instrumentation, and analytical methods for rheology measurement. These topics are followed by discussions of polymer adsorption, kinetic aspects of rheology, and measurement of important parameters in adsorption. This text also explores the properties of surface rheological models, the analysis of sedimentation velocity, and the application of hydrodynamic chromatography. The remaining chapters look into the colloid chemical aspects of drilling fluid rheology, the rheology of dilute polymer solutions, colloidal sol flow, and the shear thickening of colloidal dispersions, This book will prove useful to chemical engineers and other related professions who are interested in colloidal dispersion, rheology, and hydrosols.

Autoren/Hrsg.

Kerker, Milton

Inhaltsverzeichnis

1;Front Cover;1
2;Hydrosols and Rheology;4
3;Copyright Page;5
4;Table of Contents;6
5;List of Contributors;12
6;Preface;18
7;CHAPTER 1. MACHINE SIMULATION OF COLLOIDAL DISPERSIONS;20
7.1;I. INTRODUCTION;20
7.2;II. A MODEL SYSTEM;22
7.3;III. COMPARISON OF THE MODEL WITH EXPERIMENT;26
7.4;IV. CONCLUSIONS;30
7.5;V. REFERENCES;31
8;CHAPTER 2. ION-PAIR CORRELATION FUNCTIONS IN ELECTRIC DOUBLE LAYER THEORY;34
8.1;I INTRODUCTION;34
8.2;II ION-PAIR CORRELATION FUNCTION IN THE DIFFUSE LAYER;35
8.3;III. APPLICATION TO TWO ADSORBED IONS;41
8.4;REFERENCES;46
8.5;ACKNOWLEDGMENT;47
9;CHAPTER 3. THE ELECTRICAL DOUBLE LAYER OF .-Al2O3 – ELECTROLYTE
SYSTEM;48
9.1;Abstract;48
9.2;I. INTRODUCTION;49
9.3;II. MATERIALS AND METHOD;49
9.4;III. DATA EVALUATION AND RESULTS;51
9.5;IV. DISCUSSION;57
9.6;V. CONCLUSION;60
9.7;VI. REFERENCES;61
10;CHAPTER 4. THE DIRECT MEASUREMENT OF ELECTROSTATIC SURFACE FORCES;64
10.1;I. SUMMARY;64
10.2;II. INTRODUCTION;64
10.3;III. EXPERIMENTAL;65
10.4;IV. RESULTS;69
10.5;V. DISCUSSION;73
10.6;VI. ACKNOWLEDGEMENTS;75
10.7;VII REFERENCES;75
11;CHAPTER 5. THE DETERMINATION OF THE RADIAL DISTRIBUTION
FUNCTION FOR INTERACTING LATEX PARTICLES;78
11.1;I. SUMMARY;78
11.2;II. INTRODUCTION;78
11.3;III. EXPERIMENTAL;79
11.4;IV. LIGHT SCATTERING THEORY;80
11.5;V. RESULTS;82
11.6;VI. DISCUSSION;88
11.7;VII. REFERENCES;90
12;CHAPTER 6. ROLE OF PHYSICAL INTERACTIONS IN THE REVERSIBLE ADSORPTION OF HYDROSOLS OR GLOBULAR PROTEINS:
APPLICATIONS TO CHROMATOGRAPHIC SEPARATIONS;92
12.1;I. ABSTRACT;92
12.2;II. INTRODUCTION;92
12.3;III. INTERACTION FORCES;94
12.4;IV. RATES OF ADSORPTION AND DESORPTION OF HYDROSOLS;96
12.5;V. RESULTS AND DISCUSSION;97
12.6;VI. SUMMARY
AND CONCLUSIONS;106
12.7;VII. ACKNOWLEDGMENT;107
12.8;VIII. REFERENCES;107
13;CHAPTER 7. THE STRUCTURE CHANGE WITH TEMPERATURE IN THE AQUEOUS SOLUTION OF AN ETHOXYLATED SURFACTANT AND THE STABILITY
OF CARBON BLACK DISPERSIONS;110
13.1;ABSTRACT;110
13.2;I. INTRODUCTION;110
13.3;II. EXPERIMENTAL;111
13.4;III. RESULTS;112
13.5;IV. DISCUSSION;116
13.6;V. ACKNOWLEDGMENT;118
13.7;VI. REFERENCES;118
14;CHAPTER 8. DISPERSIBILITY AND STABILITY OF
CARBON BLACK IN WATER;120
14.1;Abstract;120
14.2;I. INTRODUCTION;120
14.3;II. METHOD TO MEASURE DISPERSIBILITY AND STABILITY;121
14.4;III. EVALUATION OF DISPERSION EQUIPMENT;123
14.5;IV. STABILITY MEASUREMENTS;126
14.6;V. EFFECT OF SURFACTANTS ON DISPERSIBILITY;126
14.7;VI. CONCLUSIONS;128
14.8;Acknowledgement;129
14.9;References;130
15;CHAPTER 9. STABILITY OF COLLOIDAL KAOLINITE SUSPENSIONS IN THE PRESENCE OF
SOLUBLE ORGANIC COMPOUNDS;132
15.1;SUMMARY;132
15.2;I. INTRODUCTION;132
15.3;II. EXPERIMENTAL;133
15.4;III. RESULTS;135
15.5;IV. DISCUSSION;139
15.6;V. REFERENCES;142
16;CHAPTER 10. DIFFERENCES IN COLLOID STABILITY OF BACTERIA, ALGAE AND CLAYS AT IDENTICAL AND DEFINED
SOLUTION CONDITIONS;144
16.1;I. INTRODUCTION;145
16.2;II. MATERIALS AND METHODS;147
16.3;III. RESULTS;149
16.4;IV. DISCUSSION;152
16.5;V. REFERENCES;155
16.6;VI. ACKNOWLEDGEMENTS;156
17;CHAPTER 11. REVERSAL OF CHARGE AND FLOCCULATION OF MICROCRYSTALLINE
CELLULOSE WITH CATIONIC DEXTRANS;158
17.1;I. SYNOPSIS;158
17.2;II. INTRODUCTION;158
17.3;III. EXPERIMENTAL;160
17.4;IV. RESULTS AND DISCUSSION;162
17.5;V. FINAL COMMENTS;172
17.6;VI. CONCLUSIONS;173
17.7;VII. ACKNOWLEDGEMENTS;173
17.8;VIII. REFERENCES;173
18;CHAPTER 12. Comparison of the Adsorption on Hydrous Oxide Surfaces of Aquo Metal ions with that of Inert Complex
Cations;176
18.1;I. SYNOPSIS;176
18.2;II. AMPHOTERIC PROPERTIES OF THE -Me-OH GROUP;176
18.3;III. INTERACTION OF AQUO METAL IONS WITH HYDROUS
OXIDE SURFACES;179
18.4;IV. THE ADSORPTION OF INERT Co-COMPLEXES;182
18.5;V. CONCLUSIONS;186
18.6;VI. REFERENCES;186
19;CHAPTER 13. ELECTRON MICROSCOPE OBSERVATIONS ON
THE GROWTH OF Mg(OH)2 CRYSTALS;188
19.1;I. ABSTRACT;188
19.2;II. INTRODUCTION;188
19.3;III. MATERIALS AND METHODS;190
19.4;IV. RESULTS;191
19.5;V. DISCUSSION;197
19.6;VI. REFERENCES;200
20;CHAPTER 14. MICROSTRUCTURE OF SYNTHETIC LATEX PARTICLES;202
20.1;I. INTRODUCTION;202
20.2;II. EXPERIMENTAL;203
20.3;III. TECHNIQUE EMPLOYED;206
20.4;IV. MORPHOLOGY OF SEEDED LATEX PARTICLES;207
20.5;V. DISCUSSION;212
20.6;VI. ACKNOWLEDGMENTS;214
20.7;VII. REFERENCES;214
21;CHAPTER 15. ELECTROKINETIC STUDIES ON COLLOIDAL AND PRECIPITATED NICKEL
HYDROXIDE;216
21.1;ABSTRACT;216
21.2;I. INTRODUCTION;217
21.3;II. EXPERIMENTAL;217
21.4;III. RESULTS;219
21.5;IV. DISCUSSION;223
21.6;V. REFERENCES;228
22;CHAPTER 16. STUDY OF THE DISSOLUTION AND ELECTROKINETIC
BEHAVIOR OF TRICALCIUM ALUMINATE;230
22.1;ABSTRACT;230
22.2;I. INTRODUCTION;230
22.3;II. EXPERIMENTAL;231
22.4;III. RESULTS AND DISCUSSION;232
22.5;IV. CONCLUSIONS AND REMARKS;241
22.6;V. REFERENCES;242
23;CHAPTER 17. GAPS BETWEEN THE THEORETICAL AND EXPERIMENTAL DETERMINATION OF ZETA (3 )
POTENTIAL;244
23.1;Section A: The Moving Boundary Potential;245
23.2;Section B : The slipping plane, slipping layer and
thickness of the immobilised layer;252
23.3;REFERENCES;257
24;CHAPTER 18. NEW STATE-OF-THE-ART AUTOMATIC MICROELECTROPHORESIS
INSTRUMENTATION;260
24.1;REFERENCES;265
25;CHAPTER 19. ELECTROPHORESIC MOBILITY MEASUREMENTS
BY CONTINUOUS PARTICLE ELECTROPHORESIS;266
25.1;ABSTRACT;266
25.2;I. INTRODUCTION;267
25.3;II. EXPERIMENTAL DETAILS;267
25.4;III. THEORETICAL ASPECTS OF CPE;269
25.5;IV. EXPERIMENTAL RESULTS;272
25.6;V. CONCLUSIONS;276
25.7;VI. REFERENCES;277
26;CHAPTER 20. NON-EQUILIBRIUM THERMODYNAMIC STUDIES OF ELECTRO-KINETIC EFFECTS-X ETHYLENEGLYCOL +
WATER MIXTURES;278
26.1;ABSTRACT;278
26.2;INTRODUCTION;278
26.3;EXPERIMENTAL;279
26.4;RESULTS AND DISCUSSION;282
26.5;Acknowledgement;298
26.6;REFERENCES;298
27;CHAPTER 21. THE ADSORPTION OF THE POTENTIAL DETERMINING ARSENATE
ANION ON OXIDE SURFACES;300
27.1;I. INTRODUCTION;300
27.2;II. ADSORPTION MODEL;303
27.3;III. DISCUSSION;310
27.4;IV. SUMMARY;313
27.5;V. REFERENCES;313
28;CHAPTER 22. X-RAY DIFFRACTION ANALYSIS
OF DIFFERENTLY PREPARED AgI;316
28.1;I. INTRODUCTION;316
28.2;II. EXPERIMENTAL;317
28.3;III. RESULTS AND DISCUSSION;321
28.4;IV. REFERENCES;331
29;CHAPTER 23. CHARACTERIZATION AND OXIDATION OF COLLOIDAL SILVER;334
29.1;II. INTRODUCTION;334
29.2;III. PREPARATION OF COLLOIDAL SILVER;336
29.3;IV. SELECTED PROPERTIES OF COLLOIDAL SILVER;337
29.4;V. OXIDATION RATES OF SILVER SOLS;339
29.5;VI. DISCUSSION AND SUMMARY;344
29.6;VII. REFERENCES;346
30;CHAPTER 24. DYNAMIC INTERACTION IN PARTICLE - BUBBLE
ATTACHMENT IN FLOTATION;350
30.1;ABSTRACT;350
30.2;I. INTRODUCTION;351
30.3;II. DYNAMIC INTERACTION;353
30.4;III. EXPERIMENTAL;353
30.5;IV. RESULTS;354
30.6;V. DISCUSSION;359
30.7;VI. REFERENCES;363
31;CHAPTER 25. FURTHER CONSIDERATIONS ON THE AGING OF POLYDISPERSE
SUSPENSIONS (OSTWALD RIPENING);366
31.1;ABSTRACT;366
31.2;REFERENCES;366
32;CHAPTER 26. SOLUTION OF ORNSTEIN-ZERNIKE EQUATION FOR
WALL-PARTICLE DISTRIBUTION FUNCTION;368
32.1;ABSTRACT;368
33;CHAPTER 27. ELECTROCHEMICAL PROPERTIES OF HOLLOW SPHERES AND
PHOSPHATIDIC ACID VESICLES;370
33.1;ABSTRACT;370
34;CHAPTER 28. THE ROLE OF PARTICLE SIZE AND MOLECULAR WEIGHT ON THE ADSORPTION ON AND FLOCCULATION OF POLYSTYRENE LATEX BY POLY( 1, 2-DIMETHUL- 5-VINYLPYRIDINIUM
BROMIDE);372
34.1;ABSTRACT;372
35;CHAPTER 29. ADSORPTION OF POLY (VINYL ALCOHOL) ON SILICA AT VARIOUS pH
VALUES AND ITS EFFECT ON THE FLOCCULATION OF THE DISPERSION;374
35.1;ABSTRACT;374
36;CHAPTER 30. THE INFLUENCE OF AN EXTERNAL MAGNETIC
FIELD ON THS STABILITY OF A MAGNETIC COLLOID;376
37;CHAPTER 31. THE EFFECTS OF CATIONIC SURFACTANTS ON AQUEOUS
INORGANIC PIGMENT SUSPENSIONS;378
37.1;ABSTRACT;378
38;CHAPTER 32. HETEROCOAGULATION OF AIPHOTERIC LATICES;380
38.1;ABSTRACT;380
39;CHAPTER 33. KINETIC ASPECTS OF ADSORPTION AND FLOCCULATION WITH
CATIONIC POLYMERS;382
39.1;ABSTRACT;382
40;CHAPTER 34. STABILITY IN MIXTURES OF POLYMER COLLOIDS
AND POLYMERS IN A COMMON SOLVENT;384
40.1;ABSTRACT;384
41;CHAPTER 35. POTENTIAL DISTRIBUTIONS IN PHASE-SEPARATED AQUEOUS
POLYMER SOLUTIONS;386
41.1;ABSTRACT;386
42;CHAPTER 36. ELECTROPHORESIS OF HIGHLY CHARGED CYLINDERS IN SALT
SOLUTIONS AND APPLICATION TO DOUBLE STRANDED DNA;388
42.1;ABSTRACT;388
43;CHAPTER 37. STREAMING POTENTIAL OF FINE PORES;390
43.1;ABSTRACT;390
44;CHAPTER 38. RE-DISTRIBUTION OF CHARGES IN SPACE AND DE-IONIZATION
IN PRECIPITATING (POLYELECTROLYTE) COLLOIDS;390
45;CHAPTER 39. LAMINAR OSCILLATING FLOW STREAMING
POTENTIAL MEASUREMENTS (I);392
45.1;ABSTRACT;392
46;CHAPTER 40. SIZES, CONCENTRATIONS, AND ELEGTBORHORETIC MOBILITIC OF SUBMICRO PARTICLES BY THE RESISTIVE PULSE
TECHNIQUE;394
47;CHAPTER 41. BINARY MINERAL FLOTABILITY IN THE PRESENCE OF ARSENIC TRIOXIDE;396
47.1;ABSTRACT;396
48;CHAPTER 42. DIRECT MEASUREMENT OF LONG-RANGE FORCES BETWEEN TWO MICA SURFACES IN AQUEOUS
KNO3 SOLUTIONS;398
49;CHAPTER 43. MASS ANALYSIS OF PARTICLES AND MACROMOLECULES BY
FIELD-FLOW FRACTIONATION;400
49.1;I. INTRODUCTION;400
49.2;II. PRINCIPLES AND THEORY OF FFF;403
49.3;III. SEDIMENTATION FFF;405
49.4;IV. FLOW FFF;409
49.5;V. THERMAL FFF;411
49.6;VI. PROGRAMMED THERMAL FFF;413
49.7;VII. ELECTRICAL FFF;415
49.8;VIII. CONCLUSIONS;416
49.9;IX. ACKNOWLEDGMENT;416
49.10;X. REFERENCES;416
50;CHAPTER 44. EXPERIMENTAL STUDY OF NONLINEAR SURFACE STRESS-DEFORMATION BEHAVIOR WITH THE DEEP CHANNEL SURFACE
VISCOMETER;418
50.1;I. ABSTRACT;418
50.2;II. INTRODUCTION;419
50.3;III. SOLUTION;422
50.4;IV. EXPERIMENTAL TECHNIQUE;428
50.5;V. ANALYSIS OF EXPERIMENTAL DATA;429
50.6;VI. ACKNOWLEDGEMENT;436
50.7;VII. REFERENCES;436
50.8;VIII. VALUES AND DEFINITIONS OF TERMS;437
51;CHAPTER 45. EVALUATION OF SURFACE RHEOLOGICAL MODELS;440
51.1;I. RHEOLOGICAL MODELS FOR AN INTERFACE;440
51.2;II. LINEAR CANAL THEORY;443
51.3;III. DETERMINATION OF SURFACE VISCOSITY;446
51.4;IV. DETERMINATION OF THE COMPLEX VISCOSITY;450
51.5;V. CONCLUSIONS;456
51.6;VI. ACKNOWLEDGEMENT;456
51.7;VII. REFERENCES;457
52;CHAPTER 46. A NEW METHOD FOR THE MEASUREMENT OF SHEAR VISCOELASTICITY AT LIQUID-LIQUID INTERFACES
CONTAINING SURFACTANT AND MACROMOLECULAR FILMS;458
52.1;I. INTRODUCTION;459
52.2;II. THEORY;460
52.3;III. EXPERIMENTAL;469
52.4;IV. RESULTS AND DISCUSSION;471
52.5;V. CONCLUSIONS;479
52.6;VI. REFERENCES;480
53;CHAPTER 47. APPLICATION OF EINSTEIN'S THEORY TO THE FLOW OF CONCENTRATED
SUSPENSIONS;484
53.1;ABSTRACT;484
53.2;I. INTRODUCTION;484
53.3;II. EXTENSION OF EINSTEIN'S ANALYSIS;486
53.4;III. ANALYSIS OF EXPERIMENTAL DATA;486
53.5;IV. DISCUSSION;488
53.6;REFERENCES;490
54;CHAPTER 48. HIGH-INTERNAL-PHASE-RATIO EMULSIONS; PUMPING STUDIES;492
54.1;ABSTRACT;492
54.2;I INTRODUCTION;492
54.3;II EXPERIMENTAL PROCEDURE;492
54.4;III EXPERIMENTAL RESULTS;493
54.5;IV DISCUSSION;501
54.6;REFERENCES CITED;504
55;CHAPTER 49. FLOW INSTABILITIES IN COUETTE FLOW IN NEMATIC LIQUID CRYSTALS;506
55.1;I. INTRODUCTION;506
55.2;II. THEORETICAL BACKGROUND;509
55.3;III. EXPERIMENT;511
55.4;IV. RESULTS;512
55.5;CONCLUSIONS;517
55.6;ACKNOWLEDGEMENTS;517
55.7;REFERENCES;517
56;CHAPTER 50. ANALYSIS OF SEDIMENTATION VELOCITY IN
TERMS OF BINARY PARTICLE INTERACTIONS;520
56.1;Abstract;520
56.2;I. INTRODUCTION;520
56.3;II. BASIC CONCEPTS;521
56.4;III. COMPUTATION OF SEDIMENTATION COEFFICIENTS;529
56.5;IV. REFERENCES;531
57;CHAPTER 51. A SEDIMENTATION STUDY OF POLYMERIC COLLOIDS
IN NONAQUEOUS SOLVENTS;532
57.1;I. INTRODUCTION;532
57.2;II. EXPERIMENTAL PROCEDURES;533
57.3;III. RESULTS OF THE SEDIMENTATION STUDIES;539
57.4;IV. ACKNOWLEDGMENTS;545
57.5;V. REFERENCES;546
58;CHAPTER 52. THE EFFECT OF THE ADDITION OF A WATER SOLUBLE POLYMER ON THE
ELASTICITY OF POLYMER LATEX GELS;548
58.1;ABSTRACT;548
58.2;I. INTRODUCTION;548
58.3;II. THEORETICAL;549
58.4;III. EXPERIMENTAL;558
58.5;IV. RESULTS AND DISCUSSION;562
58.6;REFERENCES;565
59;CHAPTER 53. HYDRODYNAMIC CHROMATOGRAPHY OF LATEX PARTICLES;568
59.1;ABSTRACT;568
59.2;I. INTRODUCTION;568
59.3;II. DESCRIPTION OF HDC;569
59.4;III. FLOW-SEPARATION TECHNIQUE;570
59.5;IV. APPLICATION OF HDC AND LEC TO LATEXES;579
59.6;V. ACKNOWLEDGMENTS;580
59.7;VI. REFERENCES;580
60;CHAPTER 54. COLLOID CHEMICAL ASPECTS OF DRILLING FLUID RHEOLOGY;582
60.1;I. ABSTRACT;582
60.2;II. INTRODUCTION;582
60.3;III. HYDRODYNAMICS;584
60.4;IV. COLLOID STABILITY EFFECTS;585
60.5;V. CLAY SUSPENSIONS;594
60.6;VI. POLYMER FLUIDS;596
60.7;VII. SUMMATION;597
60.8;VIII. REFERENCES;598
61;CHAPTER 55. RHEOLOGY OF DILUTE POLYMER SOLUTIONS IN POROUS MEDIA;602
61.1;ABSTRACT;602
62;CHAPTER 56. PARTICLE INTERACTION IN COLLOIDAL SOL FLOW;604
62.1;ABSTRACT;604
63;CHAPTER 57. SHEAR THICKENING IN DILUTE SOLUTIONS OF POLYMERS AND
COLLOIDAL DISPERSIONS;606
63.1;ABSTRACT;606