Krylov / Loebl Catalysis by Nonmetals

Rules for Catalyst Selection
1. Auflage 2013
ISBN: 978-1-4831-9175-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 296 Seiten, Web PDF

Catalysis by Non-metals: Rules of Catalyst Selection presents the development of scientific principles for the collection of catalysts. It discusses the investigation of the mechanism of chemosorption and catalysis. It addresses a series of properties of solid with catalytic activity. Some of the topics covered in the book are the properties of a solid and catalytic activity in oxidation-reduction reactions; the difference of electronegativities and the effective charges of atoms; the role of d-electrons in the catalytic properties of a solid; the color of solids; and proton-acid and proton-base properties of a surface. The catalytic activity and structure of solids are covered. The type of crystal lattice and crystalline lattice parameters are discussed. The text describes the decomposition of alcohols. A study of the dehydrogenation and hydrogenation reactions is presented. A chapter is devoted to the decomposition of inorganic hydrides. Another section focuses on the hydrogen-deuterium exchange and other simple reactions. The book can provide useful information to scientists, physicists, students, and researchers.

Autoren/Hrsg.

Krylov, Oleg V.

Loebl, Ernest M.

Inhaltsverzeichnis

1;Front Cover;1
2;Catalysis by Nonmetals: Rules for Catalyst Selection;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;10
6;Catalysis by Nonmetals;12
7;PART I: GENERAL METHODS OF CATALYST SELECTION
;14
7.1;Introduction;16
7.2;Chapter 1. Properties of a Solid and Catalytic Activity in Oxidation-Reduction Reactions;19
7.2.1;1.1. ELECTROCONDUCTIVITY;19
7.2.2;1.2. WORK FUNCTION;28
7.2.3;1.3. WIDTH OF THE FORBIDDEN ZONE;34
7.2.4;1.4. DOPED LEVELS;49
7.2.5;1.5. THE DIFFERENCE OF ELECTRONEGATIVITIES AND THE EFFECTIVE CHARGES OF ATOMS;53
7.2.6;1.6. THE ROLE OF d-ELECTRONS IN THE CATALYTIC PROPERTIES OF A SOLID;60
7.2.7;1.7. THE COLOR OF SOLIDS;79
7.3;Chapter 2. Solid Properties and Catalytic Activity in Acid-Base Reactions;83
7.3.1;2.1. PROTON-ACID AND -BASE PROPERTIES OF A SURFACE;83
7.3.2;2.2. COORDINATION CAPACITY OF METALS;94
7.3.3;2.3. DIELECTRIC CONSTANT;102
7.4;Chapter 3. Catalytic Activity and Structure of Solids;106
7.4.1;3.1. CRYSTALLINE LATTICE PARAMETER;106
7.4.2;3.2. TYPE OF CRYSTAL LATTICE;116
8;PART II: PRINCIPLES OF SELECTION OF CATALYSTS FOR VARIOUS REACTIONS;124
8.1;Introduction;126
8.2;Chapter 4. Decomposition of Alcohols and Acids;128
8.2.1;4.1. DECOMPOSITION OF ALCOHOLS;128
8.2.2;4.2. DECOMPOSITION OF ACIDS;147
8.3;Chapter 5. Dehydrogenation and Hydrogenation Reactions;153
8.3.1;5.1. DEHYDROGENATION OF HYDROCARBONS;153
8.3.2;5.2. HYDROGENATION;161
8.3.3;5.3. DECOMPOSITION OF INORGANIC HYDRIDES;165
8.4;Chapter 6. Hydrogen–Deuterium Exchange and Other Simple

Reactions;170
8.5;Chapter 7. Reactions of Oxidation and Decomposition of Oxygen-Containing Compounds;181
8.5.1;7.1. SIMPLE OXIDATION REACTIONS;181
8.5.2;7.2. OXIDATION OF ORGANIC COMPOUNDS;191
8.5.3;7.3. THE DECOMPOSITION OF OXYGEN-CONTAINING SUBSTANCES;198
8.6;Chapter 8. Acid–Base Reactions;211
8.6.1;8.1. ADDITION AND REMOVAL OF WATER AND HYDROGEN HALIDES;211
8.6.2;8 .2. THE REACTIONS OF CONDENSATION AND POLYCONDENSATION;220
8.6.3;8.3. ISOMERIZATION REACTIONS;225
8.6.4;8.4. CRACKING AND ALKYLATION OF HYDROCARBONS;228
8.7;Chapter 9. Polymerization Reactions;232
9;Conclusions;253
10;Appendix: Physical Properties of Some Nonmetallic Compounds Used as Catalysts;260
11;References;272
12;Subject Index;292