Majumdar / Belcher / Freiser N-Benzoylphenylhydroxylamine and Its Analogues

1. Auflage 2017
ISBN: 978-1-4832-7863-6
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 222 Seiten, Web PDF

International Series of Monographs in Analytical Chemistry, Volume 50: N-Benzoylphenylhydroxylamine and its Analogues covers the analytical applications of the organic hydroxylamine derivatives. This book is composed of seven chapters, and starts with a brief historical account of the uses of organic reagents in inorganic analysis. The next chapter discusses some basic physico-chemical factors associated with the constitution of a good reagent, including some fundamental ideas about the type and nature of the principal reactive and other groupings in the ligand. A chapter deals with the inclusion of the methods of preparation and properties of N-benzoylphenylhydroxylamine (BPHA) and its analogues and derivatives, and their reactions with different metal ions. These topics are followed by descriptions of the various types of analytical applications of BPHA and its analogues, such as gravimetry, spectrophotometry, and solvent extraction, as well as their applications in titrimetry and paper chromatography. This book is of value to analytical and organic chemists.

Autoren/Hrsg.

Majumdar, A. K.

Belcher, R.

Freiser, H.

Inhaltsverzeichnis

1;Front Cover;1
2;N-Benzoylphenylhydroxylamine and its Analogues
;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;10
6;CHAPTER 1. INTRODUCTION;12
6.1;Organic Reagents in Inorganic Analysis;12
6.2;References;16
7;CHAPTER 2. THE EFFECT OF ATOMIC GROUPINGS AND SUBSTITUENTS ON REAGENTS;18
7.1;Cupferrons;18
7.2;Hydroxytriazenes;21
7.3;Hydroxamic Acids;24
7.4;Hydroxylamines;33
7.5;References;38
8;CHAPTER 3. REPARATION AND PROPERTIES OF N-BENZOYLPHENYLHYDROXYLAMINE AND ITS ANALOGUES;41
8.1;Procedur;41
8.2;Notes;42
8.3;TV-Substituted Phenylhydroxylamines;44
8.4;Procedure for N-nicotinylphenylhydroxylamine;46
8.5;Procedure for N-benzoylnaphthylhydroxylamine;47
8.6;Procedure;51
8.7;Procedure;51
8.8;Procedure;52
8.9;Procedure;53
8.10;Procedure;53
8.11;Procedure;56
8.12;Procedure;57
8.13;Procedure;58
8.14;Procedure;59
8.15;References;63
9;CHAPTER 4. GRAVIMETRIC DETERMINATION OF THE ELEMENTS WITH N-BENZOYLPHENYLHYDROXYLAMINE AND ITS ANALOGUES;65
9.1;1. Applications of N-Benzoylphenylhydroxylamine;66
9.2;2. Applications of N-Cinnamoylphenylhydroxylamine;110
9.3;3. Applications of N-Benzoyl-0-tolylhydroxylamine;111
9.4;4. Application of N-Salicylphenylhydroxylamine;113
9.5;5. Application of N-Acetylsalicylphenylhydroxylamine;113
9.6;6. Applications of Thiobenzoylphenylhydroxylamine;114
9.7;References;116
10;CHAPTER 5. SPECTROPHOTOMETRIC DETERMINATION OF THE ELEMENTS WITH N-BENZOYLPHENYLHYDROXYLAMINE AND ITS ANALOGUES;118
10.1;1. N-Benzoylphenylhydroxylamine as a Spectrophotometric Reagent;120
10.2;2. N-Acetylphenylhydroxylamine as a Spectrophotometric Reagent;145
10.3;3. N-Benzoylmethylhydroxylamine as a Spectrophotometric Reagent;146
10.4;4. N-2-Thiophenecarbonyl-p-tolylhydroxylamineand N-2-Thiophenecarbonylphenylhydroxylamine as Spectrophotometric Reagents;147
10.5;5. N-Cinnamoylphenylhydroxylamine as a Spectrophotometric Reagent;149
10.6;6. N-Benzoyl-p-tolylhydroxylamine as a Spectrophotometric Reagent;152
10.7;7. N-Benzoyl-o-tolylhydroxylamine as a Spectrophotometric Reagent;153
10.8;8. N-Benzoyl-p-chlorophenylhydroxylamine as a Spectrophotometric Reagent;154
10.9;9. N-Benzoyl-o-Tolylhydroxylamine and Other Aromatic Hydroxylamines as Spectrophotometric Reagents;155
10.10;10. N-Furoylphenylhydroxylamine as a Spectrophotometric Reagent;161
10.11;11. N-Acetylsalicylphenylhydroxylamine as a Spectrophotometric Reagent;164
10.12;References;167
11;CHAPTER 6. SEPARATION OF ELEMENTS BY SOLVENT EXTRACTION WITH N-BENZOYLPHENYLHYDROXYLAMINE;169
11.1;Procedure;172
11.2;Separation of Scandium from Zirconium or Titanium;174
11.3;Procedure;174
11.4;Procedure;175
11.5;Procedure;175
11.6;Procedure;177
11.7;Procedure;178
11.8;Procedure;180
11.9;Note;182
11.10;Procedure;183
11.11;Procedure;184
11.12;Notes;184
11.13;Separation of Niobium from Protactinium;186
11.14;Separation of Niobium, Tantalum and Protactinium;186
11.15;Separation of Plutonium from Fission Products;188
11.16;Separation of Protactinium-233 from Thorium and Uranium;189
11.17;Procedure;193
11.18;Procedure;194
11.19;Procedure;195
11.20;Separation of Niobium and Zirconium from Uranium;196
11.21;Procedure;202
11.22;References;203
12;CHAPTER 7. TITRIMETRIC AND PAPER CHROMATOGRAPHIC APPLICATIONS OF N-BENZOYLPHENYLHYDROXYLAMINE;204
12.1;Procedure;206
12.2;Effect of Other Ions;206
12.3;Determination of Iron(III);207
12.4;Determination of Copper;207
12.5;Effect of Other Ions;207
12.6;Procedure;208
12.7;Effect of Other Ions;208
12.8;Notes;209
12.9;Procedure;210
12.10;Procedure;212
12.11;Procedure;213
12.12;Procedure;215
12.13;References;215
13;INDEX;218
14;OTHER TITLES IN THE SERIES IN ANALYTICAL CHEMISTRY;222