P¿ibil / Chalmers Applied Complexometry

Pergamon Series in Analytical Chemistry
1. Auflage 2013
ISBN: 978-1-4831-6111-2
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 456 Seiten, Web PDF

Applied Complexometry tackles complexometry from a practical perspective. The book discusses more applications, and theories are reduced to the most important ones. Comprised of 22 chapters, this book deals first with volumetric reagents in complexometry, and then tackles detection of the titration end-point. Chapter 3 covers masking (screening) reagents. Chapter 4 discusses separation methods, and Chapter 5 covers apparatus and solutions. Chapter 6 talks about the classification of EDTA complexes, while Chapter 7 discusses the complexometry anions. Chapter 8 discusses the analytical applications; Chapters 9 to 21 explain the analysis of several materials and solutions, such as alloys, silicates and rocks, cement, ores and concentrates, semiconductors, pigments, and electroplating solutions. The last chapter discusses further applications of complexometry. This book will be of great interest to researchers, especially for chemists whose work involves various chemical techniques such as complexometry.

Autoren/Hrsg.

P¿ibil, Rudolf

Chalmers, Robert A.

Inhaltsverzeichnis

1;Front Cover;1
2;Applied Complexometry;6
3;Copyright Page;7
4;Dedication;8
5;Preface;10
6;Table of Contents;12
7;CHAPTER 1. Volumetric Reagents inComplexometry;20
7.1;1.1 THE PROPERTIES OF EDTA;22
7.2;1.2 THE STABILITY OF EDTA COMPLEXES;24
7.3;1.3 EDTA AS VOLUMETRIC REAGENT;28
7.4;REFERENCES;34
8;CHAPTER 2. Detection of the TitrationEnd-point;35
8.1;2.1 COMPLEXOMETRIC INDICATORS;35
8.2;2.2 INSTRUMENTAL METHODS IN COMPLEXOMETRY;73
8.3;REFERENCES;75
9;CHAPTER 3. Masking (Screening) Reagents;77
9.1;3.1 CLASSIFICATION OF MASKING REAGENTS;78
9.2;3.2 MASKING REAGENTS FOR ALKALINE MEDIA;79
9.3;3.3 MASKING REAGENTS FOR ACID SOLUTIONS;89
9.4;3.4 MASKING BY PRECIPITATION;95
9.5;3.5 CONCLUSIONS;96
9.6;REFERENCES;96
10;CHAPTER 4. Separation Methods;99
10.1;4.1 SEPARATION DURING DISSOLUTION;99
10.2;^+.2 SEPARATION BY PRECIPITATION;100
10.3;4.3 SEPARATION BY ELECTROLYSIS;100
10.4;4.4 SEPARATION ON ION-EXCHANGERS;100
10.5;4-5 SEPARATION BY LIQUID-LIQUID EXTRACTION;101
10.6;REFERENCES;102
11;CHAPTER 5. Apparatus and Solutions;104
11.1;5 .1 GLASS AND PLASTIC WARB;104
11.2;5 .2 REAGENTS;105
11.3;REFERENCES;109
12;CHAFTER 6. Classification of EDTAComplexes;110
12.1;6.1 COMPLEXOMETRY OF GROUP I CATIONS;111
12.2;6.2 COMPLEXOMETRY OF GROUP II CATIONS;166
12.3;6.3 COMPLEXOMETRY OF GROUP III CATIONS;218
13;CHAPTER 7. The Complexometry of Anions;242
13.1;7.1 FLUORIDE;242
13.2;7.2 DETERMINATION OF SULPHATE;246
14;CHAPTER 8. Analytical Applications;257
15;CHAPTER 9. Analysis of Alloys;258
16;9.1 ALUMINIUM AND ALUMINIUM ALLOYS;258
16.1;REFERENCES;269
16.2;9.2 IRON AND ITS ALLOYS;271
16.3;REFERENCES;293
16.4;9·3 LEAD AND LEAD ALLOYS;295
16.5;REFERENCES;306
16.6;9 · ^ COPPER AND COPPER ALLOYS;306
16.7;REFERENCES;315
17;CHAPTER 10. Analysis of Rocks and Minerals;317
17.1;10.1 ANALYSIS OF LIMESTONES, DOLOMITES AN© MAGNESITES;317
17.2;10.2 FLUORSPAR AND CRYOLITE;323
17.3;10.3 ANALYSIS OF PHOSPHATES;327
17.4;10.4 ANALYSIS OF MONAZITES;327
17.5;REFERENCES;329
18;CHAPTER 11. Analysis of Silicates and Rocks;331
18.1;11.1 PARTIAL ANALYSIS OF SILICATES AND ROCKS;333
18.2;REFERENCES;336
19;CHAPTER 12. Analysis of Slags;338
19.1;12.1 DETERMINATION OF INDIVIDUAL COMPONENTS IN SLAGS;338
19.2;REFERENCES;347
20;CHAPTER 13. Analysis of Cements;349
20.1;1 3 . 1 DETERMINATION OF CaO AND MgO;350
20.2;13.2 DETERMINATION OF ALUMINIUM;352
20.3;1 3 . 3 TOTAL ANALYSIS OF CEMENTS;352
20.4;REFERENCES;354
21;CHAPTER 14. Analysis of Glasses;356
21.1;14.1 DETERMINATION OF CALCIUM, MAGNESIUM AND MANGANESE IN GLASSES;356
21.2;14.2 DETERMINATION OF ZIRCONIUM;357
21.3;1 4 . 3 DETERMINATION OF THORIUM [ i o ];358
21.4;14.4 DETERMINATION OF THORIUM, LANTHANUM, BARIUM AND BORON;359
21.5;1 4 . 5 PARTIAL ANALYSES OF GLASSES;360
21.6;REFERENCES;361
22;CHAPTER 15. Analysis of Ores andConcentrates;363
22.1;15.1 LEAD ORES AND CONCENTRATES;363
22.2;15.2 ZINC ORES AND CONCENTRATES;365
22.3;15.3 ZINC-LEAD ORES;367
22.4;15.4 CHROMIUM ORES;370
22.5;15.5 MANGANESE ORES;371
22.6;15.6 ANALYSIS OF COPPER ORES;372
22.7;15.7 DETERMINATION OF Ca AND Mg IN ORES AND CONCENTRATES;374
22.8;REFERENCES;374
23;CHAPTER 16. Analysis of Ferrites;376
23.1;16.1 DISSOLUTION OF FERRITES;376
23.2;16.2 SEPARATION OF IRON;377
23.3;I6.3 ANALYSIS OF INDIVIDUAL FERRITES;378
23.4;16.4 POTENTIOMETRIC ANALYSIS OF FERRITES;381
23.5;REFERENCES;382
24;CHAPTER 17. Analysis of Semiconductors;384
24.1;REFERENCES;385
25;CHAPTER 18. Analysis of Catalysts;387
25.1;REFERENCES;391
26;CHAPTER 19. Analysis of Pigments;393
26.1;REFERENCES;395
27;CHAPTER 20. Analysis of Varnish Driers;396
27.1;REFERENCES;397
28;CHAPTER 21. Analysis of ElectroplatingSolutions;398
28.1;21 .1 ACID BATHS;398
28.2;21.2 ALKALINE BATHS;401
28.3;21 .3 ANALYSIS OF CHROMIUM PLATING SOLUTIONS;407
28.4;21 . ANALYSIS OF SPECIAL PLATING SOLUTIONS;408
28.5;REFERENCES;411
29;CHAPTER 22. Further Applications ofComplexometry;414
29.1;22.1 PHARMACEUTICAL ANALYSIS;414
29.2;22.2 CLINICAL ANALYSIS;415
29.3;22.3 ANALYSIS OF FOODS;415
29.4;REFERENCES;416
30;Index;418