Rieman / Walton / Belcher Ion Exchange in Analytical Chemistry

International Series of Monographs in Analytical Chemistry
1. Auflage 2013
ISBN: 978-1-4831-8651-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 310 Seiten, Web PDF

Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.

Autoren/Hrsg.

Rieman, William

Walton, Harold F.

Belcher, R.

Freiser, H.

Inhaltsverzeichnis

1;Front Cover;1
2;Ion Exchange in Analytical Chemistry;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;14
6;CHAPTER 1. INTRODUCTION;16
6.1;A. History of Ion Exchange;16
6.2;B. Synthesis of Ion-exchange Resins;19
6.3;C. List of Ion-exchange Resins;29
6.4;References;30
7;CHAPTER 2. GENERAL PROPERTIES OF ION-EXCHANGE RESINS;31
7.1;A. Stability;31
7.2;B. Equivalence of Exchange Reactions;35
7.3;C. Reversibility of Ion-exchange Reactions;35
7.4;D. Conversion of the Resin from One Form to Another;35
7.5;E. Titration Curves and Capacity;37
7.6;F. Crosslinking and Swelling;39
7.7;G. Donnan Equilibrium;42
7.8;H. Absorption of Nonelectrolytes;45
7.9;I. Catalysis by Ion-exchange Resins;48
7.10;J. Ion-exchange Resins as Desiccants;48
7.11;References;49
8;CHAPTER 3. ION-EXCHANGE EQUILIBRIUM;51
8.1;A. The Equilibrium Distribution;51
8.2;B. Thermodynamics of Ion Exchange;53
8.3;C. Ionic Selectivity;58
8.4;D. Experimental Methods;66
8.5;References;68
9;CHAPTER 4. ION-EXCHANGE KINETICS;69
9.1;A. The Rate-controlling Step;69
9.2;B. Experimental Methods;69
9.3;C. Conditions that Influence the Rate;73
9.4;References;76
10;CHAPTER 5. NONCHROMATOGRAPHIC APPLICATIONS;78
10.1;A. Preparation, Care, and Use of an Ion-exchange Column;78
10.2;B. Preparation and Purification of Reagents;81
10.3;C. Removal of Interfering Constituents;85
10.4;D. Determination of Total Salt;92
10.5;E. Dissolving Insoluble Salts;94
10.6;F. Concentrating Trace Constituents;97
10.7;References;101
11;CHAPTER 6. THEORY OF ION-EXCHANGE CHROMATOGRAPHY;103
11.1;A. Subdivisions of Ion-exchange Chromatography;103
11.2;B. Importance of Theoretical Considerations;107
11.3;C. Plate Theory of Ion-exchange Elution Chromatography;108
11.4;D. Mass-transfer or Continuous-flow Plate Theory;137
11.5;E. Tracer-pulse and Concentration-pulse Methods;142
11.6;References;146
12;CHAPTER 7. TECHNIQUE OF ION-EXCHANGE CHROMATOGRAPHY;147
12.1;A. Preparation of the Column;147
12.2;B. Performing the Elution;149
12.3;C. Analyzing the Effluent;151
12.4;References;154
13;CHAPTER 8. APPLICATIONS OF ION-EXCHANGE CHROMATOGRAPHY;155
13.1;A. Separation of Inorganic Ions;155
13.2;B. Separation of Organic Compounds;177
13.3;References;187
14;CHAPTER 9. SALTING-OUT CHROMATOGRAPHY AND RELATED METHODS;190
14.1;A. Ion Exclusion;190
14.2;B. Separations by Elution with Water or Dilute Aqueous Buffer Solutions;192
14.3;C. Salting-out Elution Chromatography;193
14.4;D. Elution Chromatography with Mixed Solvents;201
14.5;E. Comparison with Gas-Liquid Chromatography;206
14.6;F. Frontal Liquid-Resin Chromatography;207
14.7;References;210
15;CHAPTER 10. LESS COMMON ION EXCHANGERS;212
15.1;A. Porous Resins;212
15.2;B. Resins with Interpenetrating Polymer Networks;220
15.3;C Ion-retardation Resins;221
15.4;D. Ion-exchange Membranes;223
15.5;E. Inorganic Ion Exchangers;231
15.6;F. Liquid Ion Exchangers;243
15.7;G. Ion-exchange Paper;253
15.8;H. Ion-exchange Materials from Carbohydrates;265
15.9;I. Thin-layer Chromatography;270
15.10;J. Chromatographic Resolution of Racemic Substances;271
15.11;References;275
16;CHAPTER 11. STUDY OF COMPLEX IONS;279
16.1;A. Separation of Kinetically Stable Complexes;279
16.2;B. Measurement of Stability Constants by Ion Exchange;280
16.3;C. Anionic Chloride Complexes;288
16.4;D. Metal-ammonia and Metal-amine Complexes;289
16.5;References;291
17;APPENDIX : LIST OF SYMBOLS;292
18;NAME INDEX;296
19;SUBJECT INDEX;306
20;OTHER TITLES IN THE SERIES IN ANALYTICAL CHEMISTRY;312