Sandler / Karo / Blomquist Organic Functional Group Preparations

1. Auflage 2013
ISBN: 978-1-4832-7555-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 512 Seiten, Web PDF

Organic Functional Group Preparations, Volume III describes 13 organic functional groups and presents a critical review of their available methods of synthesis with preparative examples of each. The book puts special attention to the presentation of specific laboratory directions for the many name reactions used in describing the synthesis of these functional groups. Each chapter deals with the preparation of a given functional group by various reaction types (condensation, elimination, oxidation, reduction) and a variety of starting materials. Acetals and ketals, anhydrides, and thiohydroxamic acids are some of the organic functional groups described in the text. Organic chemists will find the book invaluable.

Wolf Karo was a winner of the Westinghouse Science Talent Search. He holds a number of patents, and has been active in developing applications of monodispersed microspheres in diagnostic testing and other areas of biotechnology. Karo received his Ph.D. in Organic Chemistry from Cornell University.

Autoren/Hrsg.

Sandler, Stanley R.

Karo, Wolf

Blomquist, Alfred T.

Wasserman, Harry

Inhaltsverzeichnis

1;Front Cover;1
2;Organic Functional Group Preparations;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;10
6;Acknowledgments;12
7;Contents of Other Volumes;14
8;Chapter 1. ACETALS AND KETALS;16
8.1;1. Introduction;17
8.2;2. Condensation Reactions;19
8.3;3. Reactions of Acetal and Ketal Compounds;68
8.4;4. Oxidation Reactions;81
8.5;5. Reduction Reactions;83
8.6;6. Miscellaneous Methods;83
8.7;References;85
9;Chapter 2.
ANHYDRIDES;91
9.1;1. Introduction;92
9.2;2. Condensation Reactions;92
9.3;3. Elimination Reactions;110
9.4;4. Reaction of Anhydrides to Give Substituted Anhydrides;119
9.5;5. Miscellaneous Methods;124
9.6;References;125
10;Chapter 3.
MONOALKYL SULFATES;129
10.1;1. Introduction;129
10.2;2. Sulfation of Alcohols;131
10.3;3. Miscellaneous Methods;151
10.4;References;152
11;Chapter 4.
SULFENIC ACIDS AND SULFENIC ACID DERIVATIVES;157
11.1;1. Introduction;157
11.2;2. Sulfenic Acids;158
11.3;3. Sulfenyl Halides;165
11.4;4. Sulfenamides;178
11.5;5. Sulfenates;183
11.6;6. Miscellaneous Methods;188
11.7;References;189
12;Chapter 5. ISONITRILES (ISOCYANIDES);194
12.1;1. Introduction;194
12.2;2. Condensation Reactions;196
12.3;3. Elimination Reactions;203
12.4;4. Miscellaneous Methods;215
12.5;References;216
13;Chapter 6.
AMIDINES;220
13.1;1. Introduction;220
13.2;2. Condensation Reactions;222
13.3;3. Substitution Reactions;232
13.4;4. Miscellaneous Methods;249
13.5;References;252
14;Chapter 7.
IMIDES;256
14.1;1. Introduction;256
14.2;2. Condensation Reactions;260
14.3;3. Miscellaneous Methods;275
14.4;References;279
15;Chapter 8.
IMIDATES;283
15.1;1. Introduction;283
15.2;2. Condensation Reactions;286
15.3;3. Miscellaneous Methods;309
15.4;References;312
16;Chapter 9.
NITRONES;316
16.1;1. Introduction;316
16.2;2. Oxidation Reactions;320
16.3;3. Condensation Reactions;321
16.4;4. Miscellaneous Methods;331
16.5;References;332
17;Chapter 10.
HYDROXYLAMINES AND SUBSTITUTED HYDROXYLAMINES;336
17.1;1. Introduction;337
17.2;2. Condensation Reactions;343
17.3;3. Addition Reactions;367
17.4;4. Oxidation Reactions;368
17.5;5. Reduction Reactions;369
17.6;6. Rearrangement and Thermal Degradation Reactions of Tertiary Amine Oxides and Related Compounds;372
17.7;7. Miscellaneous Methods;373
17.8;References;374
18;Chapter 11.
OXIMES;380
18.1;1. Introduction;381
18.2;2. Condensation Reactions;387
18.3;3. Addition Reactions;403
18.4;4. Oxidation Reactions;403
18.5;5. Reduction Reactions;407
18.6;6. Isomerization Reactions;411
18.7;7. Properties of Oximes;412
18.8;8. Miscellaneous Methods;414
18.9;References;416
19;Chapter 12.
HYDROXAMIC ACIDS;421
19.1;1. Introduction;421
19.2;2. Condensation Reactions;428
19.3;3. Miscellaneous Methods;442
19.4;References;444
20;Chapter 13.
THIOHYDROXAMIC ACIDS;448
20.1;1. Introduction;448
20.2;2. Condensation Reactions;450
20.3;3. Miscellaneous Methods;462
20.4;References;462
21;Author Index;464
22;Name Reaction Index;500
23;Subject Index;501