Sandler / Karo / Wasserman Polymer Syntheses

Organic Chemistry: A Series of Monographs, Vol. 3
1. Auflage 2013
ISBN: 978-1-4832-2008-6
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 382 Seiten, Web PDF

Polymer Syntheses, Volume III provides useful polymer synthesis information. The book discusses the olefin-sulfur dioxide copolymers; the polythioesters; and sulphide polymers. The text also describes polymerizations reactions of mono and diisocyanates; polyoxyalkylation of hydroxyl compounds; and polymerization reactions of N-vinyl carbazole and related monomers. The polymerization of vinyl acetate and other vinyl esters; the polymerization of allyl esters; and the polymerization of vinyl fluoride are also considered. The book further tackles miscellaneous polymer preparations.

Wolf Karo was a winner of the Westinghouse Science Talent Search. He holds a number of patents, and has been active in developing applications of monodispersed microspheres in diagnostic testing and other areas of biotechnology. Karo received his Ph.D. in Organic Chemistry from Cornell University.

Autoren/Hrsg.

Sandler, Stanley R.

Karo, Wolf

Wasserman, Harry H.

Inhaltsverzeichnis

1;Front Cover;1
2;Polymer Syntheses;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;10
6;CONTENTS OF VOLUME I;12
7;CONTENTS OF VOLUME 11;13
8;Chapter 1. OLEFIN-SULFUR DIOXIDE COPOLYMERS
;14
8.1;1. INTRODUCTION;15
8.2;2. CONDITIONS OF COPOLYMERIZATION OF SULFUR

DIOXIDE WITH UNSATURATED COMPOUNDS;15
8.3;3. POLYSULFONES BY THE REACTION OF OLEFINS (LINEAR, CYCLIC, AND BRANCHED) WITH SULFUR

DIOXIDE;19
8.4;4. POLYSULFONES FROM THE REACTION OF DIENES (CONJUGATED AND UNCONJUGATED) WITH

SULFUR DIOXIDE;35
8.5;5. POLYSULFONES BY THE REACTION OF ACETYLENE

WITH SULFUR DIOXIDE;40
8.6;6. POLYSULFONES BY THE REACTION OF VINYL

MONOMERS ( C H 2=CH—R) WITH SULFUR DIOXIDE;44
8.7;7. POLYSULFONES BY THE REACTION OF ALLYLIC

COMPOUNDS WITH SULFUR DIOXIDE;47
8.8;8. MISCELLANEOUS PREPARATIONS AND METHODS;50
8.9;REFERENCES;52
9;Chapter 2. POLYTHIOESTERS;55
9.1;1. INTRODUCTION;55
9.2;2. CONDENSATION OF DIOLEFINS WITH DITHIOCARBOXYLIC ACIDS
;56
9.3;3. FREE RADICAL POLYMERIZATION OF

UNSATURATED THIOESTERS;62
9.4;4. CONDENSATION OF DIMERCAPTANS WITH

DIBASIC ACID DERIVATIVES;70
9.5;5. MISCELLANEOUS PREPARATIONS AND METHODS;79
9.6;REFERENCES;79
10;Chapter 3. SULFIDE POLYMERS;81
10.1;1. INTRODUCTION;82
10.2;2. POLYSULFIDES;82
10.3;3. POLY(ALKYLENE SULFIDES);94
10.4;4. POLY(ARYLENE SULFIDES);111
10.5;5. MISCELLANEOUS PREPARATIONS;118
10.6;REFERENCES;119
11;Chapter 4. POLYMERIZATION REACTIONS OF MONO- AND DIISOCYANATES
;125
11.1;1. INTRODUCTION;125
11.2;2. HOMOPOLYMERIZATION OF MONOISOCYANATES

TO 1-NYLON;127
11.3;3. POLYMERIZATION OF DIISOCYANATES TO GIVE

POLYCAR BODIIMIDES;132
11.4;4. POLY-2-OXAZOLIDONE BY THE REACTION OF

ISOCYANATES WITH EPOXIDES;138
11.5;5. POLYMERIZATION OF POLYISOCYANATES TO POLYISOCYANURATES
;142
11.6;6. MISCELLANEOUS METHODS;147
11.7;REFERENCES;148
12;Chapter 5. PO LYOXYALKYLATI. . OF HYDROXY COMPOUNDS
;151
12.1;1. INTRODUCTION;152
12.2;2. POLYOXYALKYLATION OF ALCOHOLS AND DIOLS;154
12.3;3. POLYOXYALKYLATION OF POLYHYDROXY COMPOUNDS;163
12.4;4. POLYOXYALKYLATION OF PHENOLS;168
12.5;5. MISCELLANEOUS POLYOXYALKYLATION

PREPARATIONS;172
12.6;REFERENCES;172
13;Chapter 6. POLYMERIZATION REACTIONS OF N -VINYL CARBAZOLE AND RELATED MONOMERS
;175
13.1;1. INTRODUCTION TO N

VINYLCARBAZOLE;176
13.2;2. POLYMERIZATION REACTIONS OF N
-VINYLCARBAZOLES;176
13.3;3. N

VINYLAMIDES;183
13.4;4. MISCELLANEOUS PREPARATIONS;187
13.5;REFERENCES;187
14;Chapter 7. POLYMERIZATION OF VINYL ACETATE AND OTHER VINYL ESTERS;191
14.1;1. INTRODUCTION;192
14.2;2. BULK POLYMERIZATIONS;210
14.3;3. SOLUTION POLYMERIZATION;219
14.4;4. SUSPENSION POLYMERIZATION;224
14.5;5. EMULSION POLYMERIZATION;234
14.6;6. NONAQUEOUS DISPERSION POLYMERIZATION;252
14.7;7. RADIATION-INITIATED POLYMERIZATIONS;253
14.8;8. POLYMERIZATIONS INITIATED BY IONIC,

COORDINATION COMPLEXES, AND OTHER MECHANISMS;254
14.9;9. MISCELLANEOUS POLYMERIZATION SYSTEMS;255
14.10;REFERENCES;255
15;Chapter 8. POLYMERIZATION OF ALLYL ESTERS
;261
15.1;1. INTRODUCTION;261
15.2;2. CHAIN TRANSFER IN ALLYL POLYMERIZATIONS;263
15.3;3. CYCLOPOLYMERIZATION OF DIALLYL ESTERS;267
15.4;4. POLYMERIZATION OF ALLYL ACETATE;276
15.5;5. POLYMERIZATION OF ALLYL ESTERS OF HIGHER MONOCARBOXYLIC ACIDS
;281
15.6;6. POLYMERIZATION OF ALLYL ACRYLATE AND

METHACRYLATE;284
15.7;7. POLYMERIZATION OF DIALLYL CARBONATES;289
15.8;8. POLYMERIZATION OF DIALLYL ESTERS OFPHTHALIC ACIDS;293
15.9;9. POLYMERIZATION OF ALLYL ESTERS OF OTHER

POLYFUNOTIONAL ACIDS;300
15.10;10. MISCELLANEOUS PREPARATIONS AND INFORMATION;304
15.11;REFERENCES;304
16;Chapter 9. POLYMERIZATION OF VINYLFLUORIDE;308
16.1;1. INTRODUCTION;308
16.2;2. CHEMICALLY INITIATED POLYMERIZATIONS;312
16.3;3. RADIATION-INITIATED POLYMERIZATIONS;324
16.4;4. HEALTH ASPECTS;326
16.5;5. MISCELLANEOUS;326
16.6;REFERENCES;327
17;Chapter 10. MISCELLANEOUS POLYMERPREPARATIONS;330
17.1;1. INTRODUCTION;330
17.2;2. PREPARATION OF MISCELLANEOUS ORGANOMETALLIC AND METAL-CONTAINING POLYMERS
;331
17.3;3. POLY(METAL PHOSPHINATE)S;334
17.4;4. MODIFICATION OF EXISTING POLYMERS;335
17.5;5. MISCELLANEOUS POLYMER-FORMING REACTIONS;340
17.6;REFERENCES;352
18;AUTHOR INDEX;354
19;SUBJECT INDEX;372
20;ORGANIC CHEMISTRYA SERIES OF MONOGRAPHS;382