Shinoda / Nakagawa / Tamamushi Colloidal Surfactants

Some Physicochemical Properties
1. Auflage 2013
ISBN: 978-1-4832-6344-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 320 Seiten, Web PDF

Colloidal Surfactants: Some Physicochemical Properties focuses on the study of surface active agents. This book elaborates the importance of surface active agents in detergency, textile industry, and biological research. The four distinctive features of the substance-moderate maximum concentration of molecularly dispersed species; surface and interfacial depression in very dilute solution; micelle formation above a certain concentration; and solubilization of water-insoluble substances by micelles, are also described. Other topics include the effect of molecular type on the critical micelle concentration, critical micelle concentration, interaction of paraffin chain electrolytes with colloids, and monolayer studies of surface active agents. This publication is suitable for chemists and specialists researching on colloidal surfactants.

Autoren/Hrsg.

Shinoda, Kozo

Nakagawa, Toshio

Tamamushi, Bun-Ichi

Loebl, Ernest M.

Inhaltsverzeichnis

1;Front Cover;1
2;Colloidal Surfactants: Some Physicochemical Properties;4
3;Copyright Page;5
4;Table of Contents;8
5;PREFACE;6
6;CHAPTER ONE. THE FORMATION OF MICELLES;12
6.1;I. An Outline of the Behavior of Surface Active Agents in Solution;12
6.2;II. Methods of Measuring the Critical Micelle Concentration;20
6.3;III. The Size and Shape of Micelles;27
6.4;IV. The Theory of Micelle Formation;36
6.5;V. The Effect of Molecular Type on the Critical Micelle Concentration (219);53
6.6;VI. The Effects of Additives and Salts on the Critical Micelle Concentration;69
6.7;VII. Surface Activity;90
6.8;VIII. The Formation of Micelles in Nonaqueous Solution;91
6.9;References;99
7;CHAPTER TWO. PHYSICOCHEMICAL STUDIES IN AQUEOUS SOLUTIONS OF NONIONIC SURFACE ACTIVE AGENTS;108
7.1;I. Introduction;108
7.2;II. Critical Micelle Concentration;109
7.3;III. Micellar Weight;123
7.4;IV. Temperature Dependence of Critical Micelle Concentration and Micellar Weight;132
7.5;V. Clouding;140
7.6;VI. Interaction with Other Substances;146
7.7;VII. Other Physicochemical Properties;171
7.8;VIII. Purification and Chromatography;174
7.9;IX. Analysis;184
7.10;References;186
8;CHAPTER THREE. ADSORPTION;190
8.1;I. Introduction;190
8.2;II. Adsorption at the Solution-Air and Solution-Oil Interfaces;192
8.3;III. Adsorption at the Solution-Mercury Interface;214
8.4;IV. Adsorption at the Solution-Solid Interface;227
8.5;V. Interaction of Paraffin Chain Electrolytes with Colloids;241
8.6;References;257
9;CHAPTER FOUR. MONOMOLECULAR LAYERS;262
9.1;I. Introduction;262
9.2;II. General Aspects of Monolayers;263
9.3;III. Experimental Techniques;266
9.4;IV. Monolayer Studies of Surface Active Agents;270
9.5;V. Surface Activity of Protein;281
9.6;VI. Surface Activity of Synthetic Polymers;285
9.7;VII. Interaction at Interface;292
9.8;VIII. Equation of State of Ionized Monolayers;295
9.9;References;299
10;AUTHOR INDEX;302
11;SUBJECT INDEX;312