Stary / Freiser Chelating Extractants

Equilibrium Constant of Liquid-Liquid Distribution Reactions
1. Auflage 2013
ISBN: 978-1-4831-5801-3
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 240 Seiten, Web PDF

Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part IV: Chelating Extractants is a compilation of liquid-liquid distribution equilibrium constants, with emphasis on extractants that form chelates. This tabulation includes all data published up to the end of 1972 for the major chelating extractants, and the given equilibrium parameters are supplemented by calculations (or recalculations) from experimental results. This monograph consists of 12 chapters and characterizes the homogeneous equilibria involving the acid dissociation of the extractant in the aqueous phase and adduct or mixed ligand complex formation in the organic phase. The information given for each system includes the chemical reactions, the equilibrium constant, the temperature, and the composition of the aqueous and organic phases. Compounds covered include dialkyldithiocarbamic acids (such as diethyldithiocarbamic acid and dibutyldithioarbamic acid), tropolones (beta-isopropyltropolone and gamma-isopropyltropolone), N-acylhydroxylamines, N-nitroso-N-arylhydroxylamines (cupferrons), alpha-dioximes, diarylthiocarbazones (dithizones), 8-hydroxyquinolines, 8-mercaptoquinolines, o-dimercaptobenzenes (toluene-3,4-dithiol), beta-diketones (such as acetylacetone and hexafluoroacetylacetone), 4-acylpyrazol-5-ones, and o-nitrosophenols (1-nitroso-2-naphthol and 2-nitroso-1-naphthol). This book will be of interest to chemists.

Autoren/Hrsg.

Stary, J.

Freiser, H.

Inhaltsverzeichnis

1;Front Cover;1
2;Chelating Extractants, Part IV;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;10
6;How to Use The Tables;12
7;CHAPTER I. DIALKYLDITHIOCARBAMIC ACIDS;14
7.1;1 -Pyrrolidinedithiocarbamic acid;14
7.2;Diethyldithiocarbamic acid;15
7.3;Dibutyldithioarbamic acid ;22
7.4;3-Phenyl-pyrazolinedithiocarbamic acid;25
7.5;5-Phenyl-pyrazolinedithiocarbamic acid;26
7.6;3-Phenyl-5-(2-furyl)-pyrazolinedithiocarbamic acid;27
7.7;3,5-Diphenyl-pyrazolinedithiocarbamic acid;28
8;CHAPTER II. TROPOLONES;29
8.1;Tropolone;29
8.2;ß-Isopropyltropolone;30
8.3;.-lsopropyltropolone;35
9;CHAPTER III. N-ACYLHYDROXYLAMINES;35
9.1;Benzohydroxamic acid;35
9.2;N-Phenylacetylhydroxamic acid;37
9.3;Caprinohydroxamic acid;37
9.4;N-Furoyl-N-phenylhydroxylamine;38
9.5;N-Benzoyl-N-phenylhydroxylamine;38
9.6;N-Phenylacetyl-N-phenylhydroxylamine;44
9.7;N-Cinnamoyl-N-phenylhydroxylamine;44
9.8;N-(o-Trifluoromethyl-benzoyl-N-phenylhydroxylamine;45
9.9;N-(m-Trifluoromethyl)benzoyl-N-phenylhydroxylamine;46
9.10;N-(p-Trifluoromethyl)benzoyl-N-phenylhydroxylamine;46
9.11;N-(3-Trifluoromethyl-5-nitro)benzoyl-N-phenylhydroxylamine;47
10;CHAPTER IV. N-NITROSO-N-ARYLHYDROXYLAMINES (CUPFERRONS);47
10.1;N-Nitroso-N-naphthylhydroxylamine;47
10.2;N-Nitroso-N-phenylhydroxylamine;48
11;CHAPTER V. a-DIOXIMES;51
11.1;Dimethylglyoxime;51
11.2;Ethylmethylglyoxime;54
11.3;1,2-Cyclohexanedionedioxime;55
11.4;1,2-Cycloheptanedionedioxime;57
11.5;a-Furildioxime;58
11.6;a-Benzildioxime;59
12;CHAPTER VI. DIARYLTHIOCARBAZONES (DITHIZONES);60
12.1;Diphenylthiocarbazone;60
12.2;Di-(p-fluorophenyl)-thiocarbazone;71
12.3;Di-(p-chlorophenyl)-thiocarbazone;71
12.4;Di-(o-chlorophenyl)-thiocarbazone;72
12.5;Di-(o-bromophenyl)-thiocarbazone;72
12.6;Di-(p-bromophenyl)-thiocarbazone;72
12.7;Di-(p-iodophenyl)-thiocarbazone;73
12.8;Di-(p-methoxyphenyl)-thiocarbazone;73
12.9;Di-(o-tolyl) -thiocarbazone;74
12.10;Di-(p-tolyl)-thiocarbazone;74
12.11;Di-(m-trifluoromethylphenyl)-thiocarbazone;76
12.12;Di-(2,4-xylyl)-thiocarbazone;76
12.13;Di-(a-naphthyl)-thiocarbazone;76
12.14;Di-(ß-naphthyl)-thiocarbazone;78
12.15;Di-(o-diphenyl)-thiocarbazone;7
13;CHAPTER VII. 8-HYDROXYQUINOLINES;79
13.1;8-Hydroxyquinoline;79
13.2;5,7-Dichloro-8-hydroxyquinoline;95
13.3;5,7-Dibromo-8-hydroxyquinoline;98
13.4;5,7-Diiodo-8-hydroxyquinoline;100
13.5;5-Chloro-7-iodo-8-hydroxyquinoline;101
13.6;2-Methyl-8-hydroxyquinoline;101
13.7;4-Methyl-8-hydroxyquinoline;104
13.8;5-Methyl-8-hydroxyquinoline;106
13.9;5-Acetyl-8-hydroxyquinoline;107
14;CHAPTER VIII. 8-MERCAPTOQUINOLINES;108
14.1;8-Mercaptoquinoline;108
14.2;5-Fluoro-8-mercaptoquinoline;112
14.3;5-Chloro-8-mercaptoquinoline;113
14.4;5-Bromo-8-mercaptoquinoline;114
14.5;5-lodo-8-mercaptoquinoline;115
14.6;2-Methyl-8-mercaptoquinoline;116
14.7;4-Methyl-8-mercaptoquinoline;117
14.8;6-Methyl-8-mercaptoquinoline;117
14.9;7-Methyl-8-mercaptoquinoline;117
14.10;2,4-Dimethyl-8-mercaptoquinoline;118
14.11;4,6-Dimethyl-8-mercaptoquinoline;118
14.12;2-Phenyl-8-mercaptoquinoline;118
15;CHAPTER IX. o-DIMERCAPTOBENZENES;119
15.1;Toluene-3,4-dithioI;119
16;CHAPTER X. ß-DIKETONES;120
16.1;Acetylacetone;120
16.2;Hexafluoroacetylacetone;132
16.3;Trifluoroacetylacetone;134
16.4;Dipropionylmethane;138
16.5;Heptafluorobutyryltrifluoroacetylmethane;139
16.6;Pivaloylacetylmethane;139
16.7;Isovaleroyltrifluoroacetone;141
16.8;2-Thenoylacetone;141
16.9;2-Furoyltrif luoroacetone;142
16.10;2-Thenoyltrif luoroacetone;144
16.11;Diisobutyrylmethane;191
16.12;Benzoylacetone;192
16.13;Benzoyltrif luoroacetone;198
16.14;Heptafluorobutyrylpivaloylmethane;203
16.15;Dipivaloylmethane;204
16.16;2-Naphthoyltrifluoroacetone;205
16.17;Dibenzoylmethane;206
16.18;2-Selenoyltrifluoroacetone;210
16.19;2-Selenoylacetone;211
16.20;2-Thenoyl-2-selenoylmethane;212
16.21;2-Furoyl-2-selenoylmethane;213
16.22;Di-2-selenoylmethane;213
16.23;2-Selenoyl-2-picolinylmethane;214
16.24;2-Selenoyl-nicotinylmethane;214
16.25;2-Selenoyl-isonicotinylmethane;215
16.26;Pyrroyltrifluoroacetone;215
16.27;2-Selenoyl-3-nitrobenzoylmethane;216
16.28;Benzoyl-2-selenoylmethane;216
17;CHAPTER XI. 4-ACYLPYRAZOL-5-ONES;216
17.1;1 -Phenyl-3-methyl-4-acetyl-pyrazol-5-one;216
17.2;1-Phenyl-3-methyl-4-trifluoroacetyl-pyrazol-5-one;219
17.3;1-Phenyl-3-methyl-4-trichloroacetyl-pyrazol-5-one;219
17.4;1-Phenyl-3-methyl-4-chloroacetyl-pyrazol-5-one;220
17.5;1 -Phenyl-3-methyl-4-propionyl-pyrazol-5-one;221
17.6;1-Phenyl-3-methyl-4-ethoxycarbonyl-pyrazol-5-one;222
17.7;1 -Phenyl-3-methyl-4-butyryl-pyrazol-5-one;223
17.8;1 -Phenyl-3-methyl-4-valeryl-pyrazol-5-on;224
17.9;1-Phenyl-3-methyl-4-thenoyl-pyrazol-5-one;225
17.10;1-Phenyl-3-methyl-4-capronyl-pyrazol-5-one;225
17.11;1-Phenyl-3-methyl-4-benzoyl-pyrazol-5-one;227
17.12;1-Phenyl-3-methyl-4-p-bromobenzoyl-pyrazol-5-one;235
17.13;1 -Phenyl-3-methyl-4-capryl-pyrazol-5-one;236
18;CHAPTER XII. o-NITROSOPHENOLS;236
18.1;1 -Nitroso-2-naphthol;236
18.2;2-Nitroso-1-naphthol;239