Suschitzky / Aaa Progress in Heterocyclic Chemistry

A Critical Review of the 1989 Literature Preceded by One Chapter on a Current Heterocyclic Topic
1. Auflage 2013
ISBN: 978-1-4832-8701-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 2, 304 Seiten, Web PDF

Reihe: Progress in Heterocyclic Chemistry

Progress in Heterocyclic Chemistry, Volume 2, reports on important original material abstracted from the 1989 literature of heterocyclic chemistry. The chapters are organized according to ring size and the type of heteroatom contained. The text is supported by clear diagrams, references and a subject index.

Autoren/Hrsg.

Suschitzky, H.

Aaa, E. F. V.

Inhaltsverzeichnis

1;Front Cover;1
2;A Critical Review of the 1989 Literature Preceded by One Chapter on a Current Heterocyclic Topic;4
3;Copyright Page;5
4;Table of Contents;6
5;Foreword;8
6;Advisory Editorial Board Members;9
7;CHAPTER 1. Oxidation of Five-Membered Ring Heterocycles Containing N and S;10
7.1;1.1 INTRODUCTION;10
7.2;1.2 THIAZOLE BASED SYSTEMS;10
7.3;1.3 ISOTHIAZOLE BASED SYSTEMS;20
7.4;1.4 THIADIAZOLE BASED SYSTEMS;21
7.5;1.5 OTHER RING SYSTEMS;23
7.6;1.6 CONCLUSION;25
7.7;1.7 REFERENCES;25
8;CHAPTER 2. Three-Membered Ring Systems;31
8.1;2.2 EPOXIDES;31
8.2;2-3 DIOXIRANES;38
8.3;2.4 AZIRIDINES;38
8.4;2.5 AZIRINES;41
8.5;2.6 DIAZIRINES;41
8.6;2.7 OXAZIRIDINES;42
8.7;2.8 EPISULPfflDES;43
8.8;2.9 References;43
9;CHAPTER 3. Four-Membered Ring Systems;46
9.1;3.1 AZETIDINES, AZETINES AND AZETES;46
9.2;3.2 OXETANES AND THIETANES;47
9.3;3.3 DIOXETANES, DITHIATANES AND SULTONES.;48
9.4;3.4 RINGS CONTAINING BORON, PHOSPHORUS, SILICON OR TITANIUM.;48
9.5;3.5 AZETIDIN-2-ONES;51
9.6;REFERENCES;56
10;CHAPTER 4.1 Five-Membered Ring Systems: Thiophenes & Se & Te Analogs;59
10.1;4.1.1 INTRODUCTION;59
10.2;4.1.2 AROMATICITY AND RADICAL STABILIZATION;59
10.3;4.1.3 RING SUBSTITUTION;61
10.4;4.1.4 THIOPHENE RING FORMATION;63
10.5;4.1.5 RING ANNELATION ON THIOPHENE;67
10.6;4.1.6 THIOPHENES AS INTERMEDIATES;71
10.7;4.1.7 THIOPHENE OLIGOMERS AND POLYMERS;72
10.8;4.1.8 SELENOPHENES AND TELLUROPHENES;73
10.9;4.1.9 REFERENCES;74
11;CHAPTER 4.2 Five-Membered Ring Systems: Pyrroles and Benzo Derivatives;79
11.1;4.2.1 Syntheses Involving Ring Closure;79
11.2;4.2.2. Ring Substitution and Substitutent Group Interconversions;84
11.3;4.2.3 Cycloaddition Reactions;90
11.4;REFERENCES;93
12;CHAPTER 4.3 Five-Membered Ring Systems: Furans and Benzo Derivatives;96
12.1;4.31 INTRODUCTION;96
12.2;4.32 REACTIVITY AT RING ATOMS;96
12.3;4.33 REACTIVITY OF SUBSTITUENTS;100
12.4;4-34 RING SYNTHESIS;101
13;CHAPTER 4.4 Five-Membered Ring Systems: With More Than One N Atom;111
13.1;4.4.1 INTRODUCTION;111
13.2;4 4.2 PYRAZOLES AND RING-FUSED PYRAZOLES;111
13.3;4,4.3 IMIDAZOLES AND FUSED-RING IMIDAZOLES;114
13.4;4.4.4 1,2,3-TRIAZOLES AND RING FUSED 1,2,3-TRIAZOLES;115
13.5;4.4.5 1,2,4-TRIAZOLES AND RING-FUSED 1,2,4-TRIAZOLES;117
13.6;4.4.6 TETRAZOLES AND RING-FUSED TETRAZOLES;120
13.7;4.4.7 AJ METAL COMPLEXES WITH RINGS CONTAINING 2 OR MORE NITROGENS;122
13.8;4.4.8 REFERENCES;124
14;CHAPTER 4.5 Three-Membered Ring Systems: With N & S (Se) Atoms;127
14.1;4.5.1 ISOTHIAZOLES;127
14.2;4.5.2 THIAZOLES;130
14.3;4.5.3 THIADIAZOLES;133
14.4;4,5.4 Selenazoles, Selenadiazoles;138
14.5;References;139
15;CHAPTER 4.6 Five-Membered Ring Systems: With O & S (Se, Te) Atoms;143
15.1;4.6.1 1,3-Dioxoles and Dioxolanes;143
15.2;4.6.2 1,3-DithioIes and Dithiolanes;146
15.3;4.6.3 1,3-Oxathioles and Oxathiolanes;148
15.4;4.6.4 1,2-Dioxolanes;149
15.5;4.6.5 1,2-DithioIes and Dithiolanes;149
15.6;4.6.6 1,2-Oxathiolanes;150
15.7;4.6.7. References;150
16;CHAPTER 4.7 Five-Membered Ring Systems: With O and N Atoms;155
16.1;ISOXAZOLES;155
16.2;OXAZOLES AND BENZOXAZOLES;161
16.3;SYSTEMS CONTAINING THREE HETEROATOMS;168
16.4;REFERENCES;171
17;CHAPTER 5.1 Six-Membered Ring Systems: Pyridine and Benzo Derivatives;175
17.1;5.1.1 SYNTHESIS;175
17.2;5.1.2 REACTIONS;183
17.3;ACKNOWLEDGEMENTS;191
17.4;REFERENCES;191
18;CHAPTER 5.2 Six-Membered Ring Systems: Diazines & Benzo Derivatives;194
18.1;5.2.1 INTRODUCTION;194
18.2;5.2.2 STRUCTURE;194
18.3;5.2.3 PYRIDAZINE, CINNOLINE;195
18.4;5.2.4 PYRIMIDINE, QUINAZOLINE;199
18.5;5.2.5 PYRAZINE, QUINOXALINE, PHENAZINE;205
18.6;REFERENCES;209
19;CHAPTER 5.3 Six-Membered Ring Systems: Triazines, Tetrazines and Fused Ring Polyaza Systems;212
19.1;5.3.1 Synthesis;212
19.2;5.3.2 Reactions;224
19.3;REFERENCES;233
20;CHAPTER 5.4 Six-Membered Ring Systems: With O and/or S Atoms;238
20.1;HETEROGYGLES CONTAINING ONE OXYGEN ATOM;238
20.2;5.4.2. HETEROCYCLES CONTAINING ONE SULPfflJR ATOM;249
20.3;5.4·3 HETEROCYCLES CONTAINING TWO OR MORE OXYGEN ATOMS;251
20.4;5.4.4 HETEROCYCLES CONTAINING TWO OR MORE SULPHUR ATOMS;253
20.5;5.4.5 HETEROCYCLES CONTAINING BOTH OXYGEN AND SOLPHÖR IN THE SAME RING;255
20.6;3.4 REFERENCES;256
21;CHAPTER 6. Seven-Membered Rings;261
21.1;INTRODUCTION;261
21.2;6.1 7-Membered Rings with Nitrogen;262
21.3;6.2 7-Membered Rings with Oxygen;266
21.4;6.3 7-Membered Rings with Heteroatom Combinations;276
21.5;REFERENCES;280
22;CHAPTER 7. Eight-Membered and Larger Rings;286
22.1;7.1 INTRODUCTION;286
22.2;7.2 CARBON-OXYGEN RINGS;287
22.3;T.3 CARBON-NITROGEN RINGS;289
22.4;7.4 CARBON-SULFUR RINGS;290
22.5;7.5 CARBON-OXYGEN-NITROGEN RINGS;290
22.6;7-6 CARBON-SULFUR-NITROGEN RINGS;292
22.7;7.7 CARBON-NITROGEN-OXYGEN-SULFUR RINGS;292
22.8;7.8 CARBON-TIN RINGS;292
22.9;7.9 CARBON-SELENIUM RINGS;292
22.10;7.10 REFERENCES;293
23;SUBJECT INDEX;298