Suschitzky Progress in Heterocyclic Chemistry

A Critical Review of the 1990 Literature Preceded by Two Chapters on Current Heterocyclic Topics
1. Auflage 2013
ISBN: 978-1-4832-8750-8
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 3, 345 Seiten, Web PDF

Reihe: Progress in Heterocyclic Chemistry

Progress in Heterocyclic Chemistry (PHC) Volume 3 reports in 17 articles on new and important developments in heterocyclic chemistry abstracted from the 1990 literature. The material is arranged in a systematic way based on ring size and selected by experts in a particular field. The chapters are preceded by two articles on heterocyclic topics hitherto unreviewed and written by chemists well known for their work in the relevant field.

Autoren/Hrsg.

Suschitzky, H.

Inhaltsverzeichnis

1;Front Cover;1
2;A Critical Review of the 1990 Literature Preceded by Two Chapters on Current Heterocyclic Topics;4
3;Copyright Page;5
4;Table of Contents;6
5;Foreword;8
6;Advisory Editorial Board Members;9
7;CHAPTER 1. Asymmetric Synthesis of Azetidinones;10
7.1;1.1 INTRODUCTION;10
7.2;1.2 ASYMMETRIC AZETIDINONE SYNTHESIS; DEFINITION;11
7.3;1.3 ONE-BOND RING CLOSURE;12
7.4;1.4 [1,2 + 3,4]-TWO-BOND RING CLOSURE;16
7.5;1.5 [2,3 + l,4]-TWO-BOND RING CLOSURE;23
7.6;1.6 SYNTHESES USING TRANSITION METAL COMPLEXES;25
8;CHAPTER 2. Annelation Effects in the Thiophene Series;30
8.1;2.1 INTRODUCTION;30
8.2;2.2 BICYCLIC SYSTEMS;31
8.3;2.3 TRICYCLIC SYSTEMS;35
8.4;ACKNOWLEDGEMENTS;47
8.5;REFERENCES;47
9;CHAPTER 3. Three-Membered Ring Systems;51
9.1;3.1 INTRODUCTION;51
9.2;3.2 EPOXIDES;51
9.3;3.3 DIOXIRANES;61
9.4;3.4 AZIRIDINES;61
9.5;3.5 AZIRINES;63
9.6;3.6 DIAZIRINES;63
9.7;3.7 EPISULFIDES;64
9.8;3.8 REFERENCES;64
10;CHAPTER 4. Four-Membered Ring Systems;67
10.1;4.1 AZETIDINES;67
10.2;4.2 OXETANES AND THIETANES;68
10.3;4.3 DIOXETANES, DITHIATANES AND DIAZATANES;69
10.4;4.4 THIAZETIDINES AND OXAZETIDINE;70
10.5;4.5 RINGS CONTAINING PHOSPHORUS , SILICON OR TITANIUM;71
10.6;4.6 AZETIDIN-2-ONES;72
10.7;REFERENCES;76
11;CHAPTER 5.1. Five-Membered Ring Systems: Thiophenes & Se & Te Analogs;79
11.1;5.1.1 INTRODUCTION;79
11.2;5.1.2 AROMATICITY, CONFORMATION AND STABILIZATION;79
11.3;5.1.3 RING SUBSTITUTION;81
11.4;5.1.4 THIOPHENE RING FORMATION;83
11.5;5.1.5 RING ANNELATION ON THIOPHENE;86
11.6;5.1.6 THIOPHENES AS INTERMEDIATES;89
11.7;5.1.7 THIOPHENE CYCLOPHANES AND POLYMERS;90
11.8;5.1.8 SELENOPHENES AND TELLUROPHENES;92
11.9;5.1.9 BIOLOGICALLY ACTIVE THIOPHENE DERIVATIVES;93
11.10;5.1.10 REFERENCES;93
12;CHAPTER 5.2. Five-Membered Ring Systems: Pyrroles and Benzo Derivatives;99
12.1;5.2.1. Methods for Ring Synthesis;99
12.2;5.2.2. Ring Substitution and Modification Reactions;105
12.3;References;114
13;CHAPTER 5.3. Five-Membered Ring Systems: Furans and Benzo Derivatives;118
13.1;5.31 INTRODUCTION;118
13.2;5.32 REACTIVITY AT RING ATOMS;118
13.3;5.33 REACTIVITY OF SUBSTITUENTS;122
13.4;5.34 RING SYNTHESIS;123
14;CHAPTER 5.4. Five-Membered Ring Systems: With More Than One N Atom;133
14.1;5.4.1 INTRODUCTION;133
14.2;5.4.2 PYRAZOLES AND RING FUSED PYRAZOLES;133
14.3;5.4.3 IMIDAZOLES AND FUSED-RING IMIDAZOLES;135
14.4;5.4.4 1,2,3-TRIAZOLES AND DERIVATIVES;138
14.5;5.4.5 1,2,4-TRIAZOLES AND DERIVATIVES;140
14.6;6.4.6 TETRAZOLES;143
14.7;6.4.7 METAL COMPLEXES OF RINGS CONTAINING TWO OR MORE NITROGENS;144
14.8;6.4.8 REFERENCES;145
15;CHAPTER 5.5. Five-Membered Ring Systems: With N & S (Se) Atoms;148
15.1;5.5.1 ISOTHIAZOLES;148
15.2;5.5.2 THIAZOLES;150
15.3;5.5.3 THIADIAZOLES;155
15.4;5.5.4 SELENAZOLES, SELENADIAZIDES;159
16;CHAPTER 5.6. Five-Membered Ring Systems: With O & S (Se, Te) Atoms;165
16.1;5.6.1 1,3-Dioxoles and Dioxolanes;165
16.2;5.6.2 1,3-Dithioles and Dithiolanes;167
16.3;5.6.3 1,3-Oxathioles and Oxathiolanes;170
16.4;5.6.4 1,2-Dioxolanes;171
16.5;5.6.5 1,2-Dithioles;171
16.6;5.6.6 1,2-Oxathioles and Oxathiolanes;172
16.7;5.6.7 Three Heteroatoms;172
16.8;5.6.8. References;173
17;CHAPTER 5.7. Five-Membered Ring Systems: With O & N Atoms;175
17.1;ISOXAZOLES;175
17.2;OXAZOLES;181
17.3;REFERENCES;191
18;CHAPTER 6.1. Six-Membered Ring Systems: Pyridine and Benzo Derivatives;195
18.1;6.1.1 SYNTHESIS;195
18.2;6.12 REACTIONS;204
18.3;REFERENCES;212
19;CHAPTER 6.2. Six-Membered Ring Systems: Diazines and Benzo Derivatives;214
19.1;6.2.1 INTRODUCTION;214
19.2;6.2.2 STRUCTURE;214
19.3;6.2.3 PYRIDAZINE, CINNOLINE, PHTHALAZINE;215
19.4;6.2.4 PYRIMIDINE, QUINAZOLINE;219
19.5;6.2.5 PYRAZINE, QUINOXALINE;226
19.6;REFERENCES;229
20;CHAPTER 6.3. Six-Membered Ring Systems: Triazines, Tetrazines and Fused Ring Polyaza Systems;232
20.1;6.3.1 SYNTHESIS;232
20.2;632 REACTIONS;247
20.3;REFERENCES;255
21;CHAPTER 6.4. Six-Membered Ring Systems: With O and/or S Atoms;261
21.1;6.4.1 HETEROCYCLES CONTAINING ONE OXYGEN ATOM;261
21.2;6.4.2. HETEROCYCLES CONTAINING ONE SULPHUR ATOM;274
21.3;6.4.3 HETEROCYCLES CONTAINING TWO OR MORE OXYGEN ATOMS;275
21.4;6.4.4. HETEROCYCLES CONTAINING TWO OR MORE SULPHUR ATOMS;277
21.5;6.4.5. HETEROCYCLES CONTAINING BOTH OXYGEN AND SULPHUR IN THE SAME RING;278
21.6;6.4.6 REFERENCES;278
22;CHAPTER 7. Seven-Membered Rings;285
22.1;INTRODUCTION;285
22.2;7.1 7-Me«bered Rings with Nitrogen;286
22.3;7.2 7-Membered Rings with Oxygen;298
22.4;7.3 7-Membered Rings with Sulfur;304
22.5;7-4 7-Membered Rings with Heteroatom Combinations;306
23;CHAPTER 8. Eight-Membered and Larger Rings;328
23.1;8.1 INTRODUCTION;328
23.2;8.2 CARBON-OXYGEN RINGS;329
23.3;8.3 CARBON-NITROGEN RINGS;330
23.4;8.4 CARBON-SULFUR RINGS;333
23.5;8.5 CARBON-OXYGEN-NITROGEN RINGS;333
23.6;8.6 CARBON-OXYGEN-SULFUR RINGS;334
23.7;8.7 CARBON-NITROGEN-SULFUR RINGS;335
23.8;8.10 REFERENCES;335
24;SUBJECT INDEX;340