Tang / Hu Polymer Synthesis Based on Triple-bond Building Blocks

1. Auflage 2018
ISBN: 978-3-319-78042-9
Verlag: Springer International Publishing
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 244 Seiten

Reihe: Topics in Current Chemistry Collections

?The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. 
Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Autoren/Hrsg.

Tang, Ben Zhong

Hu, Rongrong

Inhaltsverzeichnis

1;Contents;6
2;Preface;8
3;Helical Polyacetylenes Induced via Noncovalent Chiral Interactions and Their Applications as Chiral Materials;10
3.1;Abstract;10
3.2;1 Introduction;11
3.3;2 Macromolecular Helicity Induction in Polyacetylenes;12
3.4;3 Memory of Macromolecular Helicity Induced in Polyacetylenes;19
3.5;4 Application of Helical Polyacetylenes as Chiral Materials;27
3.6;5 Conclusion;34
3.7;Acknowledgements;34
3.8;References;34
4;Recent New Methodologies for Acetylenic Polymers with Advanced Functionalities;41
4.1;Abstract;41
4.2;1 Introduction;42
4.3;2 Homopolymerizations;43
4.3.1;2.1 Transition-Metal-Catalyzed Coordination Polymerization;43
4.3.2;2.2 Ring-Opening Alkyne Metathesis Polymerization;44
4.3.3;2.3 Transition-Metal-Free Homopolymerizations;46
4.4;3 Two-Component Polymerizations;49
4.4.1;3.1 Click Polymerization;49
4.4.2;3.2 Polycoupling;57
4.5;4 Multicomponent Polymerizations;60
4.5.1;4.1 Multicomponent One-Pot Polymerizations;61
4.5.2;4.2 Multicomponent Tandem Polymerizations;66
4.5.3;4.3 Sequence-Controlled Multicomponent Polymerization;71
4.6;Conclusions and Perspective;74
4.7;Acknowledgements;74
4.8;References;74
5;Poly(aryleneethynylene)s: Properties, Applications and Synthesis Through Alkyne Metathesis;80
5.1;Abstract;80
5.2;1 Introduction;80
5.3;2 Properties and Applications of PAEs;81
5.3.1;2.1 Structure and Properties;81
5.3.2;2.2 Applications of PAEs;83
5.3.2.1;2.2.1 Optoelectronics;83
5.3.2.2;2.2.2 Porous Materials;88
5.4;3 Synthetic Methods;90
5.4.1;3.1 Cross-Coupling Reactions Versus Alkyne Metathesis;90
5.4.2;3.2 Alkyne Metathesis Catalysts;92
5.4.3;3.3 Recent Alkyne Metathesis Techniques;96
5.4.3.1;3.3.1 Acyclic diyne metathesis polymerization (ADIMET);96
5.4.3.2;3.3.2 Ring-opening alkyne metathesis polymerization (ROAMP);96
5.4.3.3;3.3.3 Combination of Cross-Coupling Reaction with Alkyne Metathesis;97
5.4.3.4;3.3.4 Cyclooligomerization;98
5.5;4 Conclusion;100
5.6;Acknowledgements;100
5.7;References;100
6;Construction of Polyarylenes with Various Structural Features via Bergman Cyclization Polymerization;104
6.1;Abstract;104
6.2;1 Introduction;106
6.3;2 Synthesis of Linear Conjugated Polymers;108
6.3.1;2.1 Linear Conjugated Backbones with Various Side Chains;108
6.3.2;2.2 Grafting Linear Conjugated Polymers onto Carbon Nanomaterials;112
6.4;3 Synthesis of Polymeric Nanoparticles;114
6.5;4 Fabrication of Polymeric Nanomembranes;121
6.6;5 New Challenges;127
6.7;6 Conclusions;129
6.8;Acknowledgements;130
6.9;References;130
7;An Update on Isocyanide-Based Multicomponent Reactions in Polymer Science;134
7.1;Abstract;134
7.2;1 Introduction;134
7.3;2 Monomer Synthesis;136
7.4;3 Passerini Polymerization;141
7.5;4 Ugi Polymerization;144
7.6;5 Architecture Control;148
7.7;6 Sequence-Defined Macromolecules;151
7.8;7 Postpolymerization Modifications;155
7.9;8 Conclusions;159
7.10;References;159
8;Functional Organometallic Poly(arylene ethynylene)s: From Synthesis to Applications;163
8.1;Abstract;163
8.2;1 Introduction;164
8.3;2 Synthesis of Organometallic Poly(arylene ethynylene)s;165
8.3.1;2.1 Group 10 Transition Metals;165
8.3.2;2.2 Groups 8 and 9 Transition Metals;167
8.3.3;2.3 Groups 11 and 12 Transition Metals;168
8.3.4;2.4 Heterobimetallic Polymers;171
8.4;3 Photophysics and Structure--Property Relationships of Polymetallaynes;173
8.4.1;3.1 Extent of pi -Conjugation of the Spacer;174
8.4.2;3.2 Post Functionalization of the Acetylenic Linkage;178
8.4.3;3.3 Effect of Pendant Metal Coordination;179
8.4.4;3.4 Geometry of Polymers;180
8.4.5;3.5 Effect of Metal in the Main Chain;180
8.5;4 New Emerging Applications;181
8.5.1;4.1 Light/Electrical Energy Conversion;182
8.5.1.1;4.1.1 Polymer Light-Emitting Diodes (PLEDs);182
8.5.1.2;4.1.2 Polymer Solar Cells (PSCs);185
8.5.2;4.2 Energy and Magnetic Data Storage;188
8.5.2.1;4.2.1 Organic Cathode Materials in Batteries;188
8.5.2.2;4.2.2 Magnetic Nanoparticles for Data Storage;189
8.6;5 Concluding Remarks and Future Prospects;191
8.7;Acknowledgements;192
8.8;References;192
9;Chemical Tongues and Noses Based upon Conjugated Polymers;196
9.1;Abstract;196
9.2;1 Introduction;197
9.3;2 Water-Soluble and Non-Water-Soluble Conjugated Polymers Useful as Elements in Optical Tongues;200
9.4;3 Applications;201
9.4.1;3.1 General Concepts;201
9.4.2;3.2 Metal Ions;208
9.4.3;3.3 Proteins;216
9.4.4;3.4 Nucleotides and Other Biological Entities;220
9.4.5;3.5 Bacteria;224
9.4.6;3.6 Amines;226
9.4.7;3.7 Volatile Organic Compounds (VOC), Explosives, and Arenes;230
9.4.8;3.8 Other Analytes;238
9.5;4 Conclusions;241
9.6;References;243