Taniguchi / Hara / Senoo High Pressure Liquids and Solutions

1. Auflage 2013
ISBN: 978-1-4832-9051-5
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 216 Seiten, Web PDF

Reihe: Current Japanese Materials Research

Pressure, like temperature, is one of the most important parameters governing the state of matter. Today, high-pressure science and technology is applied to diverse research fields: physics, chemistry, biology, earth and marine sciences, material science and technology, chemical engineering, biotechnology and medicine. Research on liquids and solutions at high pressure is not only important for elucidating the structure of liquids, intermolecular interactions between solutes and solvents and chemical reactions in solutions, but also for providing fundamental numerical data for the design of chemical plants and the development of chemical processes. In particular, high-pressure studies of water and aqueous solutions are closely correlated with research into bioscience and biotechnology.In this volume some of the most important and most recent advances in liquids and solutions at high pressure in Japan are presented.

Autoren/Hrsg.

Taniguchi, Y.

Hara, K.

Senoo, M.

Inhaltsverzeichnis

1;Front Cover;1
2;High Pressure Liquids and Solutions;4
3;Copyright Page ;5
4;Table of Contents;10
5;Foreword;6
6;Preface;8
7;List of Contributors;12
8;Chapter 1. High-pressure solubility of several organic and inorganic solutes in water;16
8.1;1. INTRODUCTION;16
8.2;2. HIGH-PRESSURE VESSELS;17
8.3;3. SOLUBILITY OF ALKYLBENZENES IN WATER;19
8.4;4. SOLUBILITY OF NAPHTHALENE IN WATER;26
8.5;5. SOLUBILITY OF INORGANIC COMPOUNDS IN WATER;28
8.6;REFERENCES;31
9;Chapter 2. Pressure effect on the mobility of ions in heavy and light water;34
9.1;1. INTRODUCTION;34
9.2;2. EXPERIMENTAL PROCEDURE;35
9.3;3. RESULTS AND DISCUSSION;37
9.4;4. CONCLUSIONS;45
9.5;REFERENCES;45
10;Chapter 3. High-pressure multinuclear magnetic resonance studies on the solvent exchange of first-row transition metal(II) ions in acetic acid, ethylenediamine, and nitriles. Effects of the bound ligand, solvent bulkiness, and chelate-ring strain;48
10.1;1. INTRODUCTION;48
10.2;2. EXPERIMENTAL;49
10.3;3. RESULTS AND DISCUSSION;53
10.4;REFERENCES;63
11;Chapter 4. High-pressure high-resolution NMR measurements on liquid solutions;64
11.1;1. INTRODUCTION;64
11.2;2. HIGH-PRESSURE GLASS CELL;65
11.3;3. APPLICATION OF GLASS CELL METHODS TO STUDY THE PRESSURE EFFECTS ON MOLECULAR CONFORMATION AND STRUCTURE;72
11.4;ACKNOWLEDGEMENTS;79
11.5;REFERENCES AND NOTES;79
12;Chapter 5. High-pressure study of the dynamic solvent effect on isomerization rate;82
12.1;1. INTRODUCTION;82
12.2;2. THEORETICAL BACKGROUND;84
12.3;3. INTRAMOLECULAR EXCIMER FORMATION OF "DPP";86
12.4;4. GROUND-STATE ISOMERIZATION OF DODCI";88
12.5;5. BARRIER CROSSING DATA FOR ISOMERIZATION;92
12.6;6. CONCLUDING REMARKS;93
12.7;Acknowledgments;93
12.8;REFERENCES;93
13;Chapter 6. Fluid structure and chemical reactions in low- and medium-density fluids;96
13.1;1. INTRODUCTION;96
13.2;2. OVERVIEW ON THE RELATIONSHIP BETWEEN THE FLUID STRUCTURE AND CHEMICAL EQUILIBRIUM;97
13.3;3. CHEMICAL EQUILIBRIUM IN LOW- AND MEDIUM-DENSITY FLUIDS;98
13.4;4. CHEMICAL KINETICS;104
13.5;5. CRITICAL ANOMALY IN THE CHEMICAL REACTION;106
13.6;6. CONCLUSION;107
13.7;REFERENCES;107
14;Chapter 7. Pressure studies on the phase-transition behavior in phospholipid/anesthetic suspensions;110
14.1;1. INTRODUCTION;110
14.2;2. EXPERIMENTAL PROCEDURE;111
14.3;3. RESULTS;113
14.4;4. DISCUSSION;115
14.5;ACKNOWLEDGEMENT;119
14.6;REFERENCES;120
15;Chapter 8. Pressure denaturation mechanism for proteins;122
15.1;1. INTRODUCTION;122
15.2;2. THERMODYNAMIC PROPERTIES OF PRESSURE DENATURATION;123
15.3;3. SECONDARY STRUCTURE OF PROTEINS;127
15.4;REFERENCES;131
16;Chapter 9. Synthetic applications of amino SNAr reactions under high-pressure ;134
16.1;1. INTRODUCTION;134
16.2;2. CONSECUTIVE SNAr-DEQUATERNIZATION REACTIONS;134
16.3;3. SYNTHESIS OF Ag+ ION-SPECIFIC CROWN ETHERS;138
16.4;4. SYNTHESIS OF DIAZA-18-CROWN-6 THIOETHER;145
16.5;ACKNOWLEDGEMENTS;149
16.6;REFERENCES;149
17;Chapter 10. Thermophysical properties of water and alcohol mixtures;152
17.1;1. INTRODUCTION;152
17.2;2. EXPERIMENTAL PROCEDURE;153
17.3;3. EXPERIMENTAL RESULTS AND QUALITATIVE INTERPRETATION;155
17.4;4. SUMMARY;163
17.5;Acknowledgements;163
17.6;REFERENCES;163
18;Chapter 11. Measurement of the viscoelastic properties of lubricants under high pressure by DAC;164
18.1;1. INTRODUCTION;164
18.2;2. VISCOELASTIC MODEL;165
18.3;3. EXPERIMENTAL INSTRUMENTATION;167
18.4;4. VISCOSITY MEASUREMENT BY THE FALLING-SPHERE TECHNIQUE;169
18.5;5. DENSITY MEASUREMENT BY THE BRILLOUIN SCATTERING TECHNIQUE;173
18.6;6. VISCOELASTIC MEASUREMENT BY STRESS RELAXATION IN RUBIES;173
18.7;7. CONCLUDING REMARKS;181
18.8;REFERENCES;182
19;Chapter 12. Ultrasonic speed in trichloromethane and dichloromethane and their thermodynamic properties under high pressure;184
19.1;1. INTRODUCTION;184
19.2;2. EXPERIMENTAL PROCEDURE;185
19.3;3. RESULTS AND DISCUSSION;186
19.4;4. CONCLUSION;193
19.5;REFERENCES;193
20;Chapter 13. Static relative permittivity of some compressed fluids;196
20.1;1. INTRODUCTION;196
20.2;2. EXPERIMENTAL;198
20.3;3. RESULTS AND DISCUSSION;199
20.4;REFERENCES;211
21;Index;214