Ulman Organic Thin Films and Surfaces: Directions for The Nineties

Directions for the Nineties
1. Auflage 2013
ISBN: 978-1-4832-8889-5
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 20, 392 Seiten, Web PDF

Reihe: Thin Films

Physics of Thin Films has been one of the longest running continuing series in thin film science consisting of 20 volumes since 1963. The series contains some of the highest quality studies of the properties ofvarious thin films materials and systems.In order to be able to reflect the development of todays science and to cover all modern aspects of thin films, the series, beginning with Volume 20, will move beyond the basic physics of thin films. It will address the most important aspects of both inorganic and organic thin films, in both their theoretical as well as technological aspects. Therefore, in order to reflect the modern technology-oriented problems, the title has been slightly modified from Physics of Thin Films to Thin Films.Edited by Abraham Ulman, Organic Thin Films and Surfaces: Directions for the Nineties will be the first volume to link two dynamic areas in the physical sciences--organic thin films and surface science. Contributions from leading experts in the field cover a range of important topics on the processing, characterization, and applications of organic thin films.

Autoren/Hrsg.

Ulman, Abraham

Inhaltsverzeichnis

1;Front Cover;1
2;Organic Thin Films and Surfaces: Directions for the Nineties ;4
3;Copyright Page;5
4;Table of Contents;8
5;Preface;16
6;Contnbutors;18
7;Part
I: Introduction;22
7.1;Chapter 1. Supramolecular Assemblies: Vision and Strategy;24
7.1.1;1.1. Introduction;24
7.1.2;1.2. Efforts to Achieve Well-Defined Organized Molecular Assemblies;27
7.1.3;1.3. Perspective in Supramolecular Engineering;29
7.1.4;References;30
8;Part II: Advanced Materials;32
8.1;Chapter 2. Oriented Growth of Nanocrystalline Particulate Films at Monolayers: A Colloid Chemical Approach to Advanced Materials;34
8.1.1;2.1. Introduction;34
8.1.2;2.2. Experimental Methodologies and Characterizations;35
8.1.3;2.3. Growth of Nanocrystalline Particulate Films;42
8.1.4;2.4. Size Quantization and Bandgap Engineering;44
8.1.5;2.5. Semiconductor Particulate Films;46
8.1.6;2.6. Silver Particulate Films;49
8.1.7;2.7. Organizational Imperative: Molecular Recognition and Epitaxial Growth;52
8.1.8;2.8. Conclusions and Future Directions;60
8.1.9;Acknowledgments;60
8.1.10;References;61
8.2;Chapter 3. Third-Level Self-Assembly and Beyond: Polar Hybrid Superlattices via Postassembly Intercalation into Noncentrosymmetric Multilayer Matrices of Hydrogen Bonded Silanes;64
8.2.1;3.1. Introduction;64
8.2.2;3.2. The Multilayer Matrix;68
8.2.3;3.3. Intercalated Superlattices;71
8.2.4;3.4. Conclusion;85
8.2.5;Acknowledgments;88
8.2.6;References and Notes;88
8.3;Chapter 4. Building Two-Dimensional Polymers by the Langmuir-Blodgett Technique;92
8.3.1;4.1. Introduction;92
8.3.2;4.2. General Properties of Amphiphilic Porphyrins in LB Films;92
8.3.3;4.3. Ionic Network;95
8.3.4;4.4. Two-Dimensional Covalent Polymer;99
8.3.5;4.5. Conclusion;104
8.3.6;Acknowledgments;105
8.3.7;References;105
9;Part III: Surface Modification;106
9.1;Chapter 5. Polymer Surface Modification;108
9.1.1;5.1. Introduction: Polymer Surfaces and Dynamic Interfaces;108
9.1.2;5.2. Polymer Surface Modification;110
9.1.3;5.3. Chemical Modification;112
9.1.4;5.4. Hydroxylation of Polypropylene;114
9.1.5;5.5. Functionalization of Poly(chlorotrifluoroethylene);118
9.1.6;5.6. Dehydrofluorination of Poly(vinylidene fluoride);122
9.1.7;5.7. Indirect Syntheses of Carboxylic Acid-Functionalized Fluoropolymers;123
9.1.8;5.8. Gas Phase Chlorination of Polyethylene;125
9.1.9;5.9. Carbonyl Surface Chemistry of Poly(ether ether ketone);126
9.1.10;5.10. Conclusion;127
9.1.11;Acknowledgments;127
9.1.12;References;127
9.2;Chapter 6. Lithographically Patterned Self-Assembled Films;132
9.2.1;6.1. Introduction;132
9.2.2;6.2. Lithographic Considerations for Ultrathin Films as Imaging and Resist Layers;133
9.2.3;6.3. Deep-UV Photochemistry of Aromatic Hydrocarbon Organosilane Films;135
9.2.4;6.4. Selective Electroless Metallization of Patterned SA Films;140
9.2.5;6.5. Pattern Transfer and Microelectronic Device Fabrication by Means of Selectively Metallized SA Films;148
9.2.6;6.6. Deep-UV Photochemistry of Thiol-Terminal Organosilane Films and Patterned Proteins;151
9.2.7;6.7. Mked Monolayers, Coplanar Molecular Assemblies, and Controlled Wetting;153
9.2.8;6.8. Patterned Amine Surfaces as Reactivity Templates;156
9.2.9;6.9. Selective Cell Adhesion and Outgrowth on Patterned SA Films;158
9.2.10;6.10. Conclusions and Future Areas of Research;161
9.2.11;Acknowledgments;162
9.2.12;References;162
10;Part IV: Recognition at Surfaces;166
10.1;Chapter 7. Langmuir Films of Amphiphilic Alcohols and Surfaces of Polar Crystals as Templates for Ice Nucleation;168
10.1.1;7.1. Introduction;168
10.1.2;7.2. Self-Aggregates of Amphiphilic Alcohols as Templates for Ice Nucleation;169
10.1.3;7.3. Nucleation of Ice Under Monolayers of Aliphatic Alcohols;172
10.1.4;7.4. Nucleation of Ice Under Mked Monolayers of Aliphatic Alcohols;183
10.1.5;7.5. Nucleation of Ice Under Alcohol Monolayers Bearing Amide or Ester Groups in the Hydrocarbon Chain;187
10.1.6;7.6. Induced Nucleation of Ice by Amphiphilic Alcohols Aggregated at the Oil/Water Interface;193
10.1.7;7.7. Induced Nucleation of Ice on Surfaces of Polar Crystals of a-Amino Acids;197
10.1.8;7.8. Conclusion and Outlook;200
10.1.9;Acknowledgments;202
10.1.10;References and Notes;203
10.2;Chapter 8. Ion-Selective Monolayer Membranes Based on Self-Assembling Tetradentate Ligand Monolayers on Gold Electrodes: Nature of the Ionic Selectivity;206
10.2.1;8.1. Introduction;206
10.2.2;8.2. Experiments;208
10.2.3;8.3. Results and Discussion;211
10.2.4;8.4. Conclusions;225
10.2.5;Acknowledgments;226
10.2.6;References and Notes;226
10.3;Chapter 9. Specific Recognition at Functionalized Interfaces: Direct Force Measurements of Biomolecular Interactions;230
10.3.1;9.1. Introduction;230
10.3.2;9.2. Results;232
10.3.3;9.3. Discussion;243
10.3.4;9.4. Conclusion and Implications for Future Bioengineering Materials Technology;244
10.3.5;Acknowledgments;244
10.3.6;References;244
10.4;Chapter 10. Formation of Recognition Patterns by Langmuir-Blodgett Techniques;246
10.4.1;10.1. Introduction;246
10.4.2;10.2. Materials and Methods;249
10.4.3;10.3. Conclusions;257
10.4.4;Acknowledgments;258
10.4.5;References;258
11;Part V: Electronic Properties;260
11.1;Chapter 11. Photoinduced Electron Transfer in Monolayer Assemblies and Its Application to Artificial Photosynthesis and Molecular Devices;262
11.1.1;11.1. Introduction;262
11.1.2;11.2. Construction of Charge Separation Units with LB Films;266
11.1.3;11.3. Photoelectric Conversion Efficiencies in Terms of the Electron Transfer Kinetics;272
11.1.4;11.4. Simulation of the Primary Process by the Use of a Mixed Monolayer with Triad and Antenna Molecules;277
11.1.5;11.5. Construction of Nanodomains in Monolayers by the Use of Phase Separation;279
11.1.6;11.6. Artificial Photosynthesis With Multilayered LB Films;290
11.1.7;11.7. Conclusions;294
11.1.8;Acknowledgments;295
11.1.9;References;295
11.2;Chapter 12. Photoelectric Behavior of Bacteriorhodopsin Thin Films at the Solid /Liquid Interface;302
11.2.1;12.1. Introduction;302
11.2.2;12.2. Photoelectric Response Caused by bR Photocycle;303
11.2.3;12.3. Photoelectric Behavior of bR at Solid/Liquid Interfaces;306
11.2.4;12.4. Device Application for Optical Sensing and Image Processing;310
11.2.5;12.5. Conclusions;313
11.2.6;Acknowledgments;314
11.2.7;References;314
11.3;Chapter 13.
Hole-Burning Spectroscopy of Dye-Doped Langmuir-Blodgett Films;316
11.3.1;13.1. Introduction;316
11.3.2;13.2. Experimental Setup;319
11.3.3;13.3. The Hole Width and Its Temperature Dependence;322
11.3.4;13.4. The Hole as a Spectral Label;329
11.3.5;13.5. Conclusion and Prospects;335
11.3.6;Acknowledgments;336
11.3.7;References;336
12;Part V: Dynamic Processes;338
12.1;Chapter 14. Evaluation of a Transfer Process for Langmuir-Blodgett Films by Means of a Quartz-Crystal Microbalance;340
12.1.1;14.1. Introduction;340
12.1.2;14.2. Quartz-Crystal Microbalances;341
12.1.3;14.3. Vertical Dipping Depositions of LB films on a QCM Plate;342
12.1.4;14.4. Horizontal Lifting Depositions of LB Films on a QCM;344
12.1.5;14.5. Conclusions;351
12.1.6;References;352
12.2;Chapter 15.
Translational Diffusion and Electron Hopping in Monolayers at the Air /Water Interface;354
12.2.1;15.1. Electrochemistry on the Water Surface;354
12.2.2;15.2. Translational Diffusion in Octadecyl Ferrocence Monolayers;357
12.2.3;15.3. Electron Hopping in Langmuir Monolayers;362
12.2.4;15.4. Conclusions;369
12.2.5;Acknowledgments;369
12.2.6;References;369
12.3;Chapter 16.
On-Line Structure Control of Langmuir-Blodgett Films;372
12.3.1;16.1. Introduction;372
12.3.2;16.2. Structural and Compositional Variety of Organic Multilayers;373
12.3.3;16.3. Schematic of the Preparation of Langmuir-Blodgett Films;374
12.3.4;16.4. Structure Control During the Transfer Due to Substrate/Monolayer Interactions;378
12.3.5;16.5. Conclusions;384
12.3.6;Acknowledgments;387
12.3.7;References;387
13;Part VI: Structure;388
13.1;Chapter 17.
Phase Diagrams and Chain Order in Monolayers of Aliphatic Chains;390
13.1.1;171. Phases of Amphilic Monolayers;390
13.1.2;17.2. The Principle of Corresponding States;394
13.1.3;17.3. Unambiguous Tests of the Principle;398
13.1.4;17.4. Refinement of the Principle;401
13.1.5;17.5. Conclusions;405
13.1.6;References;406
14;Subject Index;408