Webb Annual Reports on NMR Spectroscopy

1. Auflage 2009
ISBN: 978-0-12-381433-3
Verlag: Elsevier Science & Techn.
Format: EPUB
Kopierschutz: 6 - ePub Watermark

E-Book, Englisch, 448 Seiten

Nuclear magnetic resonance (NMR) is an analytical tool used by chemists and physicists to study the structure and dynamics of molecules. In recent years, no other technique has gained such significance as NMR spectroscopy. It is used in all branches of science in which precise structural determination is required and in which the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a premier means for the specialist and non-specialist alike to become familiar with new techniques and applications of NMR spectroscopy.
* Provides updates on the latest developments in NMR spectroscopy * Includes comprehensive review articles * Highlights the increasing importance of NMR spectroscopy as a technique for structural determination

Autoren/Hrsg.

Webb, Graham A.

Inhaltsverzeichnis

1;Front cover;1
2;Annual Reports on NMR Spectroscopy Volume 67;5
3;Copyright page;6
4;Contents;7
5;Contributors;10
6;Preface;12
7;Chapter 1. Relativistic Computations of NMR Parameters from First Principles: Theory and Applications;14
7.1;1. Introduction;15
7.2;2. Relativistic Methods for NMR Computations;17
7.3;3. Benchmark Data and Case Studies;45
7.4;4. Concluding Remarks;100
7.5;Acknowledgments;100
7.6;References;100
8;Chapter 2. Applications of Silicon-Carbon Coupling Constants;110
8.1;1. Experimental Methods;111
8.2;2. Couplings-Results ;124
8.3;Acknowledgments;149
8.4;References;149
8.5;Appendices;154
9;Chapter 3. 1D Double Quantum Filter NMR Studies;278
9.1;1. Introduction and General Principles;279
9.2;2. Implementation of DQF Experiments;285
9.3;3. Applications of DQF Experiments;310
9.4;4. Conclusions;338
9.5;Acknowledgments;338
9.6;References;338
10;Chapter 4. Analyses of Proton NMR Spectra of Strongly and Weakly Dipolar Coupled Spins: Special Emphasis on Spectral Simplification, Chiral Discrimination, and Discerning of Degenerate Transitions;344
10.1;1. Introduction;346
10.2;2. Molecules Aligned in the Liquid Crystalline Phase;347
10.3;3. Analyses of the Spectra;355
10.4;4. Techniques to Aid the Analyses of the Complex 1H NMR Spectra;358
10.5;5. Analyses of Complex 1H NMR Spectra of Weakly Dipolar Coupled Spins;376
10.6;6. NMR Studies of Chiral Molecules;380
10.7;7. Existing NMR Experiments for Chiral Discrimination;382
10.8;8. Double Quantum Selective Refocusing (DQSERF): A Novel Concept;388
10.9;9. Spin State Selective Coherence Transfer: A Novel Conceptual Development of Methodology;399
10.10;10. Binuclear Spin State Selection for Chiral Discrimination;408
10.11;11. Single Quantum Spin Selective Correlation: A Method for Chiral Discrimination and Achieving Incredible Resolution;415
10.12;12. Band Selective Small Flip Angle COSY (BASE-beta-COSY);424
10.13;13. Conclusions;430
10.14;References;432