Wright / Winkler / Loebl Active Nitrogen

Physical Chemistry: A Series of Monographs
1. Auflage 2013
ISBN: 978-1-4831-9486-8
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 614 Seiten, Web PDF

Physical Chemistry, A Series of Monographs: Active Nitrogen presents the methods by which active nitrogen may be produced. This book is composed of five chapters that evaluate the energy content, molecular spectrum, and the emission of active nitrogen. Some of the topics covered in the book are the summary of light-emitting systems of active nitrogen; analysis of Long-Lived Lewis-Rayleigh Afterglow theory and Ionic theory of Mitra; reactions followed by induced light emission; and characteristics of homogeneous recombination. Other chapters deal with the analysis of metastable molecule theories and the mechanisms for reactions of active nitrogen involving direct N(4S) attack. The discussion then shifts to the rate constants for reactions induced by direct N(4S) attack. The evaluation of the Short-Lived Energetic Afterglow theory is presented. The final chapter is devoted to the examination of emission from molecular species with electronic energy levels below 9.76 eV. The book can provide useful information to physicists, students, and researchers.

Autoren/Hrsg.

Wright, A. Nelson

Winkler, Carl A.

Loebl, Ernest M.

Inhaltsverzeichnis

1;Front Cover;1
2;Active Nitrogen;4
3;Copyright Page;5
4;Table of Contents;10
5;Dedication;6
6;PREFACE;8
7;CHAPTER 1.
INTRODUCTION;14
7.1;I. A Brief Description of Active Nitrogen and Its Discovery;14
7.2;II. The Energy Content of Active Nitrogen and the Bond Dissociation Energy of N2;15
7.3;III. Methods by Which Active Nitrogen May Be Produced;17
8;CHAPTER 2. LIGHT EMISSION FROM ACTIVE NITROGEN SYSTEMS;26
8.1;I. The Molecular Spectrum of Nitrogen;26
8.2;II. Emission from Molecular Species with Electronic Energy Levels below 9.76 eV;28
8.3;III. Emission from Molecular Species with Electronic Energy Levels above 9.76 eV;47
8.4;IV. Emission from Atomic Nitrogen;63
8.5;V. Emission from Condensed Active Nitrogen or Activated Solid Nitrogen;66
8.6;VI. Summary of Light-Emitting Systems of Active Nitrogen;74
9;CHAPTER 3. AFTERGLOW SPECIES, THEIR LIFETIMES AND CONCENTRATIONS;78
9.1;I. Atomic Species;81
9.2;II. Molecular Species with Energy Content Less than 9.76 eV;101
9.3;III. Molecular Species with Energy Content Greater than 9.76 eV;130
9.4;IV. Other Species;139
9.5;V. Summary;151
10;CHAPTER 4. THEORIES OF ACTIVE NITROGEN;153
10.1;I. The Long-Lived Lewis-Rayleigh Afterglow;153
10.2;II. The Short-Lived, Energetic Afterglows;168
11;CHAPTER 5. CHEMICAL REACTIONS OF ACTIVE NITROGEN;174
11.1;I. Recombination of N(4S) Atoms;174
11.2;II. Survey of Reactions Investigated;213
11.3;III. Mechanisms for Reactions of Active Nitrogen That Appear to Involve Direct N(4S) Attack;481
11.4;IV. Rate Constants for Reactions Presumably Induced by Direct N(4S) Attack;489
11.5;V. Reactions Possibly Induced by Excited Nitrogen Molecule Attack;518
12;BIBLIOGRAPHY;525
13;AUTHOR INDEX;564
14;SUBJECT INDEX;594