Yan Photofunctional Rare Earth Hybrid Materials

1. Auflage 2017
ISBN: 978-981-10-2957-8
Verlag: Springer Nature Singapore
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band 251, 266 Seiten

Reihe: Springer Series in Materials Science

This book presents the main research advances in the field of photofunctional rare earth hybrid materials. The first chapter discusses the fundamental principles, ranging from rare earth, rare earth luminescence, luminescent rare earth compounds and photofunctional rare earth hybrid materials. The main body of the book consists of six chapters exploring different kinds of photofunctional hybrid materials, such as hybrids based on organically modified silica; organically modified mesoporous silica; functionalized microporous zeolite and metal-organic frameworks; polymer or polymer/silica composite; and multi-component assembly of hybrids. It also includes a chapter introducing the photofunctional application of these hybrid materials. It is a valuable resource for a wide readership in various fields of rare earth chemistry, chemical science and materials science.

Bing Yan obtained his doctorate from Changchun Institute of Applied Chemistry, Chinese Academy of Sciences in 1998. He continued his research as a research assistant and postdoctoral fellow at the City University of Hong Kong, Peking University and the University of Sherbrooke from 1998 to 2001. Since November 2001, he has been a professor of chemistry at Tongji University, China. His current interests focus on rare earth chemistry and photofunctional materials, including rare earth inorganic/organic molecular luminescent hybrids; rare earth functional compounds and micro-nano solid materials; and rare earth crystal framework hybrid systems. As a corresponding author, he has published over 400 research papers in international journals.

Autoren/Hrsg.

Yan, Bing

Inhaltsverzeichnis

1;Preface;6
2;Contents;8
3;Part I: Introduction;13
3.1;Chapter 1: Rare Earth, Rare Earth Luminescence, Luminescent Rare Earth Compounds, and Photofunctional Rare Earth Hybrid Materials;14
3.1.1;1.1 Introduction;14
3.1.2;1.2 Atomic Spectral Term and Energy Level Transition of Rare Earth Ions;17
3.1.3;1.3 Luminescence and Spectroscopy of Rare Earth Ions;17
3.1.4;1.4 Rare Earth Phosphors;20
3.1.5;1.5 Luminescent Rare Earth Coordination Compounds;22
3.1.6;1.6 Photofunctional Rare Earth Hybrid Materials;28
3.1.7;References;30
4;Part II: Typical Photofunctional Rare Earth Hybrid Material;33
4.1;Chapter 2: Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Silica;34
4.1.1;2.1 Introduction;34
4.1.2;2.2 Photofunctional Rare Earth Hybrid Materials Based on Aromatic Carboxylic Acid-Modified Silica;37
4.1.2.1;2.2.1 Photofunctional Rare Earth Hybrid Materials Based on Aromatic Carboxylic Acid-Modified Silica Through Carboxylic Group Grafting;37
4.1.2.2;2.2.2 Photofunctional Rare Earth Hybrid Materials Based on Aromatic Carboxylic Acid-Modified Silica Through Amino Group Grafting;39
4.1.2.3;2.2.3 Photofunctional Rare Earth Hybrid Materials Based on Aromatic Carboxylic Acid-Modified Silica Through Hydroxyl Group Grafting;41
4.1.2.4;2.2.4 Photofunctional Rare Earth Hybrid Materials Based on Aromatic Carboxylic Acid-Modified Silica Through Mercapto Group Grafting;41
4.1.3;2.3 Photofunctional Rare Earth Hybrid Materials Based on ?-Diketone and Its Anaologue Derivative-Modified Silica;44
4.1.3.1;2.3.1 Photofunctional Rare Earth Hybrid Materials Based on ?-Diketone-Modified Silica;44
4.1.3.2;2.3.2 Photofunctional Rare Earth Hybrid Materials Based on Sulfonamide Derivative-Modified Silica;47
4.1.3.3;2.3.3 Photofunctional Rare Earth Hybrid Materials Based on ?-Diketone Analogue-Modified Silica;48
4.1.3.4;2.3.4 Photofunctional Rare Earth Hybrid Materials Based on 1,3-Bis(2-Formylphenoxy)-2-Propanol-Modified Silica;48
4.1.4;2.4 Photofunctional Rare Earth Hybrid Materials Based on Macrocyclic Compound-Modified Silica;49
4.1.4.1;2.4.1 Photofunctional Rare Earth Hybrid Materials Based on Calixarene Derivative-Modified Silica;49
4.1.4.2;2.4.2 Photofunctional Rare Earth Hybrid Materials Based on Crown Derivative-Modified Silica;50
4.1.4.3;2.4.3 Photofunctional Rare Earth Hybrid Materials Based on Porphyrin Derivative-Modified Silica;51
4.1.4.4;2.4.4 Photofunctional Rare Earth Hybrid Materials Based on Schiff-Base Derivative Compound-Modified Silica;52
4.1.5;2.5 Photofunctional Rare Earth Hybrid Materials Based on Heterocyclic Compound-Modified Silica;52
4.1.5.1;2.5.1 Photofunctional Rare Earth Hybrid Materials Based on Bipyridine Derivative-Modified Silica;54
4.1.5.2;2.5.2 Photofunctional Rare Earth Hybrid Materials Based on Amino Compound-Modified Silica;55
4.1.5.3;2.5.3 Photofunctional Rare Earth Hybrid Materials Based on Hydroxyl Compound-Modified Silica;55
4.1.5.4;2.5.4 Photofunctional Rare Earth Hybrid Materials Based on Mercapto Compounds (3-alkyl-4-amino-5-ylsulfanyl-1,2,4-triazole)-Modified Silica;56
4.1.5.5;2.5.5 Photofunctional Rare Earth Hybrid Materials Based on Other Special ORMOSIL-Derived Silica;58
4.1.6;2.6 Photofunctional Rare Earth Hybrid Materials Based on Composite Matrices of Silica;58
4.1.7;2.7 Conclusion and Outlook;60
4.1.8;References;60
4.2;Chapter 3: Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Mesoporous Silica;66
4.2.1;3.1 Introduction;66
4.2.2;3.2 Photofunctional Rare Earth Hybrid Materials Based on Organically Modified MCM-Type Mesoporous Silica;68
4.2.3;3.3 Photofunctional Rare Earth Hybrid Materials Based on Organically Modified SBA-Type Mesoporous Silica;73
4.2.4;3.4 Photofunctional Rare Earth Hybrid Materials Based on POMs-Type Mesoporous Silica;78
4.2.5;3.5 Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Mesoporous Silica and Other Inorganic Hosts;81
4.2.6;3.6 Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Mesoporous Silica and Polymer Units;84
4.2.7;3.7 Conclusion and Outlook;86
4.2.8;References;87
4.3;Chapter 4: Photofunctional Rare Earth Hybrid Materials Based on Functionalized Microporous Zeolites;92
4.3.1;4.1 Zeolite, Rare Earth Ion-Functionalized Zeolites, and Their Photophysical Properties;92
4.3.2;4.2 Photofunctional Rare Earth Hybrid Materials Based on Functionalized Zeolite-FAU;97
4.3.3;4.3 Photofunctional Rare Earth Hybrid Materials Based on Functionalized Zeolite A;102
4.3.4;4.4 Photofunctional Rare Earth Hybrid Materials Based on Functionalized Zeolite L;106
4.3.5;4.5 Conclusion and Outlook;113
4.3.6;References;113
4.4;Chapter 5: Photofunctional Rare Earth Hybrid Materials Based on Functionalized Metal–Organic Frameworks;116
4.4.1;5.1 Introduction to Metal–Organic Frameworks (MOFs);116
4.4.2;5.2 Photofunctional Rare Earth Hybrid Materials Based on the Ionic Substitution Functionalized Metal–Organic Frameworks;119
4.4.3;5.3 Photofunctional Rare Earth Hybrid Materials Based on the Ion Exchange Functionalized Metal–Organic Frameworks;122
4.4.4;5.4 Photofunctional Rare Earth Hybrid Materials Based on the Coordinated Metal–Organic Frameworks;125
4.4.5;5.5 Photofunctional Rare Earth Hybrid Materials Based on the Covalent Postsynthetic Modification of Metal–Organic Frameworks;131
4.4.6;5.6 Photofunctional Rare Earth Hybrid Materials Based on the Composition of Metal–Organic Frameworks with Other Species;135
4.4.7;5.7 Conclusion and Outlook;139
4.4.8;References;140
4.5;Chapter 6: Photofunctional Rare Earth Hybrid Materials Based on Polymer and Polymer/Silica Composite;144
4.5.1;6.1 Photofunctional Rare Earth Hybrid Materials Based on Organic Polymers;145
4.5.2;6.2 Photofunctional Rare Earth Hybrid Materials Based on the Polymer Composite of Other Units Consisting Di-ureasils;149
4.5.3;6.3 Photofunctional Rare Earth Hybrid Material-Based Polymer/Silica Composite Through Coordination Bonding Assembly;156
4.5.4;6.4 Photofunctional Rare Earth Hybrid Materials Based on Polymer/Silica Composite Through Covalent Bonding Assembly;162
4.5.5;6.5 Photofunctional Rare Earth Hybrid Materials Based on Polymer Composite and Other Units;166
4.5.6;6.6 Conclusion and Outlook;168
4.5.7;References;169
5;Part III: Multicomponent Assembly;173
5.1;Chapter 7: Photofunctional Rare Earth Hybrid Materials Based on Multicomponent Assembly;174
5.1.1;7.1 Photofunctional Rare Earth Hybrid Materials Based on Modified Clay;175
5.1.2;7.2 Photofunctional Rare Earth Hybrid Materials Based on Ionogels;179
5.1.3;7.3 Photofunctional Rare Earth Hybrid Materials Based on Multicomponent Nanocomposite;185
5.1.4;7.4 Photofunctional Rare Earth Hybrid Materials Based on Polyoxometalate;193
5.1.5;7.5 Photofunctional Rare Earth Hybrid Materials Based on Multi-host Assembly;198
5.1.6;7.6 Conclusion and Outlook;199
5.1.7;References;200
6;Part IV: Photophysical Application;204
6.1;Chapter 8: Photophysical Applications of Photofunctional Rare-Earth Hybrid Materials;205
6.1.1;8.1 Photofunctional Rare-Earth Hybrid Materials for Luminescent Solar Concentrators (LSC);206
6.1.2;8.2 Photofunctional Rare-Earth Hybrid Materials for Luminescent Devices and Barcoding;210
6.1.3;8.3 Photofunctional Hybrid Materials as Probes or Sensors for Metal Cations;216
6.1.3.1;8.3.1 Photofunctional Hybrid Materials as Probes or Sensors for Fe3+ and Fe2+;216
6.1.3.2;8.3.2 Photofunctional Hybrid Materials as Probes or Sensors for Cd2+ and Hg2+;219
6.1.3.3;8.3.3 Photofunctional Hybrid Materials as Probes or Sensors for Cu2+ and Ag+;225
6.1.3.4;8.3.4 Photofunctional Hybrid Materials as Probes or Sensors for Other Cations;229
6.1.4;8.4 Photofunctional Hybrid Materials as Probes or Sensors for Anions;230
6.1.4.1;8.4.1 Photofunctional Hybrid Materials as Probes or Sensors for F?;230
6.1.4.2;8.4.2 Photofunctional Hybrid Materials as Probes or Sensors for CrO42? or Cr2O72?;233
6.1.4.3;8.4.3 Photofunctional Hybrid Materials as Probes or Sensors for Other Anions;235
6.1.5;8.5 Photofunctional Hybrid Materials as Probes or Sensors for Molecules;236
6.1.6;8.6 Photofunctional Hybrid Materials as Probes or Sensors for Special Molecule Species or Indices;243
6.1.7;8.7 Photofunctional Hybrid Materials as Probes or Sensors for Physical Properties;250
6.1.8;8.8 Conclusion and Outlook;257
6.1.9;References;258
7;Index;262