Hirao Redox Systems Under Nano-Space Control

1. Auflage 2006
ISBN: 978-3-540-29580-8
Verlag: Springer Berlin Heidelberg
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 292 Seiten

Nanotechnology - Short description currently not available.

Autoren/Hrsg.

Hirao, Toshikazu

Inhaltsverzeichnis

1;Contents;6
2;List of Contributors;13
3;Part I Redox Systems via d,p-Conjugation;17
3.1;Conjugated Complexes with Quinonediimine Derivatives;18
3.1.1;1.1;19
3.1.2;Introduction;19
3.1.3;1.2;20
3.1.4;Architecturally Controlled Formation of Conjugated Complexes;20
3.1.5;with 1,4-Benzoquinonediimines;20
3.1.6;1.3;32
3.1.7;Redox-Switching Properties of Conjugated Complexes;32
3.1.8;with 1,4-Benzoquinonediimines;32
3.1.9;1.4;39
3.1.10;Conclusion;39
3.1.11;1.5;40
3.1.12;References;40
3.2;Realizing the Ultimate Amplification in Conducting Polymer Sensors: Isolated Nanoscopic Pathways;43
3.2.1;Abbrevations;43
3.2.2;2.1;43
3.2.3;Dimensionality in Molecular-Wire Sensors;43
3.2.4;2.2;46
3.2.5;Analyte-Triggered Barrier Creation in Conducting Polymers;46
3.2.6;2.3;48
3.2.7;Isolated Nanoscopic Pathways;48
3.2.8;2.4;48
3.2.9;Langmuir–Blodgett Approaches to Nanofibrils;48
3.2.10;2.5;51
3.2.11;Molecular Scaffolds for the Isolation of MolecularWires;51
3.2.12;2.6;57
3.2.13;Summary and Future Prospects;57
3.2.14;2.7;57
3.2.15;References;57
3.3;Metal-Containing;59
3.4;ConjugatedMaterials;59
3.4.1;Abbreviations;59
3.4.2;3.1;60
3.4.3;Introduction;60
3.4.4;3.2;61
3.4.5;Metal-Complex-Containing Conjugated Materials;61
3.4.6;3.3;65
3.4.7;Metal-Nanoparticle-Containing Conjugated Materials;65
3.4.8;3.4;66
3.4.9;Applications;66
3.4.10;3.5;67
3.4.11;Conclusions;67
3.4.12;3.6;67
3.4.13;References;67
3.5;Redox Active Architectures and Carbon- Rich Ruthenium Complexes asModels forMolecularWires;69
3.5.1;Abbreviations;69
3.5.2;4.1;70
3.5.3;Introduction;70
3.5.4;4.2;71
3.5.5;Ruthenium Allenylidene and Acetylide Building Blocks: Basic Properties;71
3.5.6;4.3;77
3.5.7;Bimetallic Complexes fromthe Ru(dppe);77
3.5.8;System;77
3.5.9;4.4;85
3.5.10;Connection of Two Carbon-Rich Chains with the Ruthenium System;85
3.5.11;4.5;88
3.5.12;Trimetallic and Oligomeric Metal Complexes with Carbon-Rich Bridges;88
3.5.13;4.6;91
3.5.14;Star Organometallic-Containing Multiple Identical Metal Sites;91
3.5.15;4.7;93
3.5.16;Conclusion;93
3.5.17;4.8;93
3.5.18;References;93
3.6;Molecular MetalWires Built from a Linear Metal Atom Chain Supported by Oligopyridylamido Ligands;99
3.6.1;Abbreviations;99
3.6.2;5.1;100
3.6.3;Introduction;100
3.6.4;5.2;101
3.6.5;Synthesis of Oligopyridylamine Ligands;101
3.6.6;5.3;104
3.6.7;Dimerization by Self-Complementary Hydrogen Bonding;104
3.6.8;5.4;105
3.6.9;Complexation of Oligopyridylamine Ligands;105
3.6.10;5.5;105
3.6.11;Mono- and Dinuculear Complexes;105
3.6.12;5.6;106
3.6.13;Structures of Linear Multinuclear Nickel Complexes;106
3.6.14;5.7;112
3.6.15;Structures of Linear Multinuclear Cobalt Complexes;112
3.6.16;5.8;114
3.6.17;Structures of Linear Multinuclear Chromium Complexes;114
3.6.18;5.9;117
3.6.19;Structures of Triruthenium and Trirhodium Complexes;117
3.6.20;5.10;118
3.6.21;Complexes ofModified Ligands;118
3.6.22;5.11;119
3.6.23;Electrochemical Properties of the Complexes;119
3.6.24;5.12;126
3.6.25;Scanning Tunneling Microscopy Studies;126
3.6.26;5.13;128
3.6.27;Summary;128
3.6.28;5.14;129
3.6.29;References;129
3.7;Multielectron Redox Catalysts in Metal- Assembled Macromolecular Systems;132
3.7.1;Abbreviations;132
3.7.2;6.1;132
3.7.3;Introduction;132
3.7.4;6.2;133
3.7.5;Multielectron Redox Systems;133
3.7.6;6.3;135
3.7.7;Multinuclear Complexes as Redox Catalysts;135
3.7.8;6.4;136
3.7.9;Macromolecule-Metal Complexes;136
3.7.10;6.5;137
3.7.11;Metal Ion Assembly on Dendritic Macromolecules;137
3.7.12;6.6;142
3.7.13;Conclusion;142
3.7.14;6.7;142
3.7.15;References;142
4;Part II Redox Systems via Coordination Control;144
4.1;Triruthenium Cluster Oligomers that ShowMultistep/ Multielectron Redox Behavior;145
4.1.1;7.1;145
4.1.2;Introduction;145
4.1.3;7.2;147
4.1.4;Syntheses of Oligomers 1 and 2;147
4.1.5;7.3;148
4.1.6;Redox Behavior of 1 and 2;148
4.1.7;7.4;151
4.1.8;Conclusion;151
4.1.9;7.5;151
4.1.10;References;151
4.2;Molecular Architecture of Redox- Active Multilayered Metal Complexes Based on Surface Coordination Chemistry;153
4.2.1;Abbreviations;153
4.2.2;8.1;153
4.2.3;Introduction;153
4.2.4;8.2;154
4.2.5;Fabrication of Multilayer Nanoarchitectures;154
4.2.6;by Surface Coordination Chemistry;154
4.2.7;8.3;160
4.2.8;Chemical Functions of Redox-ActiveMultilayered Complexes on Surface;160
4.2.9;8.4;165
4.2.10;Conclusion;165
4.2.11;8.5;165
4.2.12;References;165
4.3;Programmed Metal Arrays by Means of Designable Biological Macromolecules;167
4.3.1;Abbreviations;167
4.3.2;9.1;167
4.3.3;Introduction;167
4.3.4;9.2;168
4.3.5;DNA-Directed Metal Arrays;168
4.3.6;9.3;173
4.3.7;Peptide-Directed Metal Arrays;173
4.3.8;9.4;176
4.3.9;Conclusion;176
4.3.10;9.5;176
4.3.11;References;176
4.4;Metal-Incorporated Hosts for Cooperative and Responsive Recognition to External Stimulus;178
4.4.1;Abbreviations;178
4.4.2;10.1;178
4.4.3;Introduction;178
4.4.4;10.2;179
4.4.5;Pseudomacrocycles for Cooperative Molecular Functional Systems;179
4.4.6;10.3;183
4.4.7;Oligo( N2O2- Chelate) Macrocycles;183
4.4.8;10.4;185
4.4.9;Acyclic Oligo( N2O2- Chelate) Ligands;185
4.4.10;10.5;188
4.4.11;Conclusion;188
4.4.12;10.6;188
4.4.13;References;188
4.5;Synthesis of Poly(binaphthol) via Controlled Oxidative Coupling;190
4.5.1;Abbreviations;190
4.5.2;11.1;190
4.5.3;Introduction;190
4.5.4;11.2;192
4.5.5;Asymmetric Oxidative Coupling with Dinuclear Metal Complexes;192
4.5.6;11.3;194
4.5.7;Oxidative Coupling Polymerization of Phenols;194
4.5.8;11.4;195
4.5.9;Oxidative Coupling Polymerization of 2,3-Dihydroxynaphthalene;195
4.5.10;11.5;199
4.5.11;Conclusion;199
4.5.12;11.6;199
4.5.13;References;199
5;Part II Redox Systems via Molecular Chain Control;201
5.1;Nano Meccano;202
5.1.1;Abbreviations and Symbols;202
5.1.2;12.1;203
5.1.3;Introduction;203
5.1.4;12.2;205
5.1.5;Redox-Controllable Molecular Switches in Solution;205
5.1.6;12.3;210
5.1.7;Application of Redox-Controllable Molecular Machines in Electronic Devices;210
5.1.8;12.4;213
5.1.9;Application of Redox-Controllable Molecular Machines in Mechanical Devices;213
5.1.10;12.5;220
5.1.11;Conclusions;220
5.1.12;12.6;221
5.1.13;References;221
5.2;Through-Space Control of Redox Reactions Using Interlocked Structure of Rotaxanes;224
5.2.1;Abbreviations;224
5.2.2;13.1;224
5.2.3;Introduction;224
5.2.4;13.2;226
5.2.5;Redox Behavior and Conformation of Ferrocene-End-Capped Rotaxane;226
5.2.6;13.3;234
5.2.7;Reduction of Ketone by Rotaxane Bearing a Dihydronicotinamide Group;234
5.2.8;13.4;239
5.2.9;Conclusion;239
5.2.10;13.5;240
5.2.11;References;240
5.3;Metal-Containing Star and Hyperbranched Polymers;242
5.3.1;Abbreviations;242
5.3.2;14.1;242
5.3.3;Introduction;242
5.3.4;14.2;244
5.3.5;Metal-Containing Star Polymers;244
5.3.6;14.3;252
5.3.7;Metal-Containing Hyperbranched Polymers;252
5.3.8;14.4;254
5.3.9;Concluding Remarks;254
5.3.10;14.5;255
5.3.11;References;255
5.4;Electronic Properties of Helical Peptide Derivatives at a Single Molecular Level;257
5.4.1;15.1;257
5.4.2;Molecular Electronics;257
5.4.3;15.2;258
5.4.4;Electron Transfer Through Molecules;258
5.4.5;15.3;259
5.4.6;Electronic Properties of Helical Peptides;259
5.4.7;15.4;262
5.4.8;Electron Transfer Mechanism over a Long Distance;262
5.4.9;15.5;262
5.4.10;Effect of Linkers on Electron Transfer;262
5.4.11;15.6;264
5.4.12;Helical-Peptide Scaffold for Electron Hopping;264
5.4.13;15.7;267
5.4.14;Photocurrent Generation with Helical Peptides Carrying Naphthyl Groups;267
5.4.15;15.8;269
5.4.16;Conclusion;269
5.4.17;15.9;269
5.4.18;References;269
5.5;Construction of Redox-Induced Systems Using Antigen- Combining Sites of Antibodies and Functionalization of Antibody Supramolecules;271
5.5.1;Abbreviations;271
5.5.2;16.1;272
5.5.3;Introduction;272
5.5.4;16.2;274
5.5.5;Photoinduced Electron Transfer from Porphyrins;274
5.5.6;to Electron Acceptor Molecules;274
5.5.7;16.3;283
5.5.8;Peroxidase Activity of Fe-Porphyrin-Antibody Complexes;283
5.5.9;16.4;290
5.5.10;Dendritic Antibody Supramolecules;290
5.5.11;16.5;293
5.5.12;Linear Antibody Supramolecules: Application for Novel Biosensing Method;293
5.5.13;16.6;297
5.5.14;Conclusions;297
5.5.15;16.7;298
5.5.16;References;298
6;Subject Index;300