Phillips Spectra-Structure Correlation

1. Auflage 2013
ISBN: 978-1-4832-6355-7
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 182 Seiten, Web PDF

Spectra-Structure Correlation focuses on absorption spectroscopy of organic compounds, including radiation, absorption, and analysis of compounds. The publication first offers information on wavelength classification of absorption spectra; intensities and shapes of absorption bands; mechanisms for the absorption of radiation; and solvent, phase, and temperature effects. The text also focuses on the spectra of hydrocarbons, as well as olefins, cyclopropanes, benzenes, allenes and cumulenes, cyclobutanes, cyclopentanes, and cyclohexanes. The manuscript reviews compounds with oxygen and nitrogen functions. Discussions focus on aldehydes and ketones, alcohols, carboxylic acids, phenols, ethers and peroxides, acid derivatives, amides and imides, amines, and nitriles and related functions. The text also ponders on organic compounds containing halogen, sulfur, phosphorus, silicon, or boron, inorganic compounds, and complex materials. Concerns include polymers, steroids, purines, pyrimidines, nucleic acids, amino acids, polypeptides, and proteins. The publication is a dependable reference for readers interested in absorption spectroscopy or organic compounds.

Autoren/Hrsg.

Phillips, John P.

Inhaltsverzeichnis

1;Front Cover;1
2;Spectra-Structure Correlation;4
3;Copyright Page;5
4;Table of Contents;8
5;Preface;6
6;Chapter I. Introduction;12
6.1;A. Wavelength Classification of Absorption Spectra;12
6.2;B. Intensities and Shapes of Absorption Bands;15
6.3;C. Instruments;16
6.4;D. Mechanisms for the Absorption of Radiation;18
6.5;E. Sources of Spectrophotometric Data;24
6.6;F. Accuracy and Precision of Spectra;30
6.7;G. Solvent, Phase, and Temperature Effects;33
7;Chapter II. Hydrocarbons;40
7.1;A. Acyclic Saturated Hydrocarbons;40
7.2;B. Cyclopropanes;45
7.3;C. Cyclobutanes, Cyclopentanes, and Cyclohexanes;46
7.4;D. Simple Olefins;47
7.5;E. Conjugated Olefins;52
7.6;F· Alkynes and Poly-ynes;57
7.7;G. Allenes and Cumulenes;60
7.8;H. Benzene and Substituted Benzenes;61
7.9;I. Polynuclear Aromatic Hydrocarbons;68
7.10;J. Ultraviolet-Visible Spectra of Other Hydrocarbons;72
8;Chapter Ill. Compounds with Oxygen Function;78
8.1;A. Alcohols;78
8.2;B. Aldehydes and Ketones;81
8.3;C. Carbonyl Derivatives (Oximes, Semicarbazones, Thiosemicarbazones, and 2,4-Dinitrophenylhydrazones);89
8.4;D. Carboxylic Acids;91
8.5;E. Acid Derivatives (Esters, Acid Chlorides, Anhydrides, and Lactones);97
8.6;F. Phenols;100
8.7;G. Ethers and Peroxides;103
9;Chapter IV. Compounds with Nitrogen Functions;106
9.1;A. Amines;106
9.2;B. Amides and Imides;112
9.3;C. Double Bond from Nitrogen to Carbon, Nitrogen, or Oxygen;114
9.4;D. Nitriles and Related Functions;120
10;Chapter V. Heterocycles;124
10.1;A. Aza Benzenes and Naphthalenes (Pyridines, Pyrimidines, Quinolines, etc.);124
10.2;B. Conjugated 5-Membered Heterocyclic Rings;131
11;Chapter VI. Organic Compounds Containing Halogen, Sulfur, Phosphorus, Silicon, or Boron;136
11.1;A. Organic Halides;136
11.2;B. Sulfur Compounds;139
11.3;C. Phosphorus Compounds;144
11.4;D. Silicon Compounds;146
11.5;E. Boron Compounds;148
12;Chapter VII. Inorganic Compounds;150
12.1;A. Ultraviolet-Visible;150
12.2;B. Infrared and Far Infrared;153
13;Chapter VIII. Complex Materials;158
13.1;A. Polymers;158
13.2;B. Sugars, Polysaccharides, Cellulose, and Wood;159
13.3;C. Steroids;160
13.4;D. Amino Acids, Polypeptides, and Proteins;161
13.5;E. Purines, Pyrimidines, Nucleic Acids, and Related Materials;163
13.6;F. Ultraviolet-Visible Spectra of Porphins, Chlorine, and Tetrahydroporphins;166
13.7;G. Visible Spectra of Dyes;166
14;Author Index;168
15;Subject Index;174