Buch, Englisch, 446 Seiten, Format (B × H): 157 mm x 235 mm, Gewicht: 872 g
Buch, Englisch, 446 Seiten, Format (B × H): 157 mm x 235 mm, Gewicht: 872 g
Reihe: Physical Organometallic Chemistry
ISBN: 978-0-471-49635-9
Verlag: Wiley
The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests.
Unusual Structures and Physical Properties in Organometallic Chemistry:
* Provides test cases for computational and theoretical models
* Presents a challenge for synthetic chemists
* Provides ideal show cases for analytical techniques
This volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods.
Autoren/Hrsg.
Fachgebiete
Weitere Infos & Material
Contributors.
Series Preface.
Preface.
1. Structure and Electrochemistry of Transition Metal Carbonyl Clusters with Interstitial or Semi-Interstitial Atoms: Contrast between Nitrides or Phosphides and Carbides (Piero Zanello).
2. Unusual Nuclear Magnetic Shielding and Coupling Constants Related to Unusual Bonding Situations (Bernd Wrackmeyer).
3. Deuterium Spin-Lattice Relaxation and Deuterium Quadrupole Coupling Constants. A Novel Strategy for Characterization of Transition Metal Hydrides and Dihydrogen Complexes in Solution (Vladimir I. Bakhmutov).
4. NMR Studies of Ligand Nuclei in Organometallic Compounds--New Information from Solid-State NMR Techniques (Guy M. Bernard and Roderick E. Wasylishen).
5. Metal Atom Motion in Some Iron Organometallics (Rolfe H. Herber).
6. Magnetic Communication in Binuclear Organometallic Complexes Mediated by Carbon-Rich Bridges (Frédéric Paul and Claude Lapinte).
7. Molecular Cluster Complexes with Facial Arene Ligands (Herbert Wadepohl).
8. Cobaltafulvenes and Cobaltapentalenes: Highly Polar Metallacyclic II-Systems with Unusual Properties (Herbert Wadepohl).
9. Novel Highly Nucleophilic Ylidic Ligands for the Preparation of Unusually Stable Metal Complexes (Norbert Kuhn, Martin Göhner, Gernot Frenking and Yu Chen).
10. Supramolecular Interactions in Structures of Organic Antimony and Bismuth Compounds (Gabor Balázs and Hans Joachim Breunig).
Index.