Griffith Ruthenium Oxidation Complexes

Their Uses as Homogenous Organic Catalysts
1. Auflage 2010
ISBN: 978-1-4020-9378-4
Verlag: Springer Netherlands
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band 34, 258 Seiten

Reihe: Catalysis by Metal Complexes

Ruthenium Oxidation Complexes explores ruthenium complexes, particularly those in higher oxidation states, which function as useful and selective organic oxidation catalysts. Particular emphasis is placed on those systems which are of industrial significance. The preparation, properties and applications of the ruthenium complexes are described, followed by a presentation of their oxidative properties and summary of the different mechanisms involved in the organic oxidations (e.g. oxidations of alcohols, alkenes, arenes and alkynes, alkanes, amines, ethers, phopshines and miscellaneous substrates). Moreover, future trends and developments in the area are discussed. This monograph is aimed at inorganic, organic, industrial and catalysis chemists, especially those who wish to carry out specific organic oxidations using catalytic methods.

Autoren/Hrsg.

Griffith, William P.

Inhaltsverzeichnis

1;Preface;6
2;Contents;8
3;Abbreviations;14
4;The Chemistry of Ruthenium Oxidation Complexes;18
4.1;1.1 Overview and Introduction;18
4.2;1.2 Ru(VIII) Complexes;24
4.3;1.3 Ru(VII) Complexes;47
4.4;1.4 Ru(VI) Complexes;57
4.5;1.5 Ru(V) Complexes;84
4.6;1.6 Ru(IV) Complexes;86
4.7;1.7 Ru(III) Complexes;93
4.8;1.8 Ru(II–III) Complexes;106
4.9;1.9 Ru(II) Complexes;106
4.10;1.10 Ru(0) Complexes;127
4.11;1.11 Appendix: Brief Resumé of Preparations of Ru Oxidants and Oxidation Reactions;127
4.12;References;130
5;Oxidation of Alcohols, Carbohydrates and Diols;152
5.1;2.1 Primary Alcohols to Aldehydes (Table 2.1);153
5.2;2.2 Primary Alcohols to Carboxylic Acids (Table 2.1);158
5.3;2.3 Secondary Alcohols to Ketones or Lactones;159
5.4;2.4 Carbohydrates;168
5.5;2.5 Diols 2.5.1 Specific Examples;177
5.6;2.6 Miscellaneous Oxidations of Alcohols;179
5.7;References;180
6;Oxidation of Alkenes, Arenes and Alkynes;190
6.1;3.1 Oxidation of Alkenes Involving No C=C Bond Cleavage;190
6.2;3.2 Oxidative Cleavage of Alkenes;209
6.3;3.3 Oxidation of Arenes;217
6.4;3.4 Oxidation of Alkynes;222
6.5;References;224
7;Oxidation of Alkanes;231
7.1;4.1 Oxidation of C–H Bonds in Alkanes;231
7.2;4.2 Oxidation of C–C Bonds in Alkanes;239
7.3;References;240
8;Oxidations of Amines, Amides, Ethers, Sulfides, Phosphines, Arsines, Stibines and Miscellaneous Substrates;243
8.1;5.1 Oxidation of Amines;243
8.2;5.2 Oxidation of Amides;250
8.3;5.3 Oxidation of Ethers, R1R2O;254
8.4;5.4 Oxidation of Sulfides (thioethers), R1R2S;257
8.5;5.5 Oxidation of Phosphines, Arsines and Stibines;261
8.6;5.6 Oxidations of Miscellaneous Substrates ;262
8.7;References;264
9;Index;269