Lappert / Protchenko / Power Metal Amide Chemistry

1. Auflage 2008
ISBN: 978-0-470-74037-8
Verlag: John Wiley & Sons
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 370 Seiten, E-Book

Written by internationally recognised leaders in the field,Metal Amide Chemistry is the authoritative survey of thisimportant class of compounds, the first since Lappert andPower's 1980 book "Metal and Metalloid Amides."
An introduction to the topic is followed by in-depth discussionsof the amide compounds of:
* alkali metals
* alkaline earth metals
* zinc, cadmium and mercury
* the transition metals
* group 3 and lanthanide metals
* group 13 metals
* silicon and the group 14 metals
* group 15 metals
* the actinide metals
Accompanied by a substantial bibliography, this is an essentialguide for researchers and advanced students in academia andresearch working in synthetic organometallic, organic and inorganicchemistry, materials chemistry and catalysis.

Autoren/Hrsg.

Lappert, Michael

Protchenko, Andrey

Power, Philip

Seeber, Alexandra

Inhaltsverzeichnis

Biographies.
Preface.
1. Introduction.
1.1. Scope and Organisation of Subject Matter.
1.2. Developments and Perspectives.
2. Alkali Metal Amides.
2.1. Introduction.
2.2. Lithium Amides.
2.3. Sodium Amides.
2.4. Potassium Amides.
2.5. Rubidium Amides.
2.6. Caesium Amides.
3. Beryllium and the Alkaline Earth Metal Amides.
3.1. Introduction.
3.2. Beryllium Amides.
3.3. Magnesium Amides.
3.4. Calcium Amides.
3.5. Strontium Amides.
3.6. Barium Amides.
4. Amides of the Group 3 Lanthanide Metals.
4.1. Introduction.
4.2. The Pre-1996 Literature: Anwander's Review.
4.3. The Recent (Post-1995)Literature.
5. Amides of the Actinide Metals.
5.1. Introduction
5.2.Neutral Amidouranium (IV) and Thorium (IV) Complexes.
5.3. Neutral U¯III Amides.
5.4. Neutral Mixed Valence (U¯III/U¯IV),U¯II U¯V and U¯VI Amides.
5.5. Amidouranates.
5.6. Amidouranium Tetraphenylborates.
6. Amides of the Transition Metals.
6.1. Introduction.
6.2. Transition Metal Derivatives of Monodentate Amides.
6.3. Transition Metal Complexes of Polydentate AmidoLigands.
6.4. Other Chelating Amido Ligands.
7. Amides of Zinc, Cadmium and Mercury.
7.1. Introduction.
7.2. Neutral Homoleptic Zinc, Cadmium and Mercury Amides.
7.3. Ionic Metal Amides.
7.4. Lewis Base Complexes, Chelated Metal Amides andHeteroleptic Amido Complexes.
8. Amides of the Group 13 Metals.
8.1. Introduction.
8.2. Aluminum Amides.
8.3. Gallium Amides.
8.4. Indium Amides.
8.5. Thallium Amides.
9. Subvalent Amides of Silicon and the Group 14Metals.
9.1. Introduction.
9.2. Subvalent Amidosilicon Compounds.
9.3. Amidometal(II) Chemistry [Ge(II), Sn(II), Pb(II)].
9.4. Dimeric Metal(III) Imides: Biradicaloid Compounds.
9.5. Higher-Nuclearity Group 14 Metalloid Clusters having AmidoLigands.
10. Amides of the Group 15 Metals (As, Sb, Bi).
10.1. Introduction.
10.2. Mononuclear Group 15 Metal (III) Amides.
10.3. Oligomeric Group 15 Metal Imides.
10.4. Mononuclear Group 15 Metal (V) Amides.
10.5. Group 15 Metal (III) Macrocyclic Imides.
10.6. Miscellaneous Group 15 Metal-Nitrogen Compounds.
Index.

Über Autor(innen)

Michael Lappert is Emeritus Research Professor of Chemistryat the University of Sussex. A graduate of Northern Polytechnic,his B.S.c. was followed by a Ph.D. (with W. Gerard to which in 1960he added a D.Sc. (University of London). He has been at Sussexsince 1964, having previously been at UMIST (1959-1964). He was therecipient of the first chemical Society Award for Main Group Metalchemistry (1970) and then of the chemistry (1976); with the RSC (hewas its Dalton Division President, 1989-1991), he has been a Tilden(1972), Nyholm (1994), and Sir Edward Frankland (1998) Medallistand Lecturer. In 2008, he was awarded the GDCh Alfred-Stock Prize.he was elected FRS in 1979 and was award an honorary doctorate fromLudwig-Maximilians-Universitat (Munchen, 1989). With co-workers hehas published 2 books, edited 4 others, and more than 780 papersand reviews and a few patents on various aspects of inorganic andorganometallic chemistry.
Philip Power received a b.A. from trinity college Dublinin 1974 and a D. Phil, under M. F. Lappert from the University ofSussex in 1977. After postdoctoral studies with R.H. Holm atStanford University, he joined the faculty at the department ofChemistry at the University of California at Davis in 1981, wherehe is a Distinguished Professor of chemistry. His main interestslie in the exploratory synthesis of new main-group andtransition-metal complexes. A major theme of his work has been theuse of sterically crowded ligands to stabilize species with newtypes of bonding, low coordination numbers, and high reactivity. Hehas been the recipient of several awards including the A. P. SloanFoundation Fellow (1985), Alexander von Humboldt Fellowship forSenior U. S. Scientist (1992), Ludwig Mond Medal of the RoyalSociety of Chemistry (2005), F.A. Cotton Award in SyntheticInorganic Chemistry of the American Chemical Society (2005) and waselected Fellow of the Royal Society of London (FRS) (2005).
Andrey Protchenko was born in 1961 in Rostov-on-Don,Russia. A graduate of the Moscow State University (Russia) in 1983,he carried out his doctoral work at the Karpov Institute ofphysical Chemistry (Moscow) and completed his Ph.D. in chemistry(1997) at the Razuvaev Institute of Organometallic Chemistry(Nizhny Novgorod) under the supervision of Prof. M. N. Bochkarevstudying naphthalene complexes of the lanthanides. In 1998 hejoined the group of Prof. M. F. Lappert at the University of Sussex(England) working on a series of projects (Royal Society, EPSRC andLeverhulme trust grants) involving lanthanide redox chemistry basedon cyclopentadienyl, N- and N, N' -centred ligands.
Alexandra Seeber, nee Pickering, was born in 1979 inLichfield, UK. After graduating in chemistry at Keele University in2001 and completing a Ph.D. in Inorganic Chemistry into the designand synthesis of ligands for the controlled self-assembly oftr5ansition metal complexes at the University of Glasgow (Scotland)in 2004, she carried out postdoctoral research into nanoparticlesynthesis at the University of California, Davis with Prof. PhilipPower under a Department of energy grant for the Design of highsurface area materials as hydrogen storage vessels. AlexandraSeeber has worked since 2006 in Research and development in thecatalysis department at BASF in Ludwigshafen (Germany).