Polyoxometalate Chemistry From Topology via Self-Assembly to Applications

1. Auflage. Softcover version of original hardcover Auflage 2001
ISBN: 978-90-481-5716-7
Verlag: Springer Netherlands

Buch, Englisch, 427 Seiten, Paperback, Format (B × H): 155 mm x 235 mm, Gewicht: 663 g

An authoritative up-to-date summary of the chemistry and applications of polyoxometalates with emphasis on new synthetic strategies directed towards functionalized organic derivatives, self-assembly of mesoscopic composite polyoxoanions, generation of framework materials and thin oxide films, extended optical, magnetic, and electrical properties, applications in homogeneous and nanocluster-based catalysts, photocatalytic water decontamination, ribosomal crystallography, and topological aspects of large symmetrical structures.

Zielgruppe

Research

Autoren/Hrsg.

Müller, Achim

Pope, M.T.

Fachgebiete

• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffprüfung
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffkunde, Materialwissenschaft: Forschungsmethoden
• Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie
• Naturwissenschaften Chemie Physikalische Chemie Quantenchemie, Theoretische Chemie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Verfahrenstechnik, Chemieingenieurwesen
• Naturwissenschaften Chemie Anorganische Chemie Komplexchemie
• Mathematik | Informatik EDV | Informatik Informatik
• Naturwissenschaften Chemie Anorganische Chemie Festkörperchemie

Inhaltsverzeichnis

to Polyoxometalate Chemistry: From Topology via Self-assembly to Applications.- Synthetic Strategies.- Rational Approaches to Polyoxometalate Synthesis.- Functionalization of Polyoxometalates: Achievements and Perspectives.- From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M2O2S2]2+ Building Block M=Mo,W.- Organometallic Oxometal Clusters.- Structures: Molecular and Electronic.- Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspects.- Syntheses and Crystal Structure Studies of Novel Selenium- and Tellurium-substituted Lacunary Polyoxometalates.- Vibrational Spectroscopy of Heteropoly Acids.- Bond-stretch Isomerism in Polyoxometalates?.- Quantum-chemical studies of electron transfer in transition-metal substituted polyoxometalates.- Solution Equilibria and Dynamics.- Aqueous Peroxoisopolyoxometalates.- Molybdate speciation in systems related to the bleaching of kraft pulp.- NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalates.- From Discrete Clusters to Networks and Materials.- Molecular Aspect of Energy Transfer from Tb3+ to Eu3+ in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphors.- COnducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalates.- Molecular Materials from Polyoxometalates.- Framework Materials Composed of Transition Metal Oxide Clusters.- Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxides.- Polyoxometalate Clusters in a Supramolecular SelfOrganized Environment: Steps Towards Functional Nanodevices and Thin Film Applications.- Polyoxometalate Chemistry: a Source for Unusual Spin Topologies.- Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Films.- Applications: Catalysis, Biological Systems, Environmental Studies.- Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates.- Aerobic Oxidations Catalyzed by Polyoxometalates.- Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis.- Ribosomal Crystallography and Heteropolytungstates.- Photocatalytic Decontamination by Polyoxometalates.