Abd-El-Aziz / Carraher / Pittman Inorganic and Organometallic Macromolecules

Design and Applications
1. Auflage 2007
ISBN: 978-0-387-72947-3
Verlag: Springer US
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 475 Seiten

This important work is based on the editors' symposium at the 2005 ACS meeting in Washington, DC. The contents include an emphasis on main-group polymers, including boron. The chapters are not simply journal articles, but have real added value as the editors have reviewed the general area by placing the work into a larger perspective. This book will be required reading for scientists in a number of disciplines including chemical engineers and physics researchers.

Autoren/Hrsg.

Abd-El-Aziz, Alaa S.

Carraher, Charles E.

Pittman, Charles U.

Zeldin, Martel

Inhaltsverzeichnis

1;Preface;5
2;Contents;6
3;Contributors;8
4;Synthetic Versatility and Structural Modularity in Organometallic Polymers;12
4.1;1 Background;12
4.2;2 Research and Discussion;21
4.3;3 Further Considerations and Outlook;30
4.4;References;30
5;Hyperbranched Polymers Containing Transition Metals: Synthetic Pathways and Potential Applications;32
5.1;1 Background;32
5.2;2 Research and Discussion;33
5.3;3 Conclusion and Future Considerations;44
5.4;References;44
6;Transition Metal s-Acetylide Polymers Containing Main Group Elements in the Main Chain: Synthesis, Light Emission and Optoelectronic Applications;47
6.1;1 Introduction;47
6.2;2 Research and Discussion;50
6.3;3 Further Considerations and Perspectives;75
6.4;References;76
7;The Spectroscopy and Photophysical Behavior of Diphosphine- and Diisocyanide- Containing Coordination and Organometallic Oligomers and Polymers: Focus on Palladium and Platinum, Copper, Silver, and Gold;80
7.1;1 Introduction;80
7.2;2 Palladium and Platinum;81
7.3;3 Copper and Silver;89
7.4;4 Gold;108
7.5;5 Conclusion;112
7.6;References;114
8;Metal Binding Studies of Ferrocene Peptides in Solution;117
8.1;1 Introduction;117
8.2;2 Synthesis and Characterizations of Ferrocene Peptides;121
8.3;3 Conclusions;150
8.4;References;151
9;Metal Ion Binding to Ferrocene Peptide Dendrimer Films;154
9.1;1 Introduction;154
9.2;2 Synthesis of Ferrocene Peptide Cystamines;156
9.3;3 Conclusions;176
9.4;References;176
10;Iron-Containing Polymers with Azo Dyes in their Side Chains or Backbones;179
10.1;1 Introduction;179
10.2;2 Synthesis of Organoiron Polymers Containing Azo Dyes in Their Side Chains;180
10.3;3 Synthesis of Organoiron Polymers with Azo Dyes in their Backbones;188
10.4;4 Effects of Photoloysis on Organoiron Polymers Containing Azo Dyes;191
10.5;5 Summary;197
10.6;References;197
11;Cisplatin Derivatives as Antiviral Agents;199
11.1;1 Introduction;199
11.2;2 Inhibition;201
11.3;3 Currently Approved Platinum-Containing Drugs;210
11.4;4 Active Form of Cisplatin;212
11.5;5 Structure-Activity Relationships;216
11.6;6 Arguments for Cisplatin-Derivative Drugs;216
11.7;7 Arguments for Polymeric Drugs;217
11.8;8 Polymer Synthesis;219
11.9;9 Antiviral Activity;219
11.10;10 Conclusions;226
11.11;References;226
12;Vanadocene-Containing Polymers;230
12.1;1 Introduction;230
12.2;2 Anticancer Activity;231
12.3;3 Spermicidal Activity;231
12.4;4 Model Compounds for Polymer Formation;232
12.5;5 Dendrimers;234
12.6;6 Linear Polymers;236
12.7;7 Acyclovir Polymers;236
12.8;8 F HR Matrix-Assisted Laser Desorption/Ionization Time- of- Flight Mass Spectrometry ( MALDI- TOF MS);240
12.9;9 Fibers;242
12.10;References;243
13;Hafnium-Containing Nanocomposites;245
13.1;1 Introduction;245
13.2;2 Results and Discussion;247
13.3;3 Thermodynamic Analysis of the Hf–C–H–O System;257
13.4;4 Experimental;267
13.5;References;270
14;Nanoscale Dendrimer-Platinum Conjugates as Multivalent Antitumor Drugs;272
14.1;1 Introduction;272
14.2;2 PAMAM Dendrimer-Platinum Conjugates and Applications;282
14.3;3 Perspectives on Dendrimer Platinum Conjugates;293
14.4;References;294
15;Mössbauer Spectroscopy and Organotin Polymers;298
15.1;1 Introduction;298
15.2;2 Basics;299
15.3;3 Research with Organotin Compounds;307
15.4;4 Experimental;311
15.5;5 Structural Possibilities;313
15.6;6 Mössbauer Data and Analysis;316
15.7;7 Infrared Data;323
15.8;8 Reaction Implications;326
15.9;9 Chain Length;327
15.10;10 Importance of Present Products;327
15.11;11 Conclusions;327
15.12;References;328
16;Fundamentals of Fragmentation Matrix Assisted Laser Desorption/ Ionization Mass Spectrometry;331
16.1;1 Introduction;331
16.2;2 Experimental;332
16.3;3 Results and Discussion;333
16.4;4 Further Considerations;343
16.5;References;352
17;Borazine Based Preceramic Polymers for Advanced BN Materials;353
17.1;1 Background;353
17.2;2 Boron-Containing Polymers;354
17.3;3 Future Considerations;370
17.4;References;371
18;Recent Advances in High-Temperature Network Polymers of Carboranylenesiloxanes and Silarylene- Siloxanes;374
18.1;1 Introduction;374
18.2;2 Research and Discussion;378
18.3;3 Further Considerations;395
18.4;References;403
19;Antimony-Containing Polymers;405
19.1;1 Introduction;405
19.2;2 Polyesters;406
19.3;3 Polyoxamines;408
19.4;4 Polyamines;410
19.5;5 Polyethers;411
19.6;6 Incorporation of Known Drugs;412
19.7;7 Other;417
19.8;References;418
20;Bacterial Inhibition by Organotin-Containing Polymers;420
20.1;1 Bacteria Basics;420
20.2;2 Antibacterial Action;423
20.3;3 Organotin Activities;426
20.4;4 Specific Organotin Antibacterial;429
20.5;5 Combining of Antibacterial Agents;431
20.6;6 Case for Polymeric Antibacterial Agents;431
20.7;7 Organotin-Containing Polymers;432
20.8;8 General Experimental;434
20.9;9 Current Test Organisms;436
20.10;10 Monomer Results;437
20.11;11 Organotin Polymers;438
20.12;12 Organotin Polyamines;438
20.13;13 Combined Antibacterial Agents;440
20.14;References;444
21;Polymeric Organotin Fibers;447
21.1;1 Background;447
21.2;2 Organotin Polyethers-General;450
21.3;3 Experimental;451
21.4;4 1,4-Butynediol Product;452
21.5;5 Organotin Polymer Fibers;453
21.6;6 Application;458
21.7;References;460
22;Index;462