Crystallographic Statistics in Chemical Physics

An Approach to Statistical Evaluation of Internuclear Distances in Transition Element Compounds
Softcover Nachdruck of the original 1. Auflage 1988
ISBN: 978-3-662-01601-5
Verlag: Springer

Buch, Englisch, Band 12, 185 Seiten, Format (B × H): 170 mm x 244 mm, Gewicht: 349 g

Reihe: Inorganic Chemistry Concepts

This book introduces the concept of crystallographic non-
rigidity and asymmetry of the transition elements as central
atoms organometallic compounds. This intrinsic behavior of
central atoms in condensed matter is quantified by applying
statistical approach. Averaging of extrinsic factors in
crystal structures is tested by using variance analysis.
Introductionof the above mentioned concept and applications
of variance analysis as an approximation for considering
factors influencing properties of central atomin the
crystal is original and new.

Zielgruppe

Research

Autoren/Hrsg.

Valach, Fedor

Melnik, Milan

Ondracek, Jan

Fachgebiete

• Naturwissenschaften Physik Thermodynamik Festkörperphysik, Kondensierte Materie
• Naturwissenschaften Chemie Physikalische Chemie Quantenchemie, Theoretische Chemie
• Naturwissenschaften Chemie Anorganische Chemie
• Geowissenschaften Geologie Petrologie, Mineralogie

Inhaltsverzeichnis

1 Statistics of Interatomic Distances.- 1.1 Some Statistical Concepts and Inferences.- 1.2 Statistics of Lengths of Interatomic Vectors.- Glossary of Symbols.- 1.3 References.- 2 Factors Influencing the Dispersion of Lengths of Interatomic Vectors.- 2.1 Application of Variance Analysis.- 2.2 Nonrigid Behavior of Central Monatomic Entities.- Glossary of Symbols.- 2.3 References.- 3 Statistics of Crystallographic Sites of Central Monatomic Entities.- 3.1 Crystallographic Sites.- 3.2 Lattice Complexes.- 3.3 Domains of Influence and Lattice Complexes.- 3.4 Matrix Representations of Symmetry Point Groups of Crystallographic Sites.- 3.5 Occurence of Central Monatomic Entities in Sites of Weissenberg Lattice Complexes.- Glossary of Symbols.- 3.6 References.- 4 Statistics of Bond Distances Between Central Monatomic Entities and Ligands.- 4.1 Terms of Monatomic Entities of Transition Elements and Splitting of their Energy Levels in the Crystal Field.- 4.2 Cu(II) Compounds.- 4.3 Ag(I) Compounds.- 4.4 Cd(II) Compounds.- 4.5 Fe(II) Compounds.- 4.6 Cr(III), Mo(V), Pd(II), Co(III), Ni(II), Zn(II), Nd(III), and Hg(II) Compounds.- Glossary of Symbols.- 4.7 References.- 5 Conclusions.- 5.1 References.- Chemical Abbreviations.- Appendix A.- References.- Appendix B.- Appendix C.- Appendix D.