Supramolecular Catalysis

New Directions and Developments
1. Auflage 2022
ISBN: 978-3-527-34902-9
Verlag: Wiley-VCH GmbH

Buch, Englisch, 656 Seiten, Format (B × H): 175 mm x 250 mm, Gewicht: 1450 g

Supramolecular Catalysis

Provides a timely and detailed overview of the expanding field of supramolecular catalysis

The subdiscpline of supramolecular catalysis has expanded in recent years, benefiting from the development of homogeneous catalysis and supramolecular chemistry. Supramolecular catalysis allows chemists to design custom-tailored metal and organic catalysts by devising non-covalent interactions between the various components of the reaction.

Edited by two world-renowned researchers, Supramolecular Catalysis: New Directions and Developments summarizes the most significant developments in the dynamic, interdisciplinary field. Contributions from an international panel of more than forty experts address a broad range of topics covering both organic and metal catalysts, including emergent catalysis by self-replicating molecules, switchable catalysis using allosteric effects, supramolecular helical catalysts, and transition metal catalysis in confined spaces. This authoritative and up-to-date volume: - Covers ligand-ligand interactions, assembled multi-component catalysts, ligand-substrate interactions, and supramolecular organocatalysis and non-classical interactions
- Presents recent work on supramolecular catalysis in water, supramolecular allosteric catalysis, and catalysis promoted by discrete cages, capsules, and other confined environments
- Highlights current research trends and discusses the future of supramolecular catalysis
- Includes full references and numerous figures, tables, and color illustrations

Supramolecular Catalysis: New Directions and Developments is essential reading for catalytic chemists, complex chemists, biochemists, polymer chemists, spectroscopists, and chemists working with organometallics.

Autoren/Hrsg.

Leeuwen, Piet W. N. M. van

Raynal, Matthieu

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Supramolekularchemie
• Naturwissenschaften Chemie Physikalische Chemie Chemische Reaktionen, Katalyse
• Naturwissenschaften Chemie Organische Chemie Organometallchemie

Inhaltsverzeichnis

Preface
Introduction
LIGAND-LIGAND INTERACTIONS
Supramolecular Construction of Bidentate Ligands through Self-assembly by Hydrogen Bonding
Self-Assembled bidentate ligands in transition metal catalysis; from fundamental invention to commercial application
SELF-ASSEMBLED NANOSTRUCTURES AND MULTI-COMPONENT ASSEMBLIES
Assembled Ionic Molecular Catalysts and Ligands
Self-Amplification of Enantioselectivity in Asymmetric Catalysis by Supramolecular Recognition and Stereodynamics
Interlocked Molecules in Asymmetric Catalysis
Catalytic Supramolecular Gels
Supramolecular helical catalysts
Self-Assembled multi-component supramolecular catalysts for asymmetric reactions
LIGAND-SUBSTRATE INTERACTIONS
Harnessing non-covalent interactions for control of site-selectivity in transition metal-catalyzed C-H activation and cross-coupling
Supramolecular interactions in distal C-H activation of (hetero)arenes
Transition metal-catalyzed, site- and enantioselective oxygen and nitrogen transfer enabled by lactam hydrogen bonds
Supramolecular substrate orientation as strategy to control selectivity in transition metal catalysis
Phosphine Ligands with Acylguanidinium Groups as Substrate-directing Unit
Chemical reactions controlled by remote Zn...N interactions between substrates and catalysts
CATALYSIS PROMOTED BY DISCRETE CAGES, CAPSULES AND OTHER CONFINED ENVIRONMENTS
Artificial Enzymes Created Through Molecular Imprinting of Cross-Linked Micelles
Bioinspired catalysis using innately polarized Pd2L4 coordination cages
Supramolecular catalysis with a cubic coordination cage: contributions from cavity and external-surface binding
Transition metal catalysis in confined spaces
Catalysis by Metal Organic Cages: A Computational Perspective
N-heterocyclic carbene (NHC)-capped Cyclodextrins for cavity-controlled catalysis
Supramolecular Catalysis by Metallohosts Based on Glycoluril
Catalysis inside the hexameric resorcinare capsule: Towards addressing current challenges in synthetic organic chemistry
Supramolecular Organocatalysis Within the Nanospace of Resorcinarene Capsule
Resorcin[4]arene hexamer: from nanocontainer to nanocatalyst
SUPRAMOLECULAR ORGANOCATALYSIS AND NON-CLASSICAL INTERACTIONS
The Aryl-Pyrrolidine-tert-Leucine Motif as a New Privileged Chiral Scaffold: The Role of Non-Covalent Stabilizing Interactions
Chiral Triazole Foldamers in Enantioselective Anion-Binding Catalysis
Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades
Exploration of halogen bonding for the catalysis of organic reactions
Chalcogen-Bonding Catalysis
Asymmetric Supramolecular Organocatalysis: the Fourth Pillar of Catalysis
SUPRAMOLECULAR CATALYSIS IN WATER
Metal Catalysis in Micellar Media
Surfactant assemblies as nanoreactors for organic transformations
Compartmentalized polymers for catalysis in aqueous media
Phosphines modified by cyclodextrins for supramolecular catalysis in water
Water-Soluble Yoctoliter Reaction Flasks
Chemical catalyst-promoted regioselective histone acylation
Protein-substrate supramolecular interactions for the shape selective hydroformylation of long chain a-olefins
Supramolecular assembly of DNA- and protein-based artificial metalloenzymes
SUPRAMOLECULAR ALLOSTERIC CATALYSTS AND REPLICATORS
Switchable Catalysis Using Allosteric Effects
Supramolecularly regulated enantioselective catalysts
Emergent catalysis by self-replicating molecules

Über Autor(innen)

Piet van Leeuwen worked at the Koninklijke Shell Laboratorium Amsterdam (1968-1994) heading the homogeneous catalysis group, he is emeritus professor of homogeneous catalysis of the University of Amsterdam (1989-2007) and the Eindhoven University of Technology (2001-2006), the Netherlands, he was Group leader in ICIQ, Tarragona, Spain (2004-2015), and had an IDEX Chair at LPCNO in INSA-Toulouse, France (2015-2020).
 
Matthieu Raynal is a researcher at Sorbonne Université, Paris, France. His current research focuses on the development of supramolecular helical catalysts, the design of functional chiral assemblies, and the structure-property relationship of supramolecular polymers.