Aaa / Suschitzky Progress in Heterocyclic Chemistry

A Critical Review of the 1988 Literature Preceded by Three Chapters on Current Heterocyclic Topics
1. Auflage 2016
ISBN: 978-1-4832-9377-6
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 1, 345 Seiten, Web PDF

Reihe: Progress in Heterocyclic Chemistry

The International Society of Heterocyclic Chemistry in collaboration with Pergamon Press is pleased to announce a new annual publication, Progress in Heterocyclic Chemistry. The first volume contains chapters on three new developing topics with the remainder of the volume being devoted to highlights of the 1988 heterocyclic chemistry literature. These highlights are novel and unusual chemistry and not a condensed summary of the literature. Subsequent volumes will review other topics of current interest to heterocyclic chemists as well as covering the previous year's literature. All contributors will be acknowledged authorities in their fields.

Autoren/Hrsg.

Aaa, E. F. V.

Suschitzky, H.

Inhaltsverzeichnis

1;Front Cover;1
2;A Critical Review of the 1988 Literature Preceded by Three Chapters on Current Heterocyclic Topics;4
3;Copyright Page;5
4;Table of Contents;6
5;Foreword;8
6;Advisory Editorial Board Members;10
7;Chapter 1. Some New Strategies for Protection, Activation and Direction in Lithiation Chemistry;12
7.1;1.1 INTRODUCTION;12
7.2;1.2 CARBAMATE ANION INTERMEDIATES;12
7.3;1.3 AMINAL INTERMEDIATES;20
7.4;1.4 HEMIAMINAL ANION INTERMEDIATES;27
7.5;1.5 ACTIVATION OF HETEROCYCLIC N-ALKYL AND S-ALKYL GROUPS TOWARD LITHIATION;28
7.6;1.6 CONCLUSIONS;35
7.7;1.7 REFERENCES;37
8;Chapter 2. Recent Applications of the Inverse Electron Demand Diels-Alder Reaction;41
8.1;INTRODUCTION;41
8.2;DISCUSSION;44
8.3;ACKNOWLEDGMENTS;72
8.4;REFERENCES;72
9;Chapter 3. Biotransformations Relating to Heterocyclic Compounds;76
9.1;Introduction;76
9.2;Hydrolysis and esterification reactions;77
9.3;Oxidations;80
9.4;Reduction Reactions and other Biotransformations;85
9.5;Future Prospects;88
9.6;References;89
10;Chapter 4. Three-Membered Ring Systems;93
10.1;4.1 INTRODUCTION;93
10.2;4.2 EPOXIDES;93
10.3;4.3 DIOXIRANES;100
10.4;4.4 AZIRIDINES;101
10.5;4.4 TRIAZIRINES;104
10.6;4.5 DIAZIRINES;104
10.7;4.6 OXAZIRIDINES;104
10.8;4.7 EPISULPHIDES;104
10.9;4.8 References;106
11;Chapter 5. Four-Membered Ring Systems;109
11.1;5.1 AZETIDINES,AZETINESANDAZETES;109
11.2;5.2 OXETANESANDTHIETANES;110
11.3;5.3 DIOXETANES;112
11.4;5.4 OTHER FOUR-MEMBERED HETEROCYCLES;112
11.5;5.5 AZETIDIN-2-ONES AND RELATED SYSTEMS;114
11.6;References;118
12;Chapter 6.1 Five-Membered Ring Systems: Thiophenes and Se and Te Analogs ;121
13;Chapter 6.2. Five-Membered Ring Systems: Pyrroles and Benzo Derivatives;122
13.1;6.2.1 Syntheses Involving Ring Closure;122
13.2;6.2.2 Ring Substitution and Substituent Group Interconvers ions;126
13.3;6.2.3 Cycloaddition Reactions;131
14;Chapter 6.3 Five-Membered Ring Systems: Furans and Benzo Derivatives ;137
14.1;6.31 INTRODUCTION;137
14.2;6.32 REACTIVITY AT RING ATOMS;137
14.3;6.33 REACTIVITY OF SUBSTITUENTS;144
14.4;6.34 RING SYNTHESIS;145
14.5;REFERENCES;150
15;Chapter 6.4 Five-Membered Ring Systems: With More Than One N Atom;154
15.1;6.4.1. INTRODUCTION;154
15.2;6.4.2. PYRAZOLES AND RING-FUSED PYRAZOLES;154
15.3;6.4.3. IMIDAZOLES AND RING-FUSED IMIDAZOLES;157
15.4;6.4.4. 1,2,3-TRIAZOLES AND RING-FUSED 1,2,3-TRIAZOLES;161
15.5;6·4·5. 1,2,4-TRIAZOLES AND RING-FUSED 1,2,4-TRIAZOLES;164
15.6;6.4.6. TETRAZOLES AND RING-FUSED TETRAZOLES;168
15.7;6.4.7. METAL COMPLEXES FROM 5-MEMBERED RINGS WITH 2 OR MORE NITROGENS;169
15.8;ACKNOWLEDGEMENTS;170
15.9;6.4.8. REFERENCES;171
16;Chapter 6.5 Five-Membered Ring Systems: With N and S (Se) Atoms ;175
16.1;6.5.1 Isothiazoles;175
16.2;6.5.2 Thiazoles;177
16.3;6.5.3 Thiadiazoles;180
16.4;6.5.4 Selenazoles, and Selenadiazoles;184
16.5;6.5.5. Reviews;184
16.6;References;185
17;Chapter 6.6 Five-Membered Ring Systems: With O and S (Se, Te) Atoms ;189
17.1;6.6.1 INIRODUCTION;189
17.2;6.6.2 1,3-DI0X0LANES;189
17.3;6.6.3 OXATHIOLES AND OXAIHIOLANES;192
17.4;6.6.4 1,3-DITHIOLANES;193
17.5;6.6.5 1,3-DITOIOLES AND DITHIOLAISES;193
17.6;6.6.6 REFERENCES;195
18;Chapter 6.7 Five-Membered Ring Systems: With O and N Atoms ;197
18.1;Isoxazoles and Benzisoxazoles;197
18.2;Oxazoles and Benzoxazoles;208
18.3;Oxadiazoles;219
18.4;References;220
19;Chapter 7.1 Six-Membered Ring Systems: Pyridine and Benzo Derivatives ;225
19.1;7.1,1 Synthesis;225
19.2;7.1.2 Reactions;238
19.3;7.1 REFERENCES;251
20;Chapter 7.2 Six-Membered Ring Systems: Diazines and Benzo Derivatives ;254
20.1;7.2.1 INTRODUCTION;254
20.2;7.2.2 STRUCTURE;255
20.3;7.2.3 PYRIDAZINE, CINNOLINE, PHTHALAZINE;256
20.4;7.2.4 PYRIMIDINE, QUINAZOLINE;259
20.5;7.2.5. PYRAZINE, QUINOXALINE, PHENAZINE;266
20.6;REFERENCES;270
21;Chapter 7.3 Six-Membered Ring Systems: Tri and Tetrazines and Fused Systems ;274
21.1;7,3.1 Synthesis;274
21.2;7.3.2 Reactions;280
21.3;7.3 REFERENCES;289
22;Chapter 7.4 Six-Membered Ring Systems: With O and/or S Atoms ;291
22.1;1. BETEROCYCLES CONTAINING ONE OXYGEN ATOM;291
22.2;2. HETEROCYCLES CONTAINING ONE SULPHUR ATOM;301
22.3;3. HETBROCYCLES CONTAINING TWO OR MORE OXYGEN ATOMS;302
22.4;4. HETEROCYCLES CONTAINING TWO SDLPHDR ATOMS;304
22.5;5. HETEROCYCLES CONTAINING BOTH OXYGEN AND SDLPHDR ATOMS IN THE SAME RING;304
22.6;References;305
23;Chapter 8. Seven-Membered Rings;308
23.1;INTRODUCTION;308
23.2;8.1 7-Membered Rings with Nitrogen;309
23.3;8.2 Seven-Membered Rings with Oxygen;315
23.4;8.3 7-Membered Rings with Sulfur;317
23.5;8.4 7-Membered Rings with Heteroatom Combinations;318
23.6;VOLUME 8 REFERENCES;321
24;Chapter 9. Eight-Membered and Larger Rings;328
24.1;9.1 INTRODUCTION;328
24.2;9.2 CARBON-OXYGEN RINGS;329
24.3;9.3 CARBON-SULFUR RINGS;332
24.4;9.4 CARBON-SELENIUM RINGS;333
24.5;9.5 CARBON-NITROGEN RINGS;333
24.6;9.6 CARBON-OXYGEN-NITROGEN RINGS;334
24.7;9.7 CARBON-NITROGEN-SULFUR RINGS;335
24.8;9.8 CARBON-NITROGEN-ARSENIC RINGS;335
24.9;9.9 CARBON-NITROGEN-SULFUR-OXYGEN RINGS;335
24.10;9;10 CARBON-OXYGEN-SULFUR-METAL RINGS;335
24.11;REFERENCES;335
25;SUBJECT INDEX;338